• Carbon letters
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• v.25
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• pp.43-49
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• 2018

This study suggests the novel thermoplastic toughening agent, which can be applied in the monomer forms without increasing the viscosity of the epoxy resin and polymerized during the resin curing. The diazide (p-BAB) and dialkyne (SPB) compounds are synthesized and mixed with the epoxy resin and the carbon fiber reinforced epoxy composites are prepared using vacuum infusion process (VIP). Then, flexural and drop weight tests are performed to evaluate the improvement in the toughness of the prepared composites to investigate the potential of the novel toughening agent. When 10 phr of p-BAB and SPB is added, the flexural properties are improved, maintaining the modulus as well as the toughness is improved. Even with a small amount of polytriazolesulfone polymerized, due to the filtering effect of the solid SPB by the layered carbon fabrics during the VIP, the toughening and strengthening effect were observed from the novel toughening agent, which could be added in monomer forms, p-BAB and SPB. This suggests that the novel toughening agent has a potential to be used for the composites prepared from viscosity sensitive process, such as resin transfer molding and VIP.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.137-140
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• 2005

Resin transfer molding (RTM) is one of the most popular processes for producing fiber reinforced polymer composites. In the manufacture of complex thick composite structures, analysis on flow front advancement on the resin impregnating the multi-layered fiber preform is helpful for the optimization of the process. In this study, three-dimensional mold filling simulation of RTM is carried out by using CVFEM (Control Volume Finite Element Method). On the assumption of isothermal flow of Newtonian fluid, Darcy’s law and continuity equation are used as governing equations. Different permeability tensors employed in each layer are obtained by experiments. Numerically predicted flow front is compared with experimental one in order to validate the numerical results. Flow simulations are conducted in the two mold geometries, rectangular plate and hollow cylinder. Permeability tensor of each layer preform in Cartesian coordinate system is transformed to cylinder coordinates system so that the flow within the multi-layered preforms of the hollow cylinder can be calculated exactly. Our emphasis is on the three dimensional flow analysis for circular three-dimensional braided preform, which shows outstanding mechanical properties such as high impact strength and toughness compared with other conventional two-dimensional laminar-structured preforms.

• Elastomers and Composites
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• v.54 no.4
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• pp.294-298
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• 2019

A three-layered PVC sheet consisting of polyvinyl chloride (PVC) and woven polyester fabric was prepared by extrusion and calendering. The flexibility and durability of the PVC were tuned by adding plasticizers, additives, and surface coatings. The tensile and tear strengths of the three-layered PVC sheet were higher than those of commercial two-layered sheet, while exhibiting low weight. The concentrations of the total volatile organic compounds (TVOCs) and formaldehyde (HCHO) emitted from the sheet were also lowered. The PVC sheet remained stable after prolonged exposure to UV light, signifying that the PVC sheet is suitable for cargo screen applications.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.12 no.3
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• pp.144-148
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• 2002

Hydroxyapatite/titanium composites were prepared as 4-layered functionally graded materials (FGM) using a spark plasma sintering (SPS) apparatus. The maximum density and the biaxial strength of hydroxyapatite/titanium composites were achieved by SPS with a holding time 8 minutes at $1200^{\circ}C$. However, the hydroxyapatite was decomposed tetracalcium phosphate (TetCP) at $1100^{\circ}C$, and calcium titanate compounds ($CaTiO_3$) were formed. When titanium was added to hydroxyapatite, decomposition of hydroxyapatite was occurred easily at the low temperature.

• Ceramist
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• v.9 no.6
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• pp.18-23
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• 2006

In this article, the present activities regarding research and development of continuous SiC fiber reinforced ceramic matrix composites (CFCC) in Japan are reviewed. The key technologies in SiC fiber composites are interphase between fiber and matrix and its oxidation resistance. To improve oxidation resistance of interphase, various kinds of technologies such as environment barrier coating, high dense matrix, unti-oxidation matrix, multi-layered intephase have been developed. It is suggested that high performance, affordable processing cost, and excellent reliability will be important factors to be in practical use of CMCs in future.

• Carbon letters
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• v.11 no.4
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• pp.293-297
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• 2010

To investigate new potential application of a clay material for C/C composites, illite added C/C composites were prepared with various illite contents. The improvement of filler effect by illite size reduction was also investigated using wet ballmilling by evaluating illite/phenolic resin infiltration using bulk density and porosity measurements, chemical structural changes of the composites using XRD, and thermal oxidation stability in air of the composites using TGA. The size reduction of illite resulted in narrower particle size distribution and improved illite infiltration into carbon preform. And the resultant C/C composites prepared with illite had even more improved thermal oxidation stability in air, showing more increased IDTs up to $100^{\circ}C$, compared to those of the C/C composites with pristine illite, due to the SiC formation through carbothermal reduction between illite and carbon materials. The illite induced delay in oxidation of the illite-C/C composites was also observed and the delayed oxidation behavior was attributed to the layered structure of illite, which improved illite/phenol resin infiltration. Therefore, the potential use of illite as filler to improve oxidation stability of C/C composite can be promising. And the size reduction of illite can improve its effect on the desired properties of illite-C/C composites even more.

• Journal of Sensor Science and Technology
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• v.24 no.3
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• pp.181-187
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• 2015

The magnetoelectric characteristics on layered $Fe_{78}B_{13}Si_9/PZT$ and $Fe_{78}B_{13}Si_9/PZT/Fe_{78}B_{13}Si_9$($t_m=0.017$, 0.034mm) composites by epoxy bonding for magnetic field sensor were investigated in the low-frequency range and resonance frequency range. The optimal bias magnetic field $H_{dc}$ of these samples was about 23~63 Oe range. The Me coefficient of $Fe_{78}B_{13}Si_9/PZT/Fe_{78}B_{13}Si_9(t_m=0.034mm)$ composites reaches a maximum of $186mV/cm{\cdot}Oe$ at $H_{dc}=63Oe$, f=50 Hz and a maximum of $1280mV/cm{\cdot}Oe$ at $H_{dc}=63Oe$, resonance frequency $f_r=95.5KHz$. The output voltage shows linearity proportional to ac fields $H_{ac}$ and is about U=0~130.6 mV at $H_{ac}=0{\sim}7Oe$, f=50 Hz, U=0~12.4 V at $H_{ac}=0{\sim}10Oe$, $f_r=95.5KHz$(resonance frequency). The optimal frequency(f=50 Hz) of this sample is around the utility ac frequency(f=60 Hz). Therefore, this sample will allow for ac magnetic field sensor at utility frequency and low bias magnetic fields $H_{dc}$.

• Journal of the Korea institute for structural maintenance and inspection
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• v.24 no.1
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• pp.108-115
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• 2020

In this study, the flexural performance of Highly Ductile Cement Composites(HDCC) mimicking boundary conditions of shellfish skin layer was evaluated. To improve ductility by mimicking the boundary skin layer structure of shellfish, the method of stratification by charging between precast panels using HDCC and the method of distributing PE-mesh to the interface surface were applied. Evaluation of flexural performance of layered cement composite materials mimicking boundary conditions of shellfish skin layer resulted in increased ductility of all test specimens applied with stratified cross-section compared to typical bending test specimens. The layered method by inserting PE-mesh showed excellent ductility. This is most likely because the inserted PE-mesh made an interface for separating the layers while the HDCC pillars in the PE-mesh gave adhesion between layers.

• Journal of Electrochemical Science and Technology
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• v.15 no.3
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• pp.321-344
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• 2024

Transition metal compounds (TMCs) are being researched as promising electrode materials for electrochemical energy storage devices (supercapacitors). Among TMCs, transition metal phosphates (TMPs) have good, layered structures owing to open framework and protonic exchange capability among different layers, good surface area due to engrossed porosity, rich active redox reaction sites owing to octahedral structure and variable valance metallic ions. Hence TMPs become more ideal for supercapacitor electrode materials compared to other TMCs. However, TMPs have got some issues like low conductivity, rate performance, stability, energy, and power densities. But these problems can be addressed by making their composites with carbonaceous materials, e.g., carbon nanotubes (CNTs), graphene oxide (GO), graphitic carbon (GC), etc. A few factors like high surface area, excellent electrical conductivity of carbon materials and variable valence metal ions in TMPs caused great enhancement in their electrochemical performance. This article tries to discuss and compare the published data, majorly in last decade, regarding the electrochemical energy storage potential of pristine unary, binary, and ternary TMPs and their hybrid composites with carbonaceous materials (CNTs, GOs/rGOs, GC, etc.). The electrochemical performance of the hybrids has been reported to be higher than the pristine counterparts. It is hoped that the current review will open a new gateway to study and explore the high performance TMPs based supercapacitor materials.

• Carbon letters
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• v.12 no.2
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• pp.116-119
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• 2011

C/SiC composites were prepared by boron nitride (BN)-assisted liquid silicon infiltration (LSI), and their anti-oxidation and mechanical properties were investigated. The microstructures, bulk densities, and porosities of the C/SiC composites demonstrated that the infiltration of liquid silicon into the composites improved them, because the layered-structure BN worked as a lubricant. Increasing the amount of BN improved the anti-oxidation of the prepared C/SiC composites. This synergistic effect was induced by the assistance of BN in the LSI. More thermally stable SiC was formed in the composite, and fewer pores were formed in the composite, which reduced inward oxygen diffusion. The mechanical strength of the composite increased up to the addition of 3% BN and decreased thereafter due to increased brittleness from the presence of more SiC in the composite. Based on the anti-oxidation and mechanical properties of the prepared composites, we concluded that improved anti-oxidation of C/SiC composites can be achieved through BN-assisted LSI, although there may be some degradation of the mechanical properties. The desired anti-oxidation and mechanical properties of the composite can be achieved by optimizing the BN-assisted LSI conditions.