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Effect of metal conditioner on bonding of porcelain to cobalt-chromium alloy

  • Minesaki, Yoshito;Murahara, Sadaaki;Kajihara, Yutaro;Takenouchi, Yoshihisa;Tanaka, Takuo;Suzuki, Shiro;Minami, Hiroyuki
    • The Journal of Advanced Prosthodontics
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    • v.8 no.1
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    • pp.1-8
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    • 2016
  • PURPOSE. The purpose of this study was to evaluate the efficacy of two different metal conditioners for non-precious metal alloys for the bonding of porcelain to a cobalt-chromium (Co-Cr) alloy. MATERIALS AND METHODS. Disk-shaped specimens ($2.5{\times}10.0mm$) were cast with Co-Cr alloy and used as adherend materials. The bonding surfaces were polished with a 600-grid silicon carbide paper and airborne-particle abraded using $110{\mu}m$ alumina particles. Bonding specimens were fabricated by applying and firing either of the metal conditioners on the airborne-particle abraded surface, followed by firing porcelain into 5 mm in diameter and 3 mm in height. Specimens without metal conditioner were also fabricated. Shear bond strength for each group (n=8) were measured and compared (${\alpha}=.05$). Sectional view of bonding interface was observed by SEM. EDS analysis was performed to determine the chemical elements of metal conditioners and to determine the failure modes after shear test. RESULTS. There were significant differences among three groups, and two metal conditioner-applied groups showed significantly higher values compared to the non-metal conditioner group. The SEM observation of the sectional view at bonding interface revealed loose contact at porcelain-alloy surface for non-metal conditioner group, however, close contact at both alloy-metal conditioner and metal conditioner-porcelain interfaces for both metal conditioner-applied groups. All the specimens showed mixed failures. EDS analysis showed that one metal conditioner was Si-based material, and another was Ti-based material. Si-based metal conditioner showed higher bond strengths compared to the Ti-based metal conditioner, but exhibited more porous failure surface failure. CONCLUSION. Based on the results of this study, it can be stated that the application of metal conditioner is recommended for the bonding of porcelain to cobalt-chromium alloys.

Flow behavior characteristics according to superficial gas velocity of NiO/MoO3/MoS2 (NiO/MoO3/MoS2의 공탑속도에 따른 유동화 특성)

  • Lee, Jae-Rang;Hasolli, Naim;Jeon, Seong-Min;Lee, Kang-San;Lee, Kwan-Young;Kim, Kwang-Deuk;Park, Young-Ok
    • Particle and aerosol research
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    • v.13 no.2
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    • pp.79-85
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    • 2017
  • This study identified the loss of minimum fluidization velocity and pressure in accordance with the superficial velocity of $NiO/MoO_3/MoS_2$, a rare metallic oxide and high value-added material in the lab-scale fluidized bed reactor (L=0.25 m, D=0.05 m). The average pressure loss in L/D 1, 2, and 3 of $NiO/MoO_3/MoS_2$ within the scope of superficial gas velocity between 0.07 and 0.45 m/s based on the L/D 1, 2, and 3 of the specimen was shown to be 290~1952 Pa at decreasing flux and 253~1925 Pa at increasing flux. The comparison between the theoretical value proposed by Wen and the test data showed a difference between 0.021~0.36 magnification. Based on these results, this study was able to determine the operation conditions where rare metallic oxides could be applied in real phenomena.

Estimation of PM2.5 Correction Factor for Optical Particle Counter in Ambient Air (대기환경에서 광산란 미세먼지 측정기의 PM2.5 보정계수 산정)

  • Kim, Jong Bum;Kim, Danbi;Noh, Sujin;Yoon, Kwan Hoon;Park, Duckshin;Lee, Jeong Joo;Kim, Jeongho
    • Particle and aerosol research
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    • v.16 no.2
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    • pp.49-59
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    • 2020
  • Various devices have been developed to the measurement of particulate matter pollutants, and Optical Particle Counter (OPC) that can be easily and quickly measured is widely used lately. The measured value by OPC is converted to weight concentration using the correction factor (CF). The calculation of CF is very important to improve the reliability and accuracy of OPC. In this study, the CF calculation study of light scattering laser photometer (model 8533, TSI) was carried out to measure in the atmospheric environment using 2 gravimetric devices and 3 light scattering laser photometer devices. Regression analysis and Tukey tests were used to significance the test of measurement devices. Measurements were carried out twice. There was a comparative analysis of measurement data between light scattering laser photometer and gravimetric devices in 1st measurement, and then the Evaluation of PM2.5 concentration corrected by CF performed in 2nd measurement. As a result of the significance analysis between light scattering laser photometer and gravimetric devices, the correlation between the same method was high, but the correlation between different methods was low. CF was calculated as 0.4258 based on the measurement results, and it is a similar level to previous studies at home and abroad. It is expected that these results can be used as basic data in the future study for air quality measurement research using light scattering laser photometer. Also, in order to improve the accuracy of the measurement techniques and the development of technology in the atmospheric environment, CF calculation research should be conducted continuously.

Concentration of Polycyclic Aromatic Hydrocarbons in Cereals, Pulses, Potatoes, and their Products (곡류, 두류, 서류 및 그 가공품 중 다환 방향족 탄화수소 (polycyclic aromatic hydrocarbons) 화합물 함량)

  • Kim, Hee-Yun;Chung, So-Young;Sho, Yo-Sub;Park, Seong-Soo;Lee, Eun-Ju;Suh, Jung-Hyuk;Lee, Yun-Dong;Choi, Woo-Jeong;Kim, Jung-Soo;Eom, Ji-Yoon;Park, Hui-Og;Jin, Myeong-Sig;Kim, Dong-Sul;Ha, Sang-Chul;Lee, Jong-Ok
    • Korean Journal of Food Science and Technology
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    • v.37 no.4
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    • pp.537-541
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    • 2005
  • Estimation of concentrations of PAHs [benzo(a)anthracene, chrysene, benzo(b)fluoranthene, benzo(k)fluoranthene, benzo(a)pyrene, dibenzo(a,h)anthracene, benzo(g,h,i)perylene, indeno(1,2,3-c,d)pyrene] in cereals, pulses, potatoes, and their products available in Korean markets gave mean levels of 0.13, 0.08, 0.06, 0.03, 0.08, 0.15, 0.45, and $0.14{\mu}g/kg$, respectively, with recoveries between 82.6-106.6%. Methodology involved saponification and extraction with n-hexane, purification on Sep-Pak Florisil cartridges, and high performance liquid chromatography using a fluorescence detector.

Experimental Study on Generating mechanism of The Ground Subsidence of Due to Damaged Waters supply Pipe (상수관로 파손으로 인한 지반함몰 발생메카니즘에 관한 실험적 연구)

  • Kim, Youngho;Kim, Joo-Bong;Kim, Dowon;Han, Jung-Geun
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.2
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    • pp.139-148
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    • 2017
  • Ground subsidence caused by damaged water pipe and sewer is recently increasing due to the aging of city and pipeline in many city. Although many recent studies have verified characteristics of ground subsidence due to wastewater pipe breakdown, research about characteristics of ground subsidence due to water pipe is insignificant. subsidence due to water pipe is insignificant. This study aims to identify the ground failure mechanism caused by water and sewer pipe breakdown. Accordingly, we conducted an indoor model experiment to verify characteristics of ground subsidence considering characteristics of ground and ground failure. The water pipe pressure and velocity head was considered to find out ground subsidence mechanism. Also comparative analysis is conducted by analyzing relative density and fine-grain content considering embedded condition of water pipe. When the relative density and seepage pressure is low, small scale ground subsidence can occur, but when the conditions are opposite, ground subsidence occur in large scale and expands to ground level over time. Furthermore, it is acknowledgeable that ground cavity that is formed after soil run off due to seepage in deep earth, maintains steady strength and stays on the ground level for long period.

A Study of the Aging Properties of the Common Synthetic Resin Adhesives for Paper Conservation Purposes (시판용 접착제의 지류보존처리 적합성 판단을 위한 열화 특성 연구)

  • Sung, Yeonsim;Youm, Inkyung
    • Journal of Conservation Science
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    • v.28 no.4
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    • pp.387-394
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    • 2012
  • Most of the libraries and archives that lacks conservation lab facilities, frequently apply common synthetic resin adhesives such as PVAc group(Pa), acrylic group(Ac) and PVP group(Pv) on simple repairs. The archival quality synthetic adhesive(Pa-1) that is used at the National Library of Korea and the common synthetic resin adhesives were selected for the experiments. Accelerated aging test was applied on the adhesive samples and change of the pH and chromaticity were measured for one month. As the result of the pH mesurments, Pa-1 and Ac-2 were at the acceptable pH range. As the result of the chromaticity mesurments, degree of yellowing(${\Delta}b^*$) showed smaller change to greater change in the following order; Pa-1

Development of State of Charge and Life Cycle Evaluation Algorithm for Secondary Battery (이차전지의 상태 감시 및 수명 예측 알고리즘 개발)

  • Park, Jaebeom;Kim, Byeonggi;Song, Seokhwan;Rho, Daeseok
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.1
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    • pp.369-377
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    • 2013
  • This paper deals with the state of charge(SOC) and life cycle evaluation algorithm for lead-acid battery, which is essential factor of the electric vehicle(EV) and the stabilization of renewable energy in the smart grid. In order to perform the effective operation of the lead-acid battery, SOC and life cycle evaluation algorithm is required. Specific gravity with the change of electrolyte temperature inside battery case should be obtained to evaluate the SOC of lead-acid battery, however it is difficult to measure the electrolyte temperature of sealed type lead-acid battery. To overcome this problem, this paper proposes the equation of thermal transmission to compensate internal temperature of the lead-acid battery. Also, it is difficult to exactly evaluate the life cycle of battery, depending on the operation conditions of lead-acid battery such as charging and discharging state, self discharging rate and environmental issue. In order to solve the problem, this paper presents the concept for gravity accumulation of charge and discharge cycle, which is the value converted at $20^{\circ}C$. By using the proposed algorithm, this paper propose the test device based on the Labview software. The simulation results show that it is a practical tool for the maintenance of lead-acid battery in the field of industry.

A Quality Comparison of Traditional Korean Papers: Mixtures of Bast-Fiber with Straw pulp(Rice straw paper) in Different Composition Ratio (고정(藁精) 혼합비율에 따른 한지의 물성 비교)

  • Jung, Sun-Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.1 s.119
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    • pp.48-55
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    • 2007
  • The aim of this article is to review the general property of the famous traditional Korean paper, "rice straw paper"(Bast-Fiber mixed with straw pulp), and to compare the paper qualities varying with the composition ratio of straw pulp, in order to revive the traditional paper in modem Korea. The experiment was carried out by making first the two different mixture papers, i. e., one is the paper of 50% bast fiber mixed with 50% straw pulp, and the other is the paper of 75% bast fiber with 25% oats straw pulp, and finally the 100% bast fiber paper was made for the purpose of comparison. The qualitative properties of these three kinds of paper with the different mixing ratio of the straw pulp were evaluated, and the findings of the experiment can be summarized as follow: 1. As to the quality aspects of the paper strength like tensile strength, breaking length, elongation, and tear strength, the test proved the 100% bast fiber paper as best, and the 50% mixed paper as the next good one. 2. In aspect of the printing adaptability such as density, opacity, brightness, whiteness, lab colors, air permeability, and roughness, the 50% mixed paper proved to be the best, due to the short cells in the straw pulp. 3. As to the air permeability, the larger ratio of straw pulp was found to be the lesser, and 75% bast fiber with 25% straw pulp mixture paper and the 100% bast fiber one were found 1/5 degree efficient. 4. In terms of the water absorption degree, 100% bast fiber paper was the fastest, but in case of mixture paper, 50% mixed one was a little faster up to the point of 1cm, while the two kinds of mixed ones appear to be almost similar to each other beyond the point. 5. The straw pulp mixed paper, especially the 50% mixed one was evaluated as the highest by the calligraphers who had experienced using the papers in terms of movement and feeling of the caligraphy and painting. In addition, although the 25% mixed paper is judged to be good for book printing because of the strength, the 50% mixed paper can be thought to be more desirable for painting and calligraphy. In conclusion, we will be able to make the quality paper with durability, by mixing the straw pulp with the bast fiber in proper ratio, following the tradition of Korean paper making.

Optimum Conditions for The Taste of Kanjang Fermented with Barley Bran (보리등겨로 제조한 간장의 최적 발효 조건)

  • Kwon, O-Jun;Son, Dong-Hwa;Choi, Ung-Kyu;Lee, Suk-Il;Im, Moo-Hyeg;Cho, Young-Je;Yang, Sung-Ho;Kim, Sung-Hong;Chung, Yung-Gun
    • Korean Journal of Food Science and Technology
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    • v.33 no.5
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    • pp.596-602
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    • 2001
  • This study was conducted to find out optimum conditions of kanjang fermented with barley bran. Fermentation conditions for optimization of taste of kanjang made with barley bran was investigated with response surface methodology. Optimal conditions of salty taste was as follows, the content of meju: 15%, the content of salt: 7%, initial temperature: $24^{\circ}C$, middle temperature: $29^{\circ}C$ and end temperature: $14^{\circ}C$. Optimal conditions of palatable taste was as follows, the content of meju: 24%, the content of salt: 13%, initial temperature: $26^{\circ}C$, middle temperature: $25^{\circ}C$ and end temperature: $20^{\circ}C$. Optimal conditions of bitter taste was as follows, the content of meju: 28%, the content of salt: 18%, initial temperature: $35^{\circ}C$, middle temperature: $10^{\circ}C$ and end temperature: $38^{\circ}C$. Optimal conditions of overall acceptability was as follows, the content of meju: 15%, the content of salt: 19%, initial temperature: $30^{\circ}C$, middle temperature: $38^{\circ}C$ and end temperature: $23^{\circ}C$.

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Calcination Properties of Cement Raw Meal and Limestone with Oxidation/Reduction Condition (산화/환원 소성분위기에서 석회석 및 시멘트 원료물질의 소성거동 특성)

  • Moon, Ki-Yeon;Choi, Moon-Kwan;Cho, Jin-Sang;Cho, Kye-Hong
    • Resources Recycling
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    • v.29 no.5
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    • pp.64-72
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    • 2020
  • When the multi-stage combustion process is applied to the cement kiln to reduce nitrogen oxide emissions in the cement industry, oxidation/reduction section that can increase combustion efficiency by reducing NOx to NO and completely burning unburned materials is essential In this study, when applied the oxidation/reduction system of the cement kiln preheater and calciner, the optimal oxidation/reduction calcination crisis that can secure the quality stability of the final product, cement clinker, was to be observed macroscopically, and the mass change of raw materials according to the burning conditions, decarbonation rate, and calcination rate were investigated. The results showed that the thermal decomposition of raw materials tends to be promoted in the oxidation condition rather than in the reduction condition, and that the thermal decomposition of limestone, which has a relatively high CaO content, is carried out later than that of cement raw meal, which is thought to be caused by the CO2 fractionation in the kiln. The thermal decomposition properties of raw materials according to oxidation/reducing burning condition showed a relatively large difference in temperature range lower than normal limestone themal decomposition temperature, which is thought to be expected to improve the thermal efficiency of raw materials according to the formation of oxidation condition in the section 750℃ of burning temperature. However, for this study, lab scale. Because there is a difference from the field process as a scale study, it is deemed necessary to verify the actual test results of the pilot scale.