• Title/Summary/Keyword: Liquid Layer

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Application of Ionic Liquids Based on 1-Ethyl-3-Methylimidazolium Cation and Fluoroanions to Double-Layer Capacitors

  • Ue, Makoto;Takeda, Masayuki
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.192-196
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    • 2002
  • Ionic liquids based on l-ethyl-3-methylimidazolium cation $(EMI^+)$ and inorganic or organic anions containing fluorine atoms were applied to electrolyte materials for double-layer capacitors. The double-layer capacitors composed of a pair of activated carbon electrodes and an ionic liquid selected from $EMIBF_4,\; EMINbF_6,\;EMITaF_6,\;EMICF_3SO_3,\;EMI(CF_3SO_2)_2N,\;and\;EMI(C_2F_5SO_2)_2N$ showed inferior low-temperature characteristics to those of a conventional nonaqueous electrolyte based on propylene carbonate (PC) solvent. On the other hand, the capacitor using $EMIF{\cdot}2.3HF$ showed excellent low-temperature characteristics due to its high conductivity at low temperatures, however, it had a lower working voltage $(\~2V)$ than the conventional nonaqueous counterpart $(\~3V)$.

A Characteristic of Microstructures in Bonding Interlayer of Brazed Titanium to Copper (브레이징한 Ti/Cu 접합계면부의 미세조직 특성)

  • 김우열;정병호;이성렬
    • Journal of Welding and Joining
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    • v.13 no.3
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    • pp.106-115
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    • 1995
  • To know the bonding phenomena of Ti/Cu brazed joint, a characteristic of microstructures in bonding interlayer of vacuum brazed pure Ti to Cu has been studied in the temperature range from 1088 to 1133K for various bonding times using Ag-28wt%Cu filler metal. Also intermediate phases formed in bonded interlayer and behavior of layer growth have been investigated. The obtained results in this study are as follows: 1) Liquid insert metal width at the each brazing temperature was proportional to the square root of brazing time, and it was considered that the liquid insert metal width was controlled by the diffusion rate process of primary .alpha.-Cu formed at the Ti side. 2) Intermediate phases formed near the Ti interface were .betha.-Ti and intermetallic compounds TiCu, Ti$_{2}$Cu, Ti$_{3}$Cu, and TiCu. 3) .betha.-Ti formed in Ti base metal durig brazing transformed to lamellar structure, .alpha.-Ti + Ti$_{2}$Cu. The structure came from the eutectoil decomposition reaction in cooling. And the width of .betha.-Ti layer was proportional to the square root of brazing time, and it was considered that the growth of .betha.-Ti layer was controlled by interdiffusion rate process in .betha.-Ti. 4) The layer growth of TiCu, Ti$_{3}$Cu$_{4}$ and TiCu, phases formed near the Ti interface was linerface was linearly proportional to the brazing time, and it was considered that the layer growth of these phases was controlled by the chemical reaction rate at the interface.

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Liquid Crystal Alignment on the Multiple Photo-treated Layers by the Interfered Laser Light

  • Lee, Eun-Kyu;Kim, Jong-Hyun
    • Journal of Information Display
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    • v.8 no.1
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    • pp.6-9
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    • 2007
  • Orientational alignment patterns have been proven to be that they are very useful for realizing diverse properties of liquid crystals. Here we produced the patterns combining interfered laser beams. A photo-isomerizable polymer including azo unit, which induces nematic liquid crystal alignment to the polarized laser light, was used as the alignment to layer. Double irradiations into two orthogonal directions brought the orientation patterns similar to the checkerboard. It indicates the possibility of bistability on those patterns.

Mechanism of Photorefractive Effect in Polymer Layered Nematic Liquid Crystal Systems (고분자 층이 도입된 네마틱 액정 시스템의 광굴절 효과 기작)

  • Mun Jun-Ho;Yun Chun-Seop;Kim Hyeon-Uk;Choe Su-An;Kim Jong-Deuk
    • Proceedings of the Optical Society of Korea Conference
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    • 2001.02a
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    • pp.206-207
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    • 2001
  • The photorefractive (PR) effect in liquid crystals sandwiched between photoconductive polymer layers was first studied by Ono et al. They reported that the PR effect vanished at steady state If there were not insulating layers because no charge trapping occurred in the photoconductive poly(N-vinylcarbazole) (PVK) layers. However we observed a significant PR effect in the polymer layered liquid crystal (PLLC) system where a liquid crystal layer doped with fullerene is sandwiched between two photoconductive PVK layers. (omitted)

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The Comparison to Physical Properties of Large Size Indium Zinc Oxide Transparent Conductive Layer (대면적 상온 Indium Zinc Oxide 투명 도전막의 물성 특성 비교)

  • Joung, Dae-Young;Lee, Young-Joon;Park, Joon-Yong;Yi, Jun-Sin
    • Journal of the Korean institute of surface engineering
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    • v.41 no.1
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    • pp.6-11
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    • 2008
  • An Indium Zinc Oxide(IZO) transparent conductive layer was deposited on a large size glass substrate by using magnetron dc sputtering method with varying a deposition temperature. As the deposition temperature decreased to a room temperature, the sheet resistance of IZO film increased. But this deposition temperature range is included in an applicable to a device. From a standpoint of the sheet resistance, the differences of the sheet resistance were not great and the uniformity of the layer was uniformed around 10%. Crystallization particles were shown on the surface of the layer as deposition temperature increased, but these particles were not shown on the surface of the layer as deposition temperature decreased to the room temperature. It didn't make a scrap of difference in a transmittance of varying deposition temperature. Therefore, it is concluded that IZO thin film manufactured by the room temperature deposition condition can be used as a large size transparent conductive layer of a liquid crystal display device.

Current Increase Effect and Prevention for Electron Trapping at Positive Bias Stress System by Dropping the Nematic Liquid Crystal on the Channel Layer of the a-InGaZnO TFT's

  • Lee, Seung-Hyun;Heo, Young-Woo;Kim, Jeong-Joo;Lee, Joon-Hyung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.163-163
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    • 2015
  • The effect of nematic liquid crystal(5CB-4-Cyano-4'-pentylbiphenyl) on the amorphous indium gallium zinc oxide thin film transistors(a-IGZO TFTs) was investigated. Through dropping the 5CB on the a-IGZO TFT's channel layer which is deposited by RF-magnetron sputtering, properties of a-IGZO TFTs was dramatically improved. When drain bias was induced, 5CB molecules were oriented by Freedericksz transition generating positive charges to one side of dipoles. From increment of the capacitance by orientation of liquid crystals, the drain current was increased, and we analyzed these phenomena mathematically by using MOSFET model. Transfer characteristic showed improvement such as decreasing of subthreshold slope(SS) value 0.4 to 0.2 and 0.45 to 0.25 at linear region and saturation region, respectively. Furthermore, in positive bias system(PBS), prevention effect for electron trapping by 5CB liquid crystal dipoles was observed, which showing decrease of threshold voltage shift [(${\delta}V$]_TH) when induced +20V for 1~1000sec at the gate electrode.

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Concentration of Liquid-phase in the Surface Region and Microstructural Change in Pressureless Sintered$\beta$-SiC (상압소결 $\beta$-SiC에 있어서 표면부에서의 액상집중과 미세구조의 변화)

  • Lee, Jong-Kook;Yang, Gwon-Seung;Kim, Hwan
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.921-927
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    • 1996
  • The liquid-phase concentration from the interior to the surface region and its influence on the microstructural changes were investigated in pressureless sintered $\beta$-SiC Surface reaction-layer was formed by reaction of packing powder and volatile components on the surface during sintering which was induced the concentration of liquid-phase in the surface regions. The microstructural changes between the surface region and the interior were appeared in sintered specimen which was resulted from the difference of liquid-phase content during sintering. Microstructural changes were observd with the depth of about 250${\mu}{\textrm}{m}$ from he surface. The grain size and aspect ratio of SiC in the interior are larger than those in the surface region and the rate of transforma-tion of $\beta$-to $\alpha$-SiC during sintering is higher in the interior than that in the surface region.

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Development of X-ray Detector using Liquid Crystal with Front Light (전면광원(Front Light)을 적용한 액정 X선 검출기 개발)

  • Rho, Bong Gyu;Baek, Sam Hak;Kang, Seok Jun;Lee, Jong Mo;Bae, Byung Seong
    • Journal of the Korean Society of Radiology
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    • v.13 no.6
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    • pp.831-840
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    • 2019
  • The X-ray detector by liquid crystal with front light was proposed and verified by a X-ray image. The proposed detector utilizes the visible light instead of the electric signal by transistor. Therefore, it shows low noise and can be fabricated at low cost. The liquid crystal detector uses the orientation change of the liquid crystal molecule by conductivity change of the photoconductive layer. We can get the X-ray image from the transmitted light through the liquid crystal. The X-ray dose was calibrated from the measured transmittance of the visible light after comparison to the reference transmittance curve of the liquid crystal. The amorphous Se was used for photo con ducting layer and parylene was used for the liquid crystal alignment instead of the conventional alignment layer which needs high-temperature process over 200℃. The proposed X-ray detector can decrease the X-ray dose by high sensitivity which was verified by simulation. After the fabrication of the X-ray detector, the X-ray image was obtained as a function of the bias voltage to the liquid crystal. 10 lines/mm resolution was obtained from the line pattern and we will apply it to the 17inch diagonal liquid crystal X-ray detector with 3π retardation.

Polarization-dependence of liquid crystal alignment on an organic surface with ion beam irradiation

  • Choi, Dae-Sub;Han, Jeong-Min
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.208-208
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    • 2009
  • We used Brewster's Law to examine the mechanism of liquid crystal (LC) alignment on an organic insulation layer when subjected to ion-beam irradiation. Brewster's Law implies that the maximum rate polarized ray on a slanted insulation layers on the substrate and it illustrates the dependence of polarization and themechanical structure on the ion beam irradiation process. The pretilt angle of nematic LCs on the organic insulation surface was about $1.13^{\circ}$ for an ion beam exposure of $45^{\circ}$ for 1 minute at 1800eV. This shows the dependence of LC alignment on the polarization ratio in a slanted organic insulation layer.

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Solution-Derived Hafnium Lanthanum Oxide Films Prepared Using Ion-Beam Irradiation and Their Applications as Alignment Layers for Twisted-Nematic Liquid Crystal Displays

  • Oh, Byeong-Yun
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.6
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    • pp.355-358
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    • 2016
  • We present the alignment characteristics of LC (liquid crystal) molecules on solution-derived HLO (hafnium lanthanum oxide) films fabricated using IB (ion-beam) irradiation. We then demonstrated that LC molecules can be homogeneously and uniformly aligned on the HLO film irradiated at an IB incident energy of 1.2 keV. Physicochemical analysis methods such as atomic force microscopy and X-ray photoelectron spectroscopy were used to verify the LC alignment mechanism on the IB-irradiated HLO film. In addition, the electro-optical performance of a TN (twisted-nematic) cell fabricated using the IB-irradiated HLO film exhibited characteristics superior to those of the conventional TN cell fabricated using a rubbed polyimide layer.