• Title/Summary/Keyword: Linear Shift

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A Study on the Corrosion Inhibition Effects of Sodium Heptanoate for Carbon Steel in Aqueous Solution

  • Won, D.S.;Kho, Y.T.
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.227-232
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    • 2004
  • The carboxylates as a corrosion inhibitor has been studied by many researchers because of its environmental safety and low depletion rate. However, conventional test methods of inhibitor such as weight loss measurements, linear polarization resistance and corrosion potential monitoring etc., evaluate uniform corrosion of metals. These methods are unable to evaluate crevice-related corrosions, which are encountered in most of heat exchanging facilities. In order to choose the optimum corrosion inhibitor, the appropriate test methods are required to evaluate their performances in service environment. From this point of view, polarization technique was used to evaluate the characteristics of sodium heptanoate on corrosion behavior for carbon steel. Especially a thin film crevice sensor technique were applied to simulate the crevice corrosion in this study. From these experiments, we found that oxygen as an oxidizing agent was required to obtain stable passive film on the metal. Presence of oxygen, however, accelerated crevice corrosion. Potential shift by oxygen depletion and weakened inhibitive film inside the crevice were responsible for such accelerated feature. It is shown that film for corrosion inhibition is a mixture of sodium heptanoate and iron (II) heptanoate as reaction product of iron surface and sodium heptanoate. The iron (II) heptanoate which has been synthesized by reaction of heptanoic acid and ferrous chloride in methanol solution forms bidentate complex.

Generalized Analysis on the Combined Effect of SPM and Fiber Chromatic Dispersion on Subcarrier Multiplexed Optical Transmission Systems for RoF Applications

  • Kim, Kyoung-Soo;Lee, Jae-Hoon;Jeong, Ji-Chai
    • Journal of the Optical Society of Korea
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    • v.15 no.2
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    • pp.132-139
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    • 2011
  • We investigate theoretically the combined effect of fiber chromatic dispersion and self-phase modulation (SPM) on multi-channel subcarrier multiplexed (SCM) optical transmission systems in terms of the detected RF carrier power and SPM-induced power gain after transmission over single-mode fiber (SMF) links. According to the calculated power gain due to the SPM effect at the transmission distance of P3dB using the detected radio-frequency (RF) carrier power after photo-detection, the power gain is significantly degraded with large optical modulation index (OMI), small SCM channel spacing, and large fiber launching power because of the increased interaction between subcarrier channels. The nonlinear phase shift due to linear and nonlinear fiber characteristics is investigated to explain these results in detail. The numerical simulation results show that the OMI per SCM channel has to be smaller than 10 % for the fiber launching power of 10 dBm to guarantee prevention of SPM-induced power gain degradation below 0.5 dB for the SCM system with the channel spacing of 100 MHz. This result is expected to be utilized for the optical transmission systems using the SCM technology in future radio-over-fiber (RoF) networks.

Direction of Intercalation of a bis-Ru(II) Complex to DNA Probed by a Minor Groove Binding Molecule 4',6-Diamidino-2-phenylindole

  • Jang, Yoon Jung;Kim, Raeyeong;Chitrapriya, Nataraj;Han, Sung Wook;Kim, Seog K.;Bae, Inho
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.2895-2899
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    • 2013
  • Direction of intercalation to DNA of the planar dipyrido[3,2-a:2',3'-c]phenazine ligands (dppz) of a bis-Ru(II) complex namely, $[Ru(1,10-phenanthroline)_2dipyrido[3,2-a:2^{\prime},3^{\prime}-c]phenazine]^{2+}$ linkered by a 1,3-bis(4-pyridyl)propane, was investigated by probing the behavior of 4',6-diamidino-2-phenylindole (DAPI) that bound deep in the minor groove. Bis-intercalation of DPPZ resulted in a little blue shift and hyperchromism in DAPI absorption band, and a large decrease in DAPI fluorescence intensity which accompined by an increase in the dppz emission intensity. Diminishing the intenisty of the positive induced circular dichroism (CD) and linear dichroism (LD) were also observed. These spectral changes indicated that insertion of dppz ligand caused the change of the binding mode of DAPI, which probably moved to the exterior of DNA from the minor groove and interacted with the phospghate groups of DNA by electrostatic interaction. At the surface of DNA, DAPI binds at the phosphate groups of DNA by electrostatic attraction. Consequently, this observation indicated that the dppz ligand intercalated from the minor groove.

Low Dimensional Multiuser Detection Exploiting Low User Activity

  • Lee, Junho;Lee, Seung-Hwan
    • Journal of Communications and Networks
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    • v.15 no.3
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    • pp.283-291
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    • 2013
  • In this paper, we propose new multiuser detectors (MUDs) based on compressed sensing approaches for the large-scale multiple antenna systems equipped with dozens of low-power antennas. We consider the scenarios where the number of receiver antennas is smaller than the total number of users, but the number of active users is relatively small. This prior information motivates sparsity-embracing MUDs such as sparsity-embracing linear/nonlinear MUDs where the detection of active users and their symbol detection are employed. In addition, sparsity-embracing MUDs with maximum a posteriori probability criterion (MAP-MUDs) are presented. They jointly detect active users and their symbols by exploiting the probability of user activity, and it can be solved efficiently by introducing convex relaxing senses. Furthermore, it is shown that sparsity-embracing MUDs exploiting common users' activity across multiple symbols, i.e., frame-by-frame, can be considered to improve performance. Also, in multiple multiple-input and multiple-output networks with aggressive frequency reuse, we propose the interference cancellation strategy for the proposed sparsity-embracing MUDs. That first cancels out the interference induced by adjacent networks and then recovers the desired users' information by exploiting the low user activity. In simulation studies for binary phase shift keying modulation, numerical evidences establish the effectiveness of our proposed MUDs exploiting low user activity, as compared with the conventional MUD.

A High-Power Step-up Converter with High Efficiency and Fast Control-to-Output Dynamics

  • Kang, Jeong-il;Roh, Chung-Wook;Moon, Gun-Woo;Youn, Myung-Joong
    • Journal of Power Electronics
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    • v.1 no.2
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    • pp.78-87
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    • 2001
  • A new high-power step-up based on the two-module parallel-input (PISO) modular dual inductor-fed push-pull converter is proposed. The proposed converter is operated at a constant duty cycle and employs and auxiliary circuit to control the output voltage with a phase-shift between two modules. It shows a high efficiency due to the greatly reduced switch turn-off stress. It also shows a high and linear voltage conversion ratio, low current stress in the output capacitor, and fast control-to-output dynamics. The operation principles and the mathematical models of the proposed converter are presented. Features of the proposed converter are discussed in comparison with the two-module PISO modular dual inductor-fed push-pull converter. Also, experimental results from a 50kHz, 800W, 350 Vdc prototype with an input voltage range of 20-32 Vdc are provided to confirm the validity of the proposed converter. The new converter compares favorably with the conventional counterpart, and is considered well siuted to high-power step-up applications.

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The injection-locking coupled oscillators for the active integrated phased array antenna (능동 위상배열 안테나를 위한 Injection-locking coupled oscillators)

  • 김교헌;이두한;류연국;이승무;오일덕;홍의석
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.21 no.9
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    • pp.2362-2372
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    • 1996
  • This paper deals with the design and development of an Injection-Locking Coupled Oscillators(ILCO), which functions like phase-shifter in the Active Intergrated Phased Array Antenna(AIPAA). This linear array 2-element ILCO consists of two Injection Locking Hair-pin Resonator Oscillators(ILHRO) and an unilateral amplifier. The first and second elements of the ILCO have same frequency tuning range but locking bandwidths of 11.5MHz and 14MHz respectively. A phase shift of .DELTA..PHI.=158.4.deg.(-78.0.deg. to 80.4.deg.) could be obtained inthe second element of ILCO when the first elementof the ILCO was in the reference locking mode(.DELTA..PHI.=0.deg.). When the ILCO is applied to the AIPAA, the predicted beam scanning angle value will be 38.4.deg.. Each ILCO gives good frequency stability and lower AM, FM, and PM noise charactheristics in the mutual coupling lockingmode. The ILCO can not only play a part as the phase shifter for the AIPAA but it can also be usedas the power combining device in the mm-wave frequency range and as a part of a T/R MMIC module.

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A Prony Method Based on Discrete Fourier Transform for Estimation- of Oscillation Mode in Power Systems (이산푸리에변환에 기초한 Prony 법과 전력계통의 진동모드 추정)

  • Nam Hae-Kon;Shim Kwan-Shik
    • The Transactions of the Korean Institute of Electrical Engineers A
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    • v.54 no.6
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    • pp.293-305
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    • 2005
  • This paper describes an improved Prony method in its speed, accuracy and reliability by efficiently determining the optimal sampling interval with use of DFT (discrete Fourier transformation). In the Prony method the computation time is dominated by the size of the linear prediction matrix, which is given by the number of data times the modeling order The size of the matrix in a general Prony method becomes large because of large number of data and so does the computation time. It is found that the Prony method produces satisfactory results when SNR is greater than three. The maximum sampling interval resulting minimum computation time is determined using the fact that the spectrum in DFT is inversely proportional to sampling interval. Also the process of computing the modes is made efficient by applying Hessenberg method to the companion matrix with complex shift and computing selectively only the dominant modes of interest. The proposed method is tested against the 2003 KEPCO system and found to be efficient and reliable. The proposed method may play a key role in monitoring in real time low frequency oscillations of power systems .

The Optical Measurement and Quantitative Analysis of Algesia in Spodoptera litura Larva

  • Chen, Ying-Yun;Chang, Rong-Seng;Tsai, Mi-Yin;Chen, Der-Chin
    • Journal of the Optical Society of Korea
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    • v.19 no.2
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    • pp.169-174
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    • 2015
  • Muscle vibration measurement has long been an unique scientific study, in general, and the direct reaction of animals to feel pain (algesia), either from vascular or muscle contraction, is a complex perceptual experience. Thus this paper proposes a way to measure animal algesia quantitatively, by measuring the changes in muscle vibration due to a pinprick on the surface of the skin of a Spodoptera litura larva. Using the laser optical triangulation measurement principle, along with a CMOS image sensor, linear laser, software analysis, and other tools, we quantify the subtle object point displacement, with a precision of up to $10{\mu}m$, for our chosen Spodoptera litura larva animal model, in which it is not easy to identify the tiny changes in muscle contraction dynamics with the naked eye. We inject different concentrations of formalin reagent (empty needle, 12% formalin, and 37% formalin) to obtain a variety of different muscle vibration frequencies as the experimental results. Because of the high concentrations of reagent applied, we see a high frequency shift of muscle vibration, which can be presented as pain indices, so that the algesia can be quantified.

Implementation of an LFM-FSK Transceiver for Automotive Radar

  • Yoo, HyunGi;Park, MyoungYeol;Kim, YoungSu;Ahn, SangChul;Bien, Franklin
    • IEIE Transactions on Smart Processing and Computing
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    • v.4 no.4
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    • pp.258-264
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    • 2015
  • The first 77 GHz transceiver that applies a heterodyne structure-based linear frequency modulation-frequency shift keying (LFM-FSK) front-end module (FEM) is presented. An LFM-FSK waveform generator is proposed for the transceiver design to avoid ghost target detection in a multi-target environment. This FEM consists of three parts: a frequency synthesizer, a 77 GHz up/down converter, and a baseband block. The purpose of the FEM is to make an appropriate beat frequency, which will be the key to solving problems in the digital signal processor (DSP). This paper mainly focuses on the most challenging tasks, including generating and conveying the correct transmission waveform in the 77 GHz frequency band to the DSP. A synthesizer test confirmed that the developed module for the signal generator of the LFM-FSK can produce an adequate transmission signal. Additionally, a loop back test confirmed that the output frequency of this module works well. This development will contribute to future progress in integrating a radar module for multi-target detection. By using the LFM-FSK waveform method, this radar transceiver is expected to provide multi-target detection, in contrast to the existing method.

Studies on the interaction of Azo dyes with cationic surfactant(1)

  • Cho, Yung-Mee;Lee, Wang-Kyu;Kim, Bak-Kwang
    • Archives of Pharmacal Research
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    • v.4 no.2
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    • pp.75-84
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    • 1981
  • As the cetyltrimenthy ammonium bromide (CTAB) concentration increases to $2{\times}10^{-4}$/M the absorption maximum of ethyl orange (EO) makes a blue shift from 475 mm to 395 mm. At higher concentration of CTAB than $2{\times}10^{-4}$ / M the absorption maximum shifts to higher wavelength than 395 nm. A new peak at 395 nm is shown to result from the mixed micelle due to dye stacking interaction rather than from a change in dye geometry. Because Raman spectra of EO on interaction with varying amount of CTAB are similar to that of EO in water. EO retains trans azo type on interaction with CTAB. There is a change of c.m.c.s. of CTAB for the mixed micelle in the presence of salt. The effect of added salt on C. M. C. of CTAB for the mixed micelle is given that the logarithm of the c. m. c. is a linear function of the logarithm of the sum of the c. m. c. and the concentration of added salt.

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