• Korean Chemical Engineering Research
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• v.50 no.6
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• pp.988-993
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• 2012

Energy and cost analysis of the preprocessing for carbon capture and storage transportation such as supercritical compression and liquefaction is done using chemical simulation model. Direct compression to supercritical phase (process 1-1), liquefaction and pumping (process 1-2), carbon dioxide compression and expansion as a refrigerant itself (process 2), usage of other refrigerant with compression and expansion (process 3-1), with absorption chiller (process 3-2), cascade refrigeration (process 3-2) have been simulated and evaluated. The specific cost is about 4 to 7 $/ton.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.2
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• pp.259-264
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• 2020

In this study, comparison study has been performed between two-stage compression and a vapor-recompression refrigeration cycle and a liquefaction using LNG cold heat. When using a first method using two-stage compression and a refrigeration cycle, at least three compressors are required, however when using LNG cold heat, no compressor is required since carbon dioxide can be pumped after condensing with the heat exchange with -160℃ of LNG. Through this study, we can save more than one hundred million KRW annually by using LNG cold heat instead of using gas compression and refrigeration cycle.

• Journal of the Society of Naval Architects of Korea
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• v.55 no.5
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• pp.415-420
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• 2018

The development of sail gas has increased the production of ethane as well as natural gas. The decline in the market price for ethane has led to a change in the petroleum-based ethylene production process into an ethane-based ethylene production process and an increase in the ethane/ethylene trade volume. Large-scale ethane/ethylene carrier have been needed due to an increase in long-distance trade from the US, and cargo type change have leaded to consider a liquefaction process to re-liquefy Boil-Off gas generated during the voyage. In this paper, the liquefaction system of Liquefied Ethane Gas carrier was evaluated with Low-GWP (Low-Global Warming Potential) refrigerant and process parameters, Boil-Off Gas pressure and expansion valve outlet pressure, were optimized. Low-GWP refrigerants were propane (R290), propylene(R1270), carbon dioxide(R744) was considered at two type of liquefaction process such as Linde and cascade cycle. The results show that the optimal pressure point depends on the individual refrigerant and the highest liquefaction efficiency of carbon dioxide (R744) - propane (R290) refrigerant.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.20 no.5
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• pp.1591-1602
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• 1996

In operating the underwater engines such as encountered in exploring submarines, the dumping of the exhaust gas out of the engine requires a large portion of the total power, frequently amounting to 25-30% of the power generated. This unfavorable circumstance can be cured by liquefying the exhaust gas and storing it. In the present study, two liquefaction systems were simulated to enhance the overall efficiency; one is a closed cycle diesel engine and the other is a closed cycle LNG engine. The liquefied natural gas (LNG) is chosen as a fuel, not only because its use is economical but also because its cold energy can be utilized within the liquefaction system. Since a mixture of oxygen and carbon dioxide is used as an oxidizer, liquefying carbon dioxide is of major concern in this study. For further improving this system, the intercooling of the compressor is devised. The necessary power consumed for the liquefying system is examined in terms of the related properties such as pressure and temperature of the carbon dioxide vessel as a function of the amount of the exhaust gas which enters the compressor. The present study was successful to show that much gain in the power and reduction of the vessel pressure could be achieved in the case of the closed cycle LNG engine. The compression power of exhaust gas were observed remarkably lower, typically only 6.3% for the closed cycle diesel engine and 3.4% for the closed cycle LNG engine respectively, out of net engine power. For practicality, a design -purpose map of the operating parameters of the liquefaction systems was also presented.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.2
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• pp.226-233
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• 2023

In this study, we compared the performance of several refrigeration cycles using different refrigerants and utilizing the cold heat of liquefied natural gas (LNG) for the liquefaction of carbon dioxide. The final conditions for the liquefied CO₂ were set to -20℃ and 20 bar. The refrigerants used included R404a, ammonia, propane, and propylene using a vapor recompression refrigeration cycle. For the refrigeration cycle, the CO₂ at room temperature and pressure was compressed in a two-stage compression process with an intermediate cooling stage using a refrigeration unit. To compare with the liquefaction process using refrigeration, we compressed the CO₂ to 8 bar in a single compression stage and cooled it to around -50℃ using the cold heat of the LNG before liquefying it. Results showed that using ammonia as the refrigerant required the least amount of compressor power for the liquefaction process, and the heat transfer area of the evaporator was the smallest when using propylene as the refrigerant. Using the cold heat of LNG instead of refrigeration using R404a resulted in approximately 69% less energy consumption.

• Transactions of the Korean hydrogen and new energy society
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• v.21 no.1
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• pp.72-79
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• 2010

This paper is studying the selective separation of methane and carbon dioxide which are the main ingredients of biogas. Adsorption performance of molecular sieve 13x for carbon dioxide seems to be reasonable. In this experiments carbon dioxide contains about 3~5 ppm of methane and it is impossible to obtain high purity carbon dioxide. Applying the low temperature technique, it is possible to separate methane and carbon dioxide from bio gas. PRO II simulation shows results a small change of liquefaction temperatures and no difference with the used thermodynamic models. Applying low temperature technique, It is possible to separate carbon dioxide and methane from biogas.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.1312-1316
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• 2009

Growing interest in $CO_2$ capturing from industrial processes and storage in underground formations is emerging from commitments in reducing $CO_2$ emissions manifested in the Kyoto Protocol. In this paper, $CO_2$ liquefaction system is treated in focus of liquefaction efficiency & production rate. Presently $CO_2$ is transported in ships or trucks at a pressure of 14-20 bar. Considering this, the liquefaction pressures of 20, 15, 6.5 bar are selected. Compressor work and cooling capacity are calculated and compared. In order to investigate the effect of intercooling, the compressed gas after compressor work is cooled by ambient air or seawater. In case of applying the intercooling to the system, consuming energy can be saved larger than 20%. In the lower liquefaction pressure, the more $CO_2$ can be obtained due to higher density. In the liquefaction pressure of 6.5 bar, its $CO_2$ production is about 35% higher than that of the system with the liquefaction pressure, 20 bar.

• Transactions of the Korean hydrogen and new energy society
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• v.34 no.5
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• pp.549-554
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• 2023

In this paper, three kinds of studies have been completed to obtain highly purified carbon dioxide having more than 7N purity as an electronic grade quality. PRO/II with PROVISION release January 2023 from AVEVA company was used, and Peng-Robinson equation of the state model with Twu's alpha function was selected for the modeling of the cryogenic distillation process. When using LN2 cold heat, we can obtain highest recovery of carbon dioxide as a bottom product for a cryogenic distillation column.

• Korean Journal of Chemical Engineering
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• v.35 no.11
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• pp.2150-2156
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• 2018

We suggest a systematic method for obtaining the optimal compression ratio in the multi-stage closed-loop compression process of carbon dioxide. Instead of adopting the compression ratio of 3 to 4 by convention, we propose a novel approach based on mathematical analysis and simulation. The mathematical analysis prescribes that the geometric mean is a better initial value than the existing empirical value in identifying the optimal compression ratio. In addition, the optimization problem considers the initial installation cost as well as the energy required for the operation. We find that it is best to use the fifth stage in the general closed-loop type carbon dioxide multi-stage compression process.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.1
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• pp.135-144
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• 2021

In this study, we investigated the characteristics of the process of hydrogen production using boil-of gas (BOG) generated from an LNG-fueled ship and the application of hydrogen fuel cell systems as auxiliary engines. In this study, the BOG steam reformer process was designed using the UniSim R410 program, and the reformer outlet temperature, pressure, and the fraction and consumption of the product according to the steam/carbon ratio (SCR) were calculated. According to the study, the conversion rate of methane was 100 % when the temperature of the reformer was 890 ℃, and maximum hydrogen production was observed. In addition, the lower the pressure, the higher is the reaction activity. However, higher temperatures have led to a decrease in hydrogen production owing to the preponderance of adverse reactions and increased amounts of water and carbon dioxide. As SCR increased, hydrogen production increased, but the required energy consumption also increased proportionally. Although the hydrogen fraction was the highest when the SCR was 1.8, it was confirmed that the optimal operation range was for SCR to operate at 3 to prevent cocking. In addition, the lower the pressure, the higher is the amount of carbon dioxide generated. Furthermore, 42.5 % of the LNG cold energy based on carbon dioxide generation was required for cooling and liquefaction.