• Title/Summary/Keyword: Lattice strain

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Nanopatterned Surface Effect on the Epitaxial growth of InGaN/GaN Multi-quantum Well Light Emitting Diode Structure

  • Kim, Keun-Joo
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.40-43
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    • 2009
  • The authors fabricated a nanopatterned surface on a GaN thin film deposited on a sapphire substrate and used that as an epitaxial wafer on which to grow an InGaN/GaN multi-quantum well structure with metal-organic chemical vapor deposition. The deposited GaN epitaxial surface has a two-dimensional photonic crystal structure with a hexagonal lattice of 230 nm. The grown structure on the nano-surface shows a Raman shift of the transverse optical phonon mode to $569.5\;cm^{-1}$, which implies a compressive stress of 0.5 GPa. However, the regrown thin film without the nano-surface shows a free standing mode of $567.6\;cm^{-1}$, implying no stress. The nanohole surface better preserves the strain energy for pseudo-morphic crystal growth than does a flat plane.

Sticking Characteristics in BiSrCaCuO Thin Film Fabricated by Layer-by-Layer Sputtering Method (순차 스퍼터법으로 제작한 BiSrCaCuO 박막의 부착 특성)

  • Cheon, Min-Woo;Park, Yong-Pil;Kim, Jeong-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05d
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    • pp.45-48
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    • 2003
  • BiSrCaCuO thin films were fabricated by atomic layer-by-layer deposition using an ion beam sputtering method. 10 wt% and 90 wt% ozone mixed with oxygen were used with ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition, two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit, then three dimensional growth takes place. Since Cu element is the most difficult to oxidize, only Sr and Bi react with each other predominantly, and forms a buffer layer on the substrate in an amorphous-like structure, which is changed to $SrBi_2O_4$ by in-situ anneal.

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A Study on the Intrinsic Degradation Behavior of LaNi5 (LaNi5의 intrinsic degradation 거동에 관한 연구)

  • Ahn, Hyo-Jun;Lee, Jai-Young
    • Transactions of the Korean hydrogen and new energy society
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    • v.2 no.1
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    • pp.77-82
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    • 1990
  • To investigate the effect of strains heat effect and thermal energy on the intrinsic degradation of $LaNi_5$, the changes of P-C-Isotherm curves under the condition of mainly applied one of the above factors were investigated. The revesible hydrogen storage capacity decreased by means of the hydrogenation at high temperature without cyclings or pressure induced cyclings with low thermal energy. The degree of degradation was more severe as the heat of hydrogenation reaction increased. Thus the intrinsic degradation of $LaNi_5$ depended upon lattice strain as well as thermal energy.

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Effect of ion implanted sapphire substrates for GaN (GaN 성장을 위한 이온 주입된 사파이어 기판의 효과)

  • 이재석;진정근;강민구;노대호;성윤모;변동진
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.170-170
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    • 2003
  • We have implanted on sapphire substrate with various ions and investigated the properties of GaN epilayers grown on implanted sapphire substrate by metal organic chemical vapor deposition (MOCVD). Sapphire is typical substrate for GaN epilayers. However, there are many problems such as lattice mismatch and thermal coefficient difference between sapphire substrate and GaN. The ion implanted substrate's surface had decreased internal tree energies during the growth of the GaN epilayer, md the misfit strain was relieved through the formation of an AlN phase on the ions implanted sapphire(0001) substrates. [1] The crystal and optical properties of GaN epilayer grown in ions implanted sapphire(0001) substrate were improved.

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Growth and characterization of ZnSe/GaAs epilayer by hot-wall epitaxy method (Hot-Wal Epitaxy 방법에 의한 ZnSe/GaAs 박막 성장과 특성)

  • 정태수;강창훈;유평렬
    • Journal of the Korean Vacuum Society
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    • v.8 no.3B
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    • pp.302-307
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    • 1999
  • We have grown a high quality ZnSe(100) epilayer on the GaAs(100) substrate by hot-wall epitaxy method. The FWHM value from double-crystal x-ray diffraction rocking curve and growth rate of the ZnSe epilayer grown under the optimal growth conditions were 195 arcsec and 0.03 $\mu \textrm m$/min, respectively. The $I_2^U$ and $I_2^L$ peaks, which split by strain due to lattice mismatch between substrate and epilayer, were measured from the photoluminescence experiment. And we found that the residual impurities in ZnSe epilayer were concerned with Al or CI elements from the calculated binding energy of donor impurity.

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Biosynthesis of Silver Nanoparticles by Phytopathogen Xanthomonas oryzae pv. oryzae Strain BXO8

  • Narayanan, Kannan Badri;Sakthivel, Natarajan
    • Journal of Microbiology and Biotechnology
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    • v.23 no.9
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    • pp.1287-1292
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    • 2013
  • Extracellular biogenic synthesis of silver nanoparticles with various shapes using the rice bacterial blight bacterium Xanthomonas oryzae pv. oryzae BXO8 is reported. The synthesized silver nanoparticles were characterized by UV-Vis spectroscopy, powder X-ray diffractometry (XRD), scanning electron microscopy, energy dispersive X-ray spectrometry, and high-resolution transmission electron microscopy (HR-TEM). Based on the evidence of HR-TEM, the synthesized particles were found to be spherical, with anisotropic structures such as triangles and rods, with an average size of 14.86 nm. The crystalline nature of silver nanoparticles was evident from the bright circular spots in the SAED pattern, clear lattice fringes in the high-resolution TEM images, and peaks in the XRD pattern. The FTIR spectrum showed that biomolecules containing amide and carboxylate groups are involved in the reduction and stabilization of the silver nanoparticles. Using such a biological method for the synthesis of silver nanoparticles is a simple, viable, cost-effective, and environmentally friendly process, which can be used in antimicrobial therapy.

Residual Stress Measurement on Welded Specimen by Neutron Diffraction (중성자 회절을 이용한 용접부위의 잔류응력 측정)

  • 박만진;장동영;최희동
    • Journal of Welding and Joining
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    • v.20 no.2
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    • pp.50-58
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    • 2002
  • Residual stress is generated in the structures as a result of irregular elastic-plastic deformation during fabrication processes such as welding, heat treatment, and mechanical processing. There are several factors attributed to the origin of residual stresses, tensile or compressive. The stresses can be determined by destructive ways or nondestructive ways using X-ray or neutron diffraction. Although X-ray diffraction is a well established technique, it is practically limited to near-surface stresses. Neutrons penetrate easily into most materials and neutron diffraction permits non-destructive evaluation of lattice strain within the bulk of large specimens because the radiation is more deeply penetrating for metallic engineering components. This paper presented application of neutron diffraction technique to the residual stress measurement using 20 mm thick welded stainless steel plate($100{\times}100 \textrm{mm}^2$)

Growth of Zn-chalcogenide epilayers by hot-wall epitaxy and their structural properties (Hot-wall epitaxy에 의한 Zn-chalcogenide 에피층의 성장 및 구조적 특성)

  • 유영문;남성운;이종광;오병성;이기선;최용대;이종원
    • Journal of the Korean Vacuum Society
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    • v.8 no.4A
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    • pp.470-475
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    • 1999
  • ZnS and ZnTe epilayers were grown on GaAs(100) GaP(100) substrates by hot-wall eitaxy. X-ray diffraction revealed that the epilayers have zinc-blende structure and were grown in (100) direction. The small values of the full width at half maximum (FWHM) of double crystal rocking curve (DCRC) showed high quality of the epilayers. From the thickness dependence of the FWHM of DCRC, the strain remaining in films is found to be due to the thermal expansion difference as well as due to the lattice mismatch.

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Engineering Characteristics of Horizontal Drainage for Stabilization of Dredged Fill (준설매립지반의 안정처리를 위한 수평배수재의 공학적 특성)

  • 이상호;박정용;장연수;박정순;김수삼
    • Proceedings of the Korean Geotechical Society Conference
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    • 2001.03a
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    • pp.563-570
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    • 2001
  • In this study, the charactersistics of horizontal drains used to stabilize the dredged fill are investigated experimentally by doing tensile strength test, discharge capacity test, and filter clogging test. The types of the drains selected for the study are filament type (Tyre-E), embossed type(Type-P) and heat bonded cubic type with the thickness 10mm(Type-010) and 5mm(Type-05). The results of tensile strength and discharge capacity test show that the performance of drain Type-O10 was better than the other drains. This is caused by the fact that the lattice shape core of drain Type-O10 has strong rigidity and minimizes the loss of the sectional area of discharge with increased confining pressure. Analyzing the compatibility of filters by the results of the strength characteristics test and clogging test, the filter of filament type drain produced with polyester clothed polyamide performed well.

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A Study on the Epitaxial Growth of Superconducting Thin Film (초전도 박막의 에피택셜 성장에 관한 연구)

  • Lee, Hee-Kab;Park, Yong-Pil;Kim, Gwi-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.208-211
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    • 2002
  • $Bi_2Sr_2CuO_x$(Bi-2201) thin films were fabricated by atomic layer-by-layer deposition using an ion beam sputtering method. 10 wt% and 90 wt% ozone mixed with oxygen were used with ultraviolet light irradiation to assist oxidation. At early stages of the atomic layer by layer deposition, two dimensional epitaxial growth which covers the substrate surface would be suppressed by the stress and strain caused by the lattice misfit, then three dimensional growth takes place. Since Cu element is the most difficult to oxidize, only Sr and Bi react with each other predominantly, and forms a buffer layer on the substrate in an amorphous-like structure, which is changed to $SrBi_2O_4$ by in-situ anneal.

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