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Korean Carbon Society (한국탄소학회)
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New Application of Clay Filler for Carbon/Carbon Composites and Improvement of Filler Effect by Clay Size Reduction

  • Jeong, Eui-Gyung (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E2M, Chungnam National University) ;
  • Kim, Jin-Hoon (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E2M, Chungnam National University) ;
  • Lee, Young-Seak (Department of Fine Chemical Engineering and Applied Chemistry, BK21-E2M, Chungnam National University)
  • Received : 2010.08.14
  • Accepted : 2010.11.23
  • Published : 2010.12.30
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Abstract

To investigate new potential application of a clay material for C/C composites, illite added C/C composites were prepared with various illite contents. The improvement of filler effect by illite size reduction was also investigated using wet ballmilling by evaluating illite/phenolic resin infiltration using bulk density and porosity measurements, chemical structural changes of the composites using XRD, and thermal oxidation stability in air of the composites using TGA. The size reduction of illite resulted in narrower particle size distribution and improved illite infiltration into carbon preform. And the resultant C/C composites prepared with illite had even more improved thermal oxidation stability in air, showing more increased IDTs up to $100^{\circ}C$, compared to those of the C/C composites with pristine illite, due to the SiC formation through carbothermal reduction between illite and carbon materials. The illite induced delay in oxidation of the illite-C/C composites was also observed and the delayed oxidation behavior was attributed to the layered structure of illite, which improved illite/phenol resin infiltration. Therefore, the potential use of illite as filler to improve oxidation stability of C/C composite can be promising. And the size reduction of illite can improve its effect on the desired properties of illite-C/C composites even more.

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References

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