• The Transactions of The Korean Institute of Electrical Engineers
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• v.67 no.4
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• pp.569-577
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• 2018

In this paper, with the aid of information which is included within data, preprocessing algorithm-based black plastic classifier is designed. The slope and area of spectrum obtained by using laser induced breakdown spectroscopy(LIBS) are analyzed for each material and its ensuing information is applied as the input data of the proposed classifier. The slope is represented by the rate of change of wavelength and intensity. Also, the area is calculated by the wavelength of the spectrum peak where the material property of chemical elements such as carbon and hydrogen appears. Using informations such as slope and area, input data of the proposed classifier is constructed. In the preprocessing part of the classifier, Principal Component Analysis(PCA) and fuzzy transform are used for dimensional reduction from high dimensional input variables to low dimensional input variables. Characteristic analysis of the materials as well as the processing speed of the classifier is improved. In the condition part, FCM clustering is applied and linear function is used as connection weight in the conclusion part. By means of Particle Swarm Optimization(PSO), parameters such as the number of clusters, fuzzification coefficient and the number of input variables are optimized. To demonstrate the superiority of classification performance, classification rate is compared by using WEKA 3.8 data mining software which contains various classifiers such as Naivebayes, SVM and Multilayer perceptron.

• Journal of the Korean Society of Propulsion Engineers
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• v.13 no.1
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• pp.58-71
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• 2009

The blast wave released during the initiation of energetic materials gives rise to pulse energy generation, characterized by a sudden increase of potential energy. A highly efficient energy source, sought from pulse-type lasers, may be utilized in various space propulsion and power applications. This paper introduces a scheme of utilizing the laser energy in 1) attitude control of a satellite requiring of a low thrust, 2) innovative laser-induced drug delivery, 3) implosion-based micro piston development, 4) deflecting and zapping of space debris for laser kill purpose, and 5) finally lunar detection using laser induced breakdown spectroscopy.

• Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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• v.23 no.1
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• pp.69-76
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• 2005

The purpose of this study was to establish the accuracy of the industrial photogrammetry system constructed with INCA2 metric camera and V-STARS system on steel box girder measurement under industrial measurement condition. The objective of the measurement was to determine the distances of plane to plane or plane to libs, precise positions of the bolt holes and angles of the plane to plane on the steel box girder using coded targets, tape targets, edge targets and target adapters. The measurement undertaken has shown that industrial photogrammetry method were a very accurate and more importantly were produced quickly to measure the steel box girder.

• Journal of the Korean Ceramic Society
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• v.47 no.1
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• pp.61-65
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• 2010

Ultrathin atomic layer deposition (ALD) coatings were found to enhance the performance of lithium-ion batteries (LIBs). Previous studies have demonstrated that $LiCoO_2$ cathode powders coated with metal oxides with thicknesses of $\sim100-1000{\AA}$ grown using wet chemical techniques improved LIB performance. In this study, $LiCoO_2$ powders were coated with conformal $Al_2O_3$ ALD films with thicknesses of only $\sim3-4{\AA}$ established using 2 ALD cycles. The coated $LiCoO_2$ powders exhibited a capacity retention of 89% after 120 charge-discharge cycles in the 3.3~4.5 V (vs. $Li/Li^+$) range. In contrast, the bare $LiCoO_2$ powders displayed only a 45% capacity retention. This dramatic improvement may result from the ultrathin $Al_2O_3$ ALD film acting to minimize Co dissolution or to reduce surface electrolyte reactions.

• Journal of Electrochemical Science and Technology
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• v.11 no.4
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• pp.361-367
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• 2020

Recently, layered nickel-rich cathode materials (NCM) have attracted considerable attention as advanced alternative cathode materials for use in lithium-ion batteries (LIBs). However, their inferior surface stability that gives rise to rapid fading of cycling performance is a significant drawback. This paper proposes a simple and convenient coating method that improves the surface stability of NCM using sulfate-based solvents that create artificial cathode-electrolyte interphases (CEI) on the NCM surface. SO_x-based artificial CEI layer is successfully coated on the surface of the NCM through a wet-coating process that uses dimethyl sulfone (DMS) and dimethyl sulfoxide (DMSO) as liquid precursors. It is found that the SO_x-based artificial CEI layer is well developed on the surface of NCM with a thickness of a few nanometers, and it does not degrade the layered structure of NCM. In cycling performance tests, cells with DMS- or DMSO-modified NCM811 cathodes exhibited improved specific capacity retention at room temperature as well as at high temperature (DMS-NCM811: 99.4%, DMSO-NCM811: 88.6%, and NCM811: 78.4%), as the SO_x-based artificial CEI layer effectively suppresses undesired surface reactions such as electrolyte decomposition.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.16 no.4
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• pp.46-52
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• 2017

We quantitatively measured the mass transfer from friction surfaces, specifically brake pads and rotors, using laser plasma spectroscopy. Specifically, we modelled the mass transfer from the pad to the rotor and measured the elemental diffusion intensity distribution in the rotor material using laser plasma spectroscopy. The main elements measured were Cu, Ni, Ti, and Cr, and the distribution of these after transfer was measured as the ratio of the atomic peak and the ion peak of the plasma in the rotor exposed to friction and the surface composition of the rotor and the roughness, respectively. We measured and quantified the diffusion coefficient for each element through the mass transfer model and found that Cr obtained the largest diffusion coefficient (D) of the elements measured based on this system with a value of $1.9484{\times}10^{-15}m^2/s$.

• Journal of the Korean Society for Precision Engineering
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• v.27 no.2
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• pp.34-39
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• 2010

In order to achieve and maintain dimensional accuracy in laser micro-machining, dominant parameters such as laser power and laser focus position need to be monitored and controlled real time. Also, in order to selectively machine multi-layered materials, the material being presently machined need to be recognized. This paper presents an auto-focusing (AF) module to keep laser focus on a large-area surface; a real-time laser power stabilizing module based on optical attenuation; and a laser-induced breakdown spectroscopy (LIBS) module. With these monitoring modules, position error in laser focus on a 4" silicon wafer was kept below $4{\mu}m$, initially $51{\mu}m$, and laser power stability of a UV laser source was improved from 1.6% to 0.3%. Also, the material transition from polyimide to copper in machining of FCCL (flexible copper clad laminate) was successfully observed.

• Ceramist
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• v.22 no.4
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• pp.402-416
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• 2019

The development of next-generation secondary batteries, including lithium-ion batteries (LIB), requires performance enhancements such as high energy/high power density, low cost, long life, and excellent safety. The discovery of new materials with such requirements is a challenging and time-consuming process with great difficulty. To pursue this challenging endeavor, it is pivotal to understand the structure and interface of electrode materials in a multiscale level at the atomic, molecular, macro-scale during charging / discharging. In this regard, various advanced material characterization tools, including the first-principle calculation, high-resolution electron microscopy, and synchrotron-based X-ray techniques, have been actively employed to understand the charge storage- and degradation-mechanisms of various electrode materials. In this article, we introduce and review recent advances in in-situ synchrotron-based x-ray techniques to study electrode materials for LIBs during thermal degradation and charging/discharging. We show that the fundamental understanding of the structure and interface of the battery materials gained through these advanced in-situ investigations provides valuable insight into designing next-generation electrode materials with significantly improved performance in terms of high energy/high power density, low cost, long life, and excellent safety.

• Bulletin of the Korean Chemical Society
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• v.34 no.11
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• pp.3253-3256
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• 2013

Lithium is a highly attractive material for high-energy-concentration batteries, since it has low weight and high potential. Rechargeable lithium-ion batteries (LIBs), which have the extremely high gravimetric and volumetric energy densities, are currently the most preferable power sources for future electric vehicles and various portable electronic devices. In order to improve the efficiency and lifetime, new electrode compounds for lithium intercalation or insertion have been investigated for rechargeable batteries. Solid-state nuclear magnetic resonance (NMR) is a very useful tool to investigate the structural changes in electrode materials in actual working lithium-ion batteries. To detect the in-situ microstructural changes of electrode and electrolyte materials, $^7Li-^{19}F$ double-resonance solid-state NMR probe with a static solenoidal coil for a 600-MHz narrow-bore magnet was designed, constructed, and tested successfully.

• Bulletin of the Korean Chemical Society
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• v.34 no.4
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• pp.1199-1204
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• 2013

Nanocomposites consisting of Sn nanoparticles and graphene oxide (GO) were electrophoretically deposited onto Cu current collectors that was used for anodes in Li ion batteries (LIBs). In order to optimize the electrochemical performance of nanocomposites as an anode material by controlling the oxygen functionality, the GO was subjected to $O_3$ treatment prior to electrophoretic deposition (EPD). During thermal reduction of the GO in the nanocomposites, the Sn nanoparticles were reduced in size, along with the formation of SnO and/or $SnO_2$ at a small fraction, relying on the oxygen functionalities of the GO. The variation in the duration of time for the $O_3$ irradiation resulted in a small change in total oxygen content, but in a significantly different fraction of each functional group in the GO, which influenced the Sn nanoparticle size and the amount of SnO (and/or $SnO_2$). As a result, the EPD films prepared with the GO that possessed the least amount of carboxylic groups (made by treating GO in an $O_3$ environment for 3 h) showed the best performance, when compared with the nanocomposites composed of untreated GO or GO that was $O_3$-treated for a duration of less than 3 h.