• Advances in materials Research
• /
• v.1 no.4
• /
• pp.299-310
• /
• 2012

This article describes the synthesis of a novel N-substituted pyrrole monomer containing an azobenzene group. The 2-[N-ethyl-N-[4-[(4-nitrophenyl) azo]-phenyl] amino] ethyl-3-chloropropionate (RedII) compound was synthesized via reaction of 4-nitro-4'-[N-ethyl-N-(2-hydroxyethyl)-amino] azobenzene (RedI) and 3-chloropropionic acid. RedII was reacted with the potassium salt of pyrrole then 2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate (Py-RedII) was prepared. Chemical polymerization of Py-RedII and copolymerization of Py-RedII with pyrrole carried out using $FeCl_3$. Poly (2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate) (PPy-RedII) was characterized by UV, IR, $^1HNMR$, $^{13}CNMR$ spectroscopies. Electropolymerization of Py-RedII and electroco-polymerization of Py-RedII and pyrrole were studied using conventional three electrodes system, Ag/AgCl reference electrode, platinum counter electrode and GC disk working electrode. Scanning electron microscopy (SEM), thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) were used for thermal and rheological studies. The TGA curve of PPy-RedII demonstrated a high thermal stability up to 200°C and its DSC thermogram showed two endothermic peaks at 88 and $122^{\circ}C$. The glass transition temperature of the polymer was found to be above the room temperature. Electrical conductivities of PPy-RedII and it's copolymer with pyrrole (PPy-RedII-co-Py) were studied by the four-probe method and produced conductivities of $7.5{\times}10^{-4}$ and $6.5{\times}10^{-3}Scm^{-1}$, respectively.

• Geomechanics and Engineering
• /
• v.16 no.2
• /
• pp.125-140
• /
• 2018

Tianjin, which is located on the west shore of the Bohai Sea, is part of China's Circum-Bohai-Sea Region, where very weak clay is deposited. From the 1970s to the early $21^{st}$ century, Tianjin marine clay deposits have been the subject of numerous geotechnical investigations. Because of these deposits' geological complexity, great depositional thickness, high water content, large void ratio, excessive settlement, and low shear strength, the geotechnical properties of Tianjin marine clay need to be summarized and evaluated based on various in situ and laboratory tests so that Tianjin can safely and economically sustain more infrastructure in the coming decades. In this study, the properties of Tianjin marine clay, especially its consolidation properties, are summarized, evaluated and discussed. The focus is on establishing correlations between the geotechnical property indexes and mechanical parameters of Tianjin marine clay. These correlations include the correlations between the water content and the void ratio, the depth and the undrained shear strength, the liquid limit and the compression index, the tip resistance and the constrained modulus, the plasticity index and the ratio of undrained shear strength and the preconsolidation pressure. In addition, the primary consolidation properties of Tianjin marine clay, such as the intrinsic compression line (ICL), sedimentation compression line (SCL), compression index, $C_c$, coefficient of consolidation, $C_v$, and hydraulic conductivity change index, $C_{kv}$, are evaluated and discussed. A secondary consolidation property, i.e., the secondary compression index, $C_a$, is also investigated, and the results show that the ratio of $C_a/C_c$ for Tianjin marine clay can be used to calculate $C_a$ in secondary consolidation settlement predictions.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2010.08a
• /
• pp.167-167
• /
• 2010

Indium tin oxide (ITO) has been widely used as transparent conductive oxides (TCOs) for transparent electrodes of various optoelectronic devices, such as liquid crystal displays (LCD) and organic light emitting diodes (OLED). However, indium has become increasingly expensive and rare because of its limited resources. In addition, ITO thin films have some problems for OLED and flexible displays, such as imperfect work function, chemical instability, and high deposition temperature. Therefore, multi-component TCO materials have been reported as anode materials. Among the various materials, IZTO thin films have been gained much attention as anode materials due to their high work function, good conductivity, high transparency and low deposition temperature. IZTO thin films with a thickness of 200nm were deposited on Corning glass substrate at different substrate temperature by pulsed DC magnetron sputtering with a sintered ceramic target of IZTO (In2O3 70 wt%, ZnO 15 wt%, SnO2 15 wt%). We investigated the electrical, optical, structural properties of IZTO thin films. As the substrate temperature is increased, the electrical properties of IZTO are improved. All IZTO thin films have good optical properties, which showed an average of transmittance over 80%. These IZTO thin films were used to fabricate organic light emitting diodes (OLEDs) as anode and the device performances studied. As a result, IZTO has utility value of TCO electrode although it reduced indium and we expect it is possible for the IZTO to apply to flexible display due to the low processing temperature.

• Journal of Powder Materials
• /
• v.24 no.4
• /
• pp.308-314
• /
• 2017

$Fe_3O_4$/Fe/graphene nanocomposite powder is synthesized by electrical wire explosion of Fe wire and dispersed graphene in deionized water at room temperature. The structural and electrochemical characteristics of the powder are characterized by the field-emission scanning electron microscopy, X-ray diffraction, Raman spectroscopy, field-emission transmission electron microscopy, cyclic voltammetry, and galvanometric discharge-charge method. For comparison, $Fe_3O_4$/Fe nanocomposites are fabricated under the same conditions. The $Fe_3O_4$/Fe nanocomposite particles, around 15-30 nm in size, are highly encapsulated in a graphene matrix. The $Fe_3O_4$/Fe/graphene nanocomposite powder exhibits a high initial charge specific capacity of 878 mA/g and a high capacity retention of 91% (798 mA/g) after 50 cycles. The good electrochemical performance of the $Fe_3O_4$/Fe/graphene nanocomposite powder is clearly established by comparison of the results with those obtained for $Fe_3O_4$/Fe nanocomposite powder and is attributed to alleviation of volume change, good distribution of electrode active materials, and improved electrical conductivity upon the addition of graphene.

• Journal of Animal Environmental Science
• /
• v.19 no.1
• /
• pp.39-46
• /
• 2013

This study was carried out to compare the filtration effect of anaerobic digestion waste water by compost filtration bed. Three types of filtration systems were set for filtration test following to composition of bedding materials. Two filtration systems were filled with sawdust, rice-hull and wood-chip. And the other was filled with sawdust and rice-hull. Anaerobic digestion waste water was applied evenly on the surface of the filtration bed with spraying nozzle. The concentration of nitrogen, biochemical oxygen demand (BOD), suspended solids (SS) of anaerobic digestion waste water was decreased by filtration treatment. The total nitrogen content was decreased from 1,313 mg/L to 1,090~1,293 mg/L and BOD concentration was decreased from 529.7 mg/L to 125~162.3 mg/L, respectively. The SS content was decreased from 69~79% by filtration process. In addition, the electrical conductivity (EC) was decreased from 10.22 ds/m to 7.91~8.31 ds/m.

• Journal of Electrochemical Science and Technology
• /
• v.8 no.2
• /
• pp.107-114
• /
• 2017

Pseudo capacitors belong to one group of super capacitors which are consisted with non carbon based electrodes. As such, conducting polymers and metal oxide materials have been employed for pseudo capacitors. Conducting polymer based pseudo capacitors have received a great attention due to their interesting features such as flexibility, low cost and ease of synthesis. Much work has been done using liquid electrolytes for those pseudo capacitors but has undergone various drawbacks. It has now been realized the use of solid polymer electrolytes as an alternative. Among them gel polymer electrolytes (GPEs) are in a key place due to their high ambient temperature conductivities as well as suitable mechanical properties. In this study, composition of a polyacrylonitrile (PAN) based GPE was optimized and it was employed as the electrolyte in a pseudo capacitor having polypyrrole (PPy) electrodes. GPE was prepared using ethylene carbonate (EC), propylene carbonate (PC), sodium thiocyanate (NaSCN) and PAN as starting materials. The maximum room temperature conductivity of the GPE was $1.92{\times}10^{-3}Scm^{-1}$ for the composition 202.5 PAN : 500 EC : 500 PC : 35 NaSCN (by weight). Performance of the pseudo capacitor was investigated using Cyclic Voltammetry technique, Electrochemical Impedance Spectroscopy (EIS) technique and Continuous Charge Discharge (GCD) test. The single electrode specific capacity (Cs) was found out to be 174.31 F/g using Cyclic Voltammetry technique at the scan rate of 10 mV/s and within the potential window -1.2 V to 1.2 V. The same value obtained using EIS was about 84 F/g. The discharge capacity ($C_d$) was 69.8 F/g. The capacity fade over 1000 cycles was rather a low value of 4%. The results proved the suitability of the pseudo capacitor for improving the performance further.

• Polymer(Korea)
• /
• v.30 no.6
• /
• pp.471-477
• /
• 2006

Ion exchange metal composite(IPMC) has toughness equivalent to the range of human's muscle, transformation-actuation force by relatively low voltage and the fast response time. Thus, as a new method for preparing thicker IPMC, the solution casting method to make the films of various thicknesses out of liquid nation was attempted in this study. To reduce the surface resistance of electrode, the first plated electrode prepared by Oguro method was replated with Au and Ir using ion beam assisted deposition(IBAD). The microstructures of electrode surfaces before and after IBAD plating were investigated using SEM. The change of water and ion-conductivity in IPMC were measured under applied voltage. The displacement and driving force of IPMCs with various thicknesses were measured to evaluate the driving properties.

• Solar Energy
• /
• v.12 no.3
• /
• pp.28-36
• /
• 1992

The performance of a latent heat storage system using a thermosyphon as the heat transfer device between the heat source and the phase change material was investigated experimentally. In order to increase the effective conductivity of the phase change material, layers of copper wire mesh were immersed in the paraffin wax(Sunoco P-116) in such a way that they also may be considered as fins of the thermosyphon. The important results are as follows : (1) The void space of the wire mesh allowed the convection to occur, thus enhanced the performance of the system : (2) The increase of the number of layer of wire mesh increased the conduction heat transfer. However, it also had adverse effect of subduing convective motion of liquid wax : and (3) Overall heat transfer coefficient and thermosyphon conductance increased with the increase of the number of layer of wire mesh, whereas the heat transfer coefficient between the thermosyphon and the wax decreased.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2010.03a
• /
• pp.11-11
• /
• 2010

In order to design for nano structured materials with enhanced thermoelectric properties, the alloys in the pseudo-binary $Bi_2Te_3$-PbTe system were investigated for their micro structure and thermal properties. For this synthesis the liquid alloys were cooled by water quenching method. The micro structure images were taken by using electron probe micro analyzer (EPMA). Dendritic and lamellar structures were clearly observed with the variation in the composition ratio between $Bi_2Te_3$ and PbTe. It was confirmed that a metastable compounds is $PbBi_2Te_4$ in the The $Bi_2Te_3$-PbTe system. The change in the composition increasing $Bi_2Te_3$ ratio causes to change structure from dendritic to lamellar. Seebeck coefficient of alloys 5 which the mixture rate of $Bi_2Te_3$ is 83% was measured as the highest value. In contrast, the others decreased by increasing $Bi_2Te_3$. n-type characteristics was observed at all condition except alloy 6 which $Bi_2Te_3$ ration is 91%. The power factors of all samples were calculated with Seebeck coefficient and resistivity. Also the thermal conductivity was measured by using laser flash analyzer (LFA). In this work, the microstructures and thermal properties have been measured as a function of ratio of $Bi_2Te_3$ in the $Bi_2Te_3$-PbTe system.

• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.3
• /
• pp.265-269
• /
• 2006

This study was to investigate the effect of acidic leachate on the landfill liner system and healing of cracks by using industrial by-products; BFS(Blast Furnace Slag) and FA(Fly Ash). From the results of pH measurement, for OPC(Ordinary Portland Cement) and DM(Dredged Mud) mixtures immersed acidic leachate, the initial pH($4.5{\sim}5.5$) was heavily increased to approximately 10 after 60 days experiment due to the production of 2 mole $OH^-$ which was occurred by hydrolysis of CaO and MgO etc.. Meanwhile, the initial pH of acidic leachate immersed DM mixtures with BFS and FA respectively was lasted for longer period as compared to the comparison. The reason was that production of low Ca C-S-H hydrates which stabilized in acidic liquid. The physical properties(compressive strength, hydraulic conductivity) of DM mixtures added BFS and FA was improved. It was concluded that the dissolution of hydrates was disturbed by high alkalinity of BFS and FA.