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http://dx.doi.org/10.4191/KCERS.2004.41.5.388

Synthesis and Characteristics of LiCoO2 Powders Prepared by SHS Process  

Hayk H. Nersisyan (충남대학교 금속공학과)
Publication Information
Abstract
LiCoO$_2$ as the cathode activity material for lithium secondary battery was prepared from a homogeneously mixed powder of LiNO$_3$/Co by SHS process under argon gas. The characteristics of powder including electrochemical properties were investigated according to various reaction conditions. The reaction temperature/velocity and the size of LiCoO$_2$ were controlled by Li/Co molar ratio and a cooling rate of the specimen, respectively. The maximum discharge capacity was 145 mAh/g on 1.05 Li/Co molar ratio and the relatively stable cycling characteristic with 6.4% of capacity fading was obtained after 10th charging-discharging test.
Keywords
$LiCoO_2$; SHS process; Discharge capacity;
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  • Reference
1 Synthesis of LiCo<TEX>$O_2$</TEX> Powders for Lithium-Ion Batteries from Precursors Derived by Rotary Evaporation /
[ P. N. Kumuta;D. Gallet;A. Waghray;G. E. Blomgren;M. P. Setter ] / J. Powder Sources   DOI   ScienceOn
2 Propagation of Gasless Reactions in Solids-I. Analytical Study of Exothermic Intermetallic Reaction Rates /
[ A. P. Hardt;P. V. Phung ] / Combution and Flame   DOI   ScienceOn
3 Soviet SHS Technology: A Potential U.S. Advatage in Ceramics /
[ J. Kiser;R. M. Spriggs ] / Ceram. Bull.
4 Reviews: Fundamentals, Acheivements, and Perspectives for Develpoment of Solid-Flame Combustion /
[ A. G. Merzhanov ] / Russ. Chem. Bull.   DOI   ScienceOn
5 Synthesis of LiCo<TEX>$O_2$</TEX> Particles with Uniform Size Distribution Using Hydrothermally Precipitated <TEX>$Co_3$</TEX><TEX>$O_4$</TEX> Fine Particles /
[ T. Nakamura;A. Kajiyama ] / Solid State Ionics   DOI   ScienceOn
6 Self-Propagation High Temperature Synthesis a Soviet Method for Producing Ceramic Material /
[ J. F. Crider ] / Ceram. Eng. Sci. Proc.   DOI
7 Structure and Electrochemistry of <TEX>$Li_{1{\pm}y}$</TEX><TEX>$NiO_2$</TEX> Phase with the <TEX>$Ni(OH)_2$</TEX> Structure /
[ J. R. Dahn;U. von Sack;C. A. Michal ] / Solid State Ionics   DOI   ScienceOn
8 Study on Self-Propagating High-Temperature Synthesis of TiN Powder. /
[ I. H. Song;S. G. Vadchenco;J. H. Jeon;Y. D. Han ] / J. Kor. Ceram. Soc.
9 The Role of the Reaction Medium in the Self Propagating High Temperature Synthesis of Nanosized Tantalum Powder /
[ H. H. Nersisyan;J. H. Lee;S. I. Lee;C. W. Won ] / Combustion and Flame   DOI   ScienceOn
10 Electrochemical and In Situ X-Ray Diffraction Studies of Lithium Intercalation in <TEX>$Li_x$</TEX>Co<TEX>$O_2$</TEX> /
[ J. N. Reimers;J. R. Dahn ] / J. Electrochem. Soc.   DOI