• 한국가스학회지
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• 제19권4호
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• pp.22-28
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• 2015

LPG가 수송용 연료로서 경쟁력을 유지하기 위해서는 지속적인 기술개발을 통해 휘발유와의 연비격차를 감소시키고 후처리시스템 등에 의한 가격 부담을 낮추어야 한다. 이에 본 연구에서는 안정적인 희박연소 구현을 통한 연비개선을 얻기 위해 실린더 중앙에 점화플러그와 연료분사기가 인접해 있고, 연료가 분사된 후 바로 점화가 이루어지도록 하는 분무유도방식의 LPG 직접분사엔진을 개발의 일환으로 연소제어인자의 변화에 따른 연소 특성을 분석하였다. 안정적인 연소를 위해 국부적으로 농후한 혼합기를 형성하는 성층희박연소의 특성상 일정 수준이상의 질소산화물이 배출되는 문제점을 갖고 있다. 질소산화물 저감을 위해 EGR을 적용한 결과 연료소비율과 THC의 배출은 약간 증가하지만 $NO_x$배출은 약 15% 저감되었다. EGR 적용에 의한 연소속도의 감소는 초기 화염발달 시기에 집중되어 나타났으며 흡입공기의 희석효과에 의해 EGR율이 증가할수록 최대 열방출율 및 열방출율 증가 기울기가 감소하였다.

• 한국대기환경학회지
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• 제31권6호
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• pp.562-572
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• 2015

$NO_x$ emissions from diesel vehicles have been regarded as a main cause of high $NO_2$ concentration in metropolitan area. Recent studies have shown that the on-road $NO_x$ emissions of diesel vehicles are quite higher than the emission limits specified with the pre-defined test method for emission certification. To reduce air pollutants effectively, the discrepancy of emissions in certification and real-driving conditions should be tackled. In this study, the real-driving emissions have been estimated with portable emission measurement system (PEMS). The results of this study have shown that the on-road $NO_x$ emissions from diesel vehicles have been decreased as the introduction of stricter emission regulation, EURO-6, but additional reduction should be still required and robust technologies should be applied to control $NO_x$ in real-driving conditions. RDE-LDV (Real Driving Emission - Light Duty Vehicles) test method being developed in the European Union can represent excessive on-road $NO_x$ emissions of diesel vehicles as applied emission technologies and can be a solution to remove discrepant $NO_x$ emissions between certification and Korean real-driving conditions. Among the $NO_x$ reduction technologies for EURO-6 diesel vehicles, selective catalytic reduction (SCR) system has shown the better performance than lean $NO_x$ trap (LNT) system to control on-road $NO_x$ emissions. Implementing RDE-LDV will require vehicle manufacturers to adopt the more effective $NO_x$ reduction technology in real driving conditions.

• 한국자동차공학회논문집
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• 제14권3호
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• pp.170-177
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• 2006

Hydrogen can extend the lean misfire limit to a large extent when it is mixed with conventional fuels for a spark ignition engine. In this study, hydrogen-enriched gaseous fuels by reforming process were simulated according to their proportions of $H_2$, CO, $CO_2$ and $N_2$ gases. Pure hydrogen and two different hydrogen-enriched gaseous mixtures(A-, B-composition) were tested for their basic effects on the engine performances and emissions in a single cylinder research engine. A- and B-composition showed different results from 100% $H_2$ addition because air/fuel mixtures were more diluted by their additions. Even though the energy fraction of reformed gases was increased, combustion stabilities and lean misfire limits were not sensitively improved. It means that combustion augmentation by $H_2$ addition was offset by the charge dilution of $N_2$ and $CO_2$. In addition, the low flammability of CO gas deteriorated thermal efficiencies. CO emission was drastically increased with B-composition which included higher CO component. However, $NO_x$ was reduced as energy fraction($X_e$) rised except for the case of 100% $H_2$ addition at $\lambda=1.2$ and was, for A-composition, lowered to a factor of ten when compared with that of $H_2$ addition. HC emissions were largely influenced by $COV_{imep}$ due to misfire and partial burns.

• 한국대기환경학회지
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• 제12권2호
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• pp.131-139
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• 1996

The developent of ceramic combustor is being increased beca- use of the excellent physical properties of ceramic material, that is, high-resistant strength, high emissivity power and high corrosin-resistance. Ceramic combustor has been interested in the application of ultra-lean combustion for low NO$_{x}$ emission and gaseuos waste incineration with good combustion. This experimental study was conducted to investigate the combustion and emission characteristics of wall recess type ceramic combustor with equivalence ratio, mixture flow velocity and wall recess depth as parameters. The results in this study are as follows: 1. Wall recess played a important role to extend flame stability region. 2. The peak temperature of gas was peoportional to equivalence ratio, mixture flow velocity and wall recess depth. 3. The static pressure of mixing chamber and inlet temperature depended on the position of flame zone. 4. NO reduction was achieved by lean mixture without lower combustibility.y.

• 한국연소학회지
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• 제21권1호
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• pp.1-7
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• 2016

This study was performed to provide the basic information of the combustion, CO and $NO_X$ characteristics of biodiesel in accordance with equivalence ratio. The closed homogeneous reactor model used for the analysis. The analysis conditions were set to 900 K of the initial temperature, 20 atm of initial pressure and equivalence ratio was changes from 0.6 to 1.4. The results of analysis were predicted and compared in terms of combustion temperature, combustion pressure, CO and $NO_X$ emissions. The results of combustion characteristics showed that ignition delay was decreased and the combustion temperature and combustion pressure was increased in accordance with equivalence ratio. CO emission was decreased in lean condition(${\Phi}$ < 1.0), however, CO emission was increased in rich condition(${\Phi}$ > 1.0) because oxygen supply insufficient. $NO_X$ emission showed the largest amount in condition 0.8 of equivalence ratio because the oxygen concentration was sufficient.

• 대한기계학회논문집B
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• 제31권6호
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• pp.539-546
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• 2007

An experimental study was performed to investigate the characteristics of chemiluminescence in a radiant burner, varying the excess air ratio from 0.91 to 1.67 at firing rate 80.5 to 134.2 kW/m2 on $OH^*,\;CH^*,\;{C_2}^*$ in LNG-Air premixed flames. The signals from electronically excited states of $OH^*,\;CH^*,\;{C_2}^*$ were detected using a Intensified Couple Charged Detector (ICCD) camera. The measurements of exhausted emission were made to investigate the correlation between chemiluminescence and emissions. The chemiluminescence intensity was increased with increase of firing rate like characteristics of $NO_x$ emission. $NO_x$ also increased with increase of firing rate and excess air ratio. It is found that offset of firing rate is more dominant excess air ratio $NO_x$ emission. The maximum chemiluminescence intensity occurs near the stoichiometric excess air ratio or lean conditions in case of high firing rate and the maximum intensity occurs rather than rich conditions in case of relatively low firing rate. Amount of $NO_x$ emission is maximum at near stoichiometric excess air ratio, which is chemiluminescence intensity is maximum.

• 한국자동차공학회논문집
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• 제18권5호
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• pp.85-90
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• 2010

As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.

• 동력기계공학회지
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• 제10권3호
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• pp.5-10
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• 2006

In a conventional and lean operating engine, the state of mixture is very important in the combustion and emission characteristics. Lean operation is known to decrease the formation while maintaining a good fuel economy, but the unstable operation due to misfire and erratic combustion prevents engines from being operated at very lean mixtures, so both combustion rates and exhaust emission formation need to be satisfied comparably. In this study, it is designed and experimented the modified engine, and analyzed the combustion and exhaust emission according to the change of engine speed and with adding ozone. The conclusions were drawn out and enumerated as follows. 1. At the experimental result of automobile diesel engine, it has been verified that the formation of particulate matter(PM) gas is able to be lower with the addition of optimum quantities of ozone. 2. Carbon monoxide(CO) was formed by the lack of oxygen and the thermal dissociation in the combustion process. Therefore, with the change of swirl valve's position and addition of oxygen and ozone, CO formation was decreased by the increasing of excessive O2, but it was increased by the temperature of combustion gas growing higher. As a result of the two effects, CO formation was decreased in this study. 3. Hydrocarbon(HC) was formed by the lack of O2, and the flow of mixture in cylinder. According to opening of the swirl valve and adding the oxygen and ozone, hydrocarbon gas was decreased by 20%, 9%, and 27.5%, respectively. 4. Nitric oxides($NO_x$) was strongly affected by the combustion gas temperature. As a result of respectively experimental conditions, $NO_x$ formation was increased about 20% due to (be the) high(er) combustion gas temperature.

• 한국가스학회지
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• 제17권1호
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• pp.1-6
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• 2013

$NO_x$ 배출허용기준이 강화되는 배출가스 규제에 대응하기 위한 대안으로서 제시되는 천연가스-수소 혼합연료 (HCNG)는 수소의 빠른 화염속도와 넓은 가연범위를 이용하여 후처리 장치 없이 규제치를 만족할 수 있어 디젤엔진에 비해 저공해성이나 가격경쟁력 측면에서 유리한 장점이 있다. 열효율 측면에서도 우수성을 인정받는 HCNG 연료는 수소 혼합율은 물론 운전영역별 운전전략에 따라 연소특성이 달라진다. 본 연구에서는 대형 천연가스 엔진에 수소혼합율 30%의 HCNG 연료를 적용하여 운전영역별 안정적인 연소특성 및 배출가스 특성을 살펴봄으로써 상용화 가능성과 운전전략을 포함한 기술 개발방향에 대해 검토하고자 하였다.

• 한국연소학회지
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• 제20권2호
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• pp.40-45
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• 2015

This study is aimed to study combustion characteristics of low $NO_X$ burner using petroleum cokes as fuel. The petroleum coke, which is produced through the oil refining process, is an attractive fuel in terms of its high heating value and relatively low price. But petroleum coke is a challenging fuel because of its low volatile content, high sulfur and nitrogen content, which give rise to undesirable emission characteristics and low ignitability. The petroleum cokes burner is operated at fuel rich condition, and overfire air are supplied to achieve fuel lean condition. The low $NO_X$ burner is designed to control fuel and air mixing to achieve air staged combustion, in addition secondary and tertiary air are supplied through swirler. Air distribution ratio of triple staged air are optimized experimentally. The result showed that $NO_X$ concentration is lowest when overfire air is used, and the burner function at a fuel rich condition.