• Journal of Electrochemical Science and Technology
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• v.6 no.2
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• pp.59-64
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• 2015

Spherical Li₄Ti₅O₁₂ and Li₄Ti₅O₁₂ carbon nanotube (CNT) composites were synthesized using a colloid system. The electrochemical properties of the composites were thoroughly examined to determine their applicability as hybrid capacitor anodes. The electrical conductivity of the spherical Li₄Ti₅O₁₂-CNT composite was improved over that of the spherical Li₄Ti₅O₁₂ composite. The synthesized composites were utilized as the anode of a hybrid capacitor, which was assembled with an activated carbon (AC) positive electrode. The CNTs attached on the spherical Li₄Ti₅O₁₂ particles contributed to a 51% reduction of the equivalent series of resistance of the Li₄Ti₅O₁₂-CNTs/AC hybrid capacitor compared to the Li₄Ti₅O₁₂/AC hybrid capacitor. Moreover, the Li₄Ti₅O₁₂-CNTs/AC hybrid capacitor showed a larger capacitance than the Li₄Ti₅O₁₂/AC hybrid capacitor; specifically, the Li₄Ti₅O₁₂-CNT/AC hybrid capacitor showed 1.6 times greater capacitance at 40 cycles with a 10 mA cm⁻² loading current density.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.545-549
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• 2001

We have produced electrolyte solution out of 1.15M LiPF$\sub$6/ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M LiPF$\sub$6/DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M LiPF$\sub$6/ EC/DEC(1/2 by vo%%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC, DMC and EMC brought the de-decomposition peak of salt anion of PF$\sub$6/$\^$-/ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. Li/Li$\^$+/\`). In addition, a kinetics current peak, in which intercalation of Li$\^$+/ is proceeded at 750mv, 450mv(vs. Li/Li$\^$+/), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance(R$\sub$ct/) according to the electric potential of Li$\^$+/ intercalation at 750mv(vs. Li/Li$\^$+/), which was the same as the resistance (R$\sub$f/) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance(R$\sub$p/) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

• Journal of Electrical Engineering and Technology
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• v.13 no.4
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• pp.1663-1672
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• 2018

In recent times, gas insulated medium voltage (MV) circuit breakers (CB) form a vital component in power system network, considering its advantages such as reduced size and safety margins. Gas insulation characteristics of circuit breakers are generally measured by lightning impulse (LI) test according to IEC standard 60060-1 as a factory routine test. Considering the environmental issues of $SF_6$ gas, many research works are being carried out towards the mixture of $SF_6$ gases for high voltage insulation applications. However, few reports are only available regarding the LI withstand and streamer propagation characteristics (at both positive and negative polarity of waveform) of $SF_6/N_2$ gas mixture insulated medium voltage circuit breakers. In this paper, positive and negative polarity LI tests are carried out on 22 kV medium voltage circuit breaker filled with $SF_6/N_2$ gas mixture at different gas pressures (1-5 bar) and at different gas mixture ratios. Important LI parameters such as breakdown voltage, streamer velocity, time to breakdown and acceleration voltage are evaluated with IEC standard LI ($1.2/50{\mu}s$) waveform. Weibull distribution analysis of LI breakdown voltage data is carried out and 50% probability breakdown voltage, scale parameter and shape parameter are evaluated. Results illustrate that the $25%SF_6+75%N_2$ gas filled insulation considerably enhances the LI withstand and breakdown strength of MV circuit breakers. LI breakdown voltage of circuit breaker under negative polarity shows higher value when compared with positive polarity. Results show that maintaining the gas pressure at 0.3 MPa (3 bar) with 10% $SF_6$ gas mixed with 90% $N_2$ will give optimum lighting impulse withstand performance of 22 kV MV circuit breaker.

• Journal of Internet Computing and Services
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• v.23 no.6
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• pp.71-78
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• 2022

This paper proposes an algorithm for 3D object detection by processing point cloud data of 3D LiDAR. Unlike 2D LiDAR, 3D LiDAR-based data was too vast and difficult to process in three dimensions. This paper introduces various studies based on 3D LiDAR and describes 3D LiDAR data processing. In this study, we propose a method of processing data of 3D LiDAR using clustering techniques for object detection and design an algorithm that fuses with cameras for clear and accurate 3D object detection. In addition, we study models for clustering 3D LiDAR-based data and study hyperparameter values according to models. When clustering 3D LiDAR-based data, the DBSCAN algorithm showed the most accurate results, and the hyperparameter values of DBSCAN were compared and analyzed. This study will be helpful for object detection research using 3D LiDAR in the future.

• Journal of the Korean Magnetic Resonance Society
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• v.18 no.2
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• pp.63-68
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• 2014

$^7Li$ nuclear magnetic resonance (NMR) spectra have been observed for $LiMPO_4$ (M = Fe, Mn) samples, as a promising cathode material of lithium ion battery. Observed $^7Li$ shifts of $LiFe_{1-x}Mn_xPO_4$ (x = 0, 0.6, 0.8, and 1) synthesized with solid-state reaction are compared with calculated $^7Li$ shift ranges based on the supertranferred hyperfine interaction of Li-O-M. Ex situ $^7Li$ NMR study of $LiFe_{0.4}Mn_{0.6}PO_4$ in different cut-off voltage for the first charge process is also performed to understand the relationship between $^7Li$ chemical shift and oxidation state of metals affected by delithiation process. The increment of oxidation state for metals makes to downfield shift of $^7Li$ by influencing the supertranferred hyperfine interaction.

• Journal of the Korean Ceramic Society
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• v.41 no.5
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• pp.388-394
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• 2004

LiCoO$_2$ as the cathode activity material for lithium secondary battery was prepared from a homogeneously mixed powder of LiNO$_3$/Co by SHS process under argon gas. The characteristics of powder including electrochemical properties were investigated according to various reaction conditions. The reaction temperature/velocity and the size of LiCoO$_2$ were controlled by Li/Co molar ratio and a cooling rate of the specimen, respectively. The maximum discharge capacity was 145 mAh/g on 1.05 Li/Co molar ratio and the relatively stable cycling characteristic with 6.4% of capacity fading was obtained after 10th charging-discharging test.

• Journal of the Korean Ceramic Society
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• v.53 no.6
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• pp.712-718
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• 2016

In this study, we investigate the effect of the$Li_3BO_3$ additive on the densification and ionic conductivity of garnet-type $Li_7La_3Zr_2O_{12}$ solid electrolytes for all-solid-state lithium batteries. We analyze their densification behavior with the addition of $Li_3BO_3$ in the range of 2-10 wt.% by dilatometer measurements and isothermal sintering. Dilatometry analysis reveals that the sintering of $Li_7La_3Zr_2O_{12}-Li_3BO_3$ composites is characterized by two stages, resulting in two peaks, which show a significant dependence on the $Li_3BO_3$ additive content, in the shrinkage rate curves. Sintered density and total ion conductivity of the system increases with increasing $Li_3BO_3$ content. After sintering at $1100^{\circ}C$ for 8 h, the $Li_7La_3Zr_2O_{12}-8$ wt.% $Li_3BO_3$ composite shows a total ionic conductivity of $1.61{\times}10^{-5}Scm^{-1}$, while that of the pure $Li_7La_3Zr_2O_{12}$ is only $5.98{\times}10^{-6}Scm^{-1}$.

• Nuclear Engineering and Technology
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• v.7 no.3
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• pp.191-198
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• 1975

A study was made on the neutron dosimetry in a mixed gamma-neutron field with LiF thermoluminescent dosimeter. In order to estimate the neutron dose in a mixed field, $^{6}$ LiF and $^{7}$ LiF dosimeters were used for fast and thermal neutron doses. The over-all conversion factors for the effects of dosimeter positions were derived for personnel monitoring and the glow curves of the LiF dosimeters for neutron and gamma-ray doses were also analyzed.

• Proceedings of the Optical Society of Korea Conference
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• 2003.02a
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• pp.234-235
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• 2003

All solid-state UV lasers provide efficient, clean and semipermanent light sources for various applications, such as eye surgery, microchip lithography. $CsLiB_{6}O_{10}$ (CLBO) is one of the most suitable crystals for UV generation because of its small walk-off, large effective nonlinear susceptibility in UV region and high damage threshold. We produced fourth (266 nm) and fifth (213 nm) harmonic generation of an Nd：YAG laser (1064 nm) with $LiB_{3}O_{5}$ as a second harmonic generation medium and CLBO as a fourth harmonic and fifth harmonic mediums. (omitted)

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1998.06a
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• pp.159-162
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• 1998

The new type polymer electrolyte composed of polyacrylonitrile(PAN) baed polymer electrolyte contain LiClO$_4$-EC/PC and LiPF$\sub$6/-EC/PC were developed for the weightless and long or life time of lithium polymer battery system with using polyaniline electrode. The gel type electrolytes were prepared by PAN at different lithium salts in the glove box. We prepared for polymer electrolyte with knife casting method. The minimum thickness of PAN gel electrolyte for the slim type is about <400∼500$\mu\textrm{m}$. These gel electrolytes showed good compatibility with lithium electrode. The test cell of Li/polymer electrolyte/Lithium cobalt oxide solid state cell which was prepared by different lithium salt was researched by electrochemical technique. Resistance of polymer electrolyte which consist of LiClO$_4$ is more less than that of LiPF$\sub$6/ and cycle life is more longer than that of LiPF$\sub$6/.