• Title/Summary/Keyword: Li-Polymer

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Effects of PEDOT:PSS Buffer Layer in a Device Structure of ITO/PEDOT:PSS/TPD/Alq3/Cathode

  • Ahn, Joon-Ho;Lee, Joon-Ung
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.1
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    • pp.25-28
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    • 2005
  • We have investigated the effects of hole-injection buffer layer in organic light-emitting diodes using poly(3,4-ethylenedioxythiophene):poly(stylenesulfonate)(PEDOT:PSS) in a device structure of $ITO/PEDOT:PSS/TPD/Alq_{3}/cathode$. Polymer PEDOT:PSS buffer layer was made by spin casting method. Current-voltage, luminance-voltage characteristics and efficiency of device were measured at room temperature with a variation of cathode materials; Al, LiF/Al, LiAl, and Ca/Al. The device with LiF/Al cathode shows an improvement of external quantum efficiency approximately by a factor of ten compared to that of Al cathode only device. Our observation shows that cathode is important in improving the efficiency of the organic light-emitting diodes.

Emission Property of Organic EL Device using Polyaniline Transparent Electrode (Polyaniline 투명전극을 사용한 유기EL 소자의 발광 특성)

  • 김주승;김대중;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.374-377
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    • 2001
  • We have synthesized poly(3-hexylthiophene)(P3HT), which is the most famous conducting polymer and studied the optical properties of P3HT. And then fabricated the device using P3HT as an emitting layer. For the improve of hole injection from ITO electrode to P3HT emitting layer, we use transparent polyaniline(PANI) electrode. In the voltage-current-luminance characteristics of ITO/PANI/P3HT/LiF/Al device which use the PANI film synthesised during 5 cycle, the device turn on at the 2V and the luminance of 218 nW/$\textrm{cm}^2$ obtained at 12V. External quantum efficiency of ITO/PANI/P3HT/LiF/Al increased at 8V than that of ITO/P3HT/LiF/Al device.

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A Simulation Study of the Performance of a Propulsion Equipment for Bimodal Tram (바이모달 트램의 추진장치 성능 모의)

  • Bae, Chang-Han;Mok, Jai-Kyun;Chang, Se-Ky;Lee, Kang-Won
    • Journal of the Korean Society for Railway
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    • v.12 no.1
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    • pp.122-128
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    • 2009
  • A bimodal low-floor tram is designed to provide the flexibility of bus and the punctuality of trains together to the passengers. The propulsion equipment of the bimodal tram is a series hybrid type using a set of CNG engine generator and Li-polymer battery. The present paper describes the specifications of the propulsion system in the bimodal tram which was drawn by a desirable driving cycle. In addition, it shows how the propulsion system of the bimodal tram can be controlled. With using a computer simulation tool of hybrid vehicles, ADVISOR, the performance of the bimodal tram was verified.

Study on the Analysis Technique of Accident Cause for Li-Polymer Battery (Li-Polymer 배터리 사고원인 분석기법에 관한 연구)

  • Lee, Ki-Yeon;Bang, Sun-Bae;Kim, Dong-Ook;Kim, Jae-Hyun;Park, Jin-Young;Park, Kwang-Muk
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1541-1542
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    • 2015
  • 본 논문에서는 휴대용 IT 기기 및 EV, ESS 등 사용이 급증하고 있는 리튬 폴리머 배터리의 화재사고 원인 분석기법에 대하여 나타내었다. 사고 원인 분석기법은 사례분석을 통하여 외형 및 탄화패턴 분석을 통한 발화 추정위치로 외력에 의한 사고 및 내부 절연 열화에 의한 사고 원인 분석 등을 나타내었다. 사고원인 분석은 배터리 안전성 확보와 사고 재발 방지를 위한 대책 마련에 필수적인 기술로 향후 증가하는 제품사고에 대한 분석기법 개발에 기초연구로 활용하고자 한다. 본 논문에서 제시한 분석기술과 향후 내부 절연 열화 원인 분석 기법을 개발하여 리튬 계열 배터리에서 발생하는 사고에 대하여 정확한 원인 분석에 활용할 것이다.

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Effect of Neutral Solvent on the Phase Behavior of Polystyrene-block-Poly(n-butyl methacrylate) Copolymers

  • Li, Chaoxu;Li, Guang-Hua;Moon, Hong-Chul;Lee, Dong-Hyun;Kim, Jin-Kon;Cho, Jun-Han
    • Macromolecular Research
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    • v.15 no.7
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    • pp.656-661
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    • 2007
  • The effects of a neutral solvent of dioctyl phthalate (DOP) on the phase behavior of symmetric polystyrene-block-poly(n-butyl methacrylate) copolymers (PS-b-PnBMA) were assessed herein. Closed-loop phase behavior with a lower disorder-to-order transition (LDOT) and an upper order-to-disorder transition (UODT) was observed for PS-b-PnBMA/DOP solution when the quantity of DOP was carefully controlled. When the molecular weight of PS-b-PnBMA became larger, the LDOT did not appreciably change at smaller quantities of DOP. With larger quantities of DOP, the reduction in the UODT is greater than the increase in the LDOT. This behavior is discussed in accordance with a molecular theory predicated on a compressible random-phase approximation.

Repair and Strengthening Methods for Concrete Structures using Sprayed Fiber Reinforced Polymers - Strengthening performance of Reinforced Concrete Shear Columns - (Sprayed FRP 공법에 의한 콘크리트 구조물의 보수.보강법 개발에 관한 연구 - 철근콘크리트 전단기둥의 보강성능 평가 -)

  • Lee, Kang-Seok;Byeon, In-Hee;Son, Young-Sun;Lee, Moon-Sung;Li, Cheng-Hao;Lee, Li-Hyung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.137-140
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    • 2006
  • In this study, a seismic performance of reinforced concrete columns strengthened by a sprayed fiber reinforced polymer (SFRP) is investigated. For this purpose, six column specimens approximately scaled into 2/3, are designed and tested under a constant axial load, 10% of the nominal axial strength of column, and pseudo-static reversed cyclic lateral loading system. Four specimens are strengthened by Sprayed FRP using different combinations of short fibers (carbon or glass fiber) and resins (epoxy or vinyl esther). For comparison, the test investigated in this study also includes a specimen strengthened using carbon fiber reinforced polymer (CFRP), and also a control specimen without strengthening. The results revealed that specimens strengthened using SFRP showed a improved structure behavior, compared to control specimen, in terms of strength, ductility, lateral drift capacity, and energy-absorbtion capacity. In addition, compared to the specimen strengthened using CFRP, Sprayed FRP-strengthened specimens reasonably showed a equivalent seismic performance.

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Properties of the Phosphorous Polymer Light Emitting Diodes with PVK:Ir(ppy)$_3$ Emission layer (PVK:Ir(ppy)$_3$ 발광부를 갖는 고분자 인광 발광다이오드의 특성평가)

  • Baek, Seung-Jun;Gong, Su-Cheol;Lee, Ho-Sub;Jang, Seong-Kyu;Chang, Ho-Jung
    • Proceedings of the KAIS Fall Conference
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    • 2010.05a
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    • pp.363-365
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    • 2010
  • 고분자 발광다이오드(polymer light emitting diode, PLED)는 초박막화, 초경량화가 가능하며 간단한 용액공정 으로 향후 휨성(flexible) 디스플레이로의 응용이 가능할 것으로 기대되고 있다. 본 연구에서는 녹색 고분자 유기 발광다이오드를 제작하고, 효율을 향상 시키고자 이중 발광층을 두어 전기 광학적 특성을 평가하였다. ITO/Glass기판 위에 정공주입층으로 PEDOT:PSS [poly(3,4-ethylenedio xythiophene):poly(styrene sulfolnate)]를 발광물질로는 형광 발광물질인 PVK(poly-vinylcarbazole)와 인광 발광 물질인 Ir(ppy)$_3$[tris(2-phenylpyridine) iridium(III)]를 각각 host와 dopant로 사용하였다. 정공 차단층 및 전자 수송층 두 개의 역할로 사용 가능한 TPBI(1,3,5-tris(2-N-phenylbenzimidazolyl) benzene)를 진공 열증착법으로 막을 형성하였다. 전자주입층으로 LiF(lithium flouride)와 음극으로 Al(aluminum)을 증착하여 최종적으로 ITO/PEDOT:PSS/PVK:Ir(ppy)$_3$/TPBI/LiF/Al 구조를 갖는 녹색 형광:인광 혼합 유기 발광 다이오드를 제작하였다.

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Axial behavior of square CFST encased seawater sea-sand concrete filled PVC/GFRP tube columns

  • Rong Su;Xian Li;Ziwei Li
    • Steel and Composite Structures
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    • v.47 no.6
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    • pp.781-794
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    • 2023
  • In order to directly apply seawater and sea sand in construction without desalination, a type of square concrete-filled steel tube (CFST) encased with prefabricated seawater sea-sand concrete filled Polyvinyl Chloride (PVC)/Glass Fiber Reinforced Polymer (GFRP) tube column was proposed. Twenty short columns were tested under uniaxial loads, and the test parameters included inner tube types, seawater sea-sand concrete replacement ratios, concrete strength, the wrapping area of Carbon Fiber Reinforced Polymer (CFRP) strips and the thickness of GFRP tube. The effects of the parameters on failure modes, loading capacity, ductility and strain responses were discussed. All the tested specimens failed with serious buckling of the steel tubes and fracture of the inner tubes. The specimens had good residual bearing capacity corresponding to 64% to 88.9% of the peak capacity. The inner GFRP tubes and PVC tubes wrapped by CFRP strips provided stronger confinement to the core concrete, and were good choices for the proposed columns. Moreover, an analytical model for the composite column with different inner tube types was proposed.

Effects of Organic Passivation Films on Properties of Polymer Solar Cells with P3HT:PC61BM Active Layers (유기 패시베이션 박막이 P3HT:PC61BM 활성층을 갖는 고분자 태양전지의 특성에 미치는 영향)

  • Lee, Sang Hee;Park, Byung Min;Cho, Yang Keun;Chang, Ho Jung;Jung, Jae Jin;Pyee, Jaeho
    • Journal of the Microelectronics and Packaging Society
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    • v.21 no.4
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    • pp.105-110
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    • 2014
  • It is required to improve the efficiency and the reliability of the polymer solar cells (PSCs) as the energy saving optical device for the future application of the smart farm facilities. In this study, we fabricated the bulk hetero junction PSCs with organic passivation film layer for the reliability improvement of the devices. The effects of the passivation layer on the electrical properties of the PSCs were studied. The materials of passivation layer are composed of poly vinyl alcohol (PVA) and ammonium dichromate, and the passivation films were fabricated by the spin coating method on the P3HT:$PC_{61}BM$/LiF/Al substrate. The prepared structure of the device is the glass/ITO/PEDOT:PSS/P3HT:$PC_{61}BM$/LiF/Al/passivation layer. The performances of the PSCs with the organic passivation film showed better electrical properties compared with the PSCs without passivation layers. The power conversion efficiency (PCE) values of passivated PSCs decreased from 3.0 to 1.3% after air exposure for 140 hrs. In contrast, the PCE values for the devices without passivation decreased sharply from 3.5 to 0.1% under the same exposure condition.

Preparation and Characterization of White Polymer Light Emitting Diodes using PFO:MEH-PPV (PFO:MEH-PPV를 이용한 White PLED의 제작과 특성평가)

  • Shin, Sang-Baie;Gong, Su-Choel;Park, Hyung-Ho;Jeon, Hyeong-Tag;Chang, Ho-Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.15 no.4
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    • pp.59-64
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    • 2008
  • In this paper, white polymer light emitting diodes(WPLEDs) were fabricated and investigated the electrical and optical properties for the prepared devices. ITO(indium tin oxide) and PEDOT:PSS [poly(3,4-ethylenedioxythiophene):poly(styrene sulfolnate)] as anode and hole injection materials, PFO [poly(9,9-dioctylfluorene)] and MEH-PPV [poly(2-methoxy-5(2-ethylhe xoxy)-1,4-phenylenevinyle)] were used as the light emitting host and guest materials, respectively. The LiF(lithium flouride) and Al(aluminum) were used electron injection materials and cathode materials. Finally, the WPLED with structure of ITO/PEDOT:PSS/PFO:MEH-PPV/LiF/Al was fabricated. The prepared WPLED showed white emission with CIE coordinates of (x=0.36, y=0.35) at the applied voltage of 9V. The maximum current density and luminance were about $740mA/cm^2\;and\;900cd/m^2$ at 13V, respectively. And the maximum current efficiency was 0.37 cd/A at $200cd/m^2$ in luminance.

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