• Korean Chemical Engineering Research
• /
• v.56 no.4
• /
• pp.474-478
• /
• 2018

For process safety, fire and explosion characteristics of combustible materials handled at industrial fields must be available. The combustion properties for the prevention of the accidents in the work place are flash point, fire point, explosion limit, and autoignition temperature (AIT) etc.. However, the combustion properties suggested in the Material Safety Data Sheet (MSDS) are presented differently according to the literatures. The accurate combustion properties are necessary to safely treatment, transportation and handling of flammable substances. In the chemical industries, n-ethylaniline which is widely used as a raw material of intermediate products and rubber chemicals was selected. For safe handling of n-ethyl aniline, the flash point, the fire point and the AIT were measured. The lower explosion limit (LEL)of n-ethylaniline was calculated using the lower flash point obtained in the experiment. The flash points of n- ethylaniline by using the Setaflash and Pensky-Martens closed-cup testers measured $77^{\circ}C$ and $82^{\circ}C$, respectively. The flash points of n-ethylaniline using the Tag and Cleveland open cup testers are measured $85^{\circ}C$ and $92^{\circ}C$, respectively. The AIT of the measured n-ethyl aniline by the ASTM E659 apparatus was measured at $396^{\circ}C$. The LEL of n-ethylaniline measured by Setaflash closed-cup tester at $77^{\circ}C$ was calculated to be 1.02 vol%. In this study, it was possible to predict the LEL by using the lower flash point of n-ethylaniline measured by closed-cup tester. The relationship between the ignition temperature and the ignition delay time of the n-ethylaniline proposed in this study makes it possible to predict the ignition delay time at different ignition temperatures.

• Journal of the Society of Disaster Information
• /
• v.20 no.1
• /
• pp.47-59
• /
• 2024

Purpose: This study aims to propose measures for the prevention of fire and explosion accidents within manufacturing facilities by improving the existing classification criteria for hazardous locations based on the leakage patterns of flammable liquids. The objective is to suggest ways to safely manage ignition sources and combustible materials. Method: The hazardous locations were calculated using "KS C IEC 60079-10-1," and the calculated explosion hazard distances were visualized in 3D. Additionally, the formula for the atmospheric dispersion of flammable vapors, as outlined in "P-91-2023," was utilized to calculate the dispersion rates within the hazardous locations represented in 3D. Result: Visualization of hazardous locations in 3D enabled the identification of blind spots in the floor plan, facilitating immediate recognition of ignition sources within these areas. Furthermore, when calculating the time taken for the Lower Explosive Limit (LEL) to reach within the volumetric space of the hazardous locations represented in 3D, it was found that the risk level did not correspond identically with the explosion hazard distances. Conclusion: Considering the atmospheric dispersion of flammable liquids, it was concluded that safety management should be conducted. Therefore, a method for calculating the concentration values requiring detection and alert based on realistically achievable ventilation rates within the facility is proposed.

• 한국연소학회:학술대회논문집
• /
• 2014.11a
• /
• pp.331-332
• /
• 2014

Underground power plant is required the strict safety management and safety assessment. Because it is the high risk of explosion by characteristic of enclosed space. In case gas leak of enclosed space, the ventilation facilities is very important in order to prevent explosion by the maintain less than the LEL(lower explosive limit). Thus, Through a safety assessment of ventilation volume is to reduce the risk for ventilation facilities in Underground power plant.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
• /
• 2002.05a
• /
• pp.69-72
• /
• 2002

저발열량 가스(LCVG : low calorific value gases)는 석탄 가스, coke oven gas, carbon black waste gas, 화학공정 폐가스, 휘발성 유기화합물(VOC) 등 다양하다. 발열량 150~2,000㎉/m$^3$정도의 가스를 말하며 주요 조성은 H$_2$, CO, CH$_4$ 등이다. 화학공정 폐가스나 휘발성 유기물질 배출공정에서는 저농도(LEL 25% 이하)의 유기물질이 주 조성이다.(중략)

• Proceedings of the KIEE Conference
• /
• summer
• /
• pp.1016-1018
• /
• 2004

최근 배전용 차단기의 조작방식은 스프링 구동 방식에서 영구자석 엑츄에이터(PMA) 구동방식으로 바뀌고 있다. PMA로 작동하는 중고압 차단기는 여자전류 권선의 수에 의해 단권선형과 이권선형으로 구분한다. 본 논문에서는 PMA의 동특성을 해석하기 위하여 유한요소법과 외부회로 방정식을 결합하였다. 가동부의 움직임을 고려하여 자계분포를 해석하였으며 가동부의 속도와 흡인력을 구하여 비교하였다. 해석된 결과는 PMA 설계에 이용될 수 있을 것으로 기대한다.

• Journal of Sensor Science and Technology
• /
• v.8 no.4
• /
• pp.327-332
• /
• 1999

Catalytic combustion type gas sensors were fabricated by using noble metal(Pt and Pd) added ${\gamma}-Al_2O_3$ powder with specific surface area of $200\;m^2/g$. The fabricated sensor showed power consumption of 500 mW at the operating voltage of 1.75 V and high sensitivity of about 120 mV for butane, methane, or propane 100%LEL, respectively. The sensor properties also showed good linearity to hydrocarbon gas concentration variation, reproductivity and stability for relative humidity variation. And it showed high stability in butane ambient for 100 days.

• Journal of the Korean Institute of Gas
• /
• v.27 no.4
• /
• pp.50-55
• /
• 2023

Lithium-ion secondary batteries are currently in high demand and supply. The purpose of this study is to secure the safety of the process by studying the combustion characteristics of EC(Ethylene Carbonate), Which is mainly used as an electrolyte organic solvent for lithium ion batteries. The flash points of the EC by using Setaflash and Pensky-Martens closed-cup testers were experimented at 141 ℃ and 143 ℃, respectively. The flash points of the EC by Tag and Cleveland open cup testers were experimented at 152 ℃ and 156 ℃, respectively. The AIT(Auto Ignition Temperature) of the EC was experimented at 420 ℃. The LEL(Lower Explosive Limit) calculated by using lower flash point of Setaflash was calculated at 3.6 Vol.%.

• Journal of the Korean Society of Safety
• /
• v.23 no.3
• /
• pp.1-7
• /
• 2008

As a clean fuel, LNG or LPG is widely used in large restaurants or plants instead of coal. These fuels are easy to use and cheap. However, they are inflammable very much and easily exploded at the worst. So there are many laws and regulations legislated for the handling and usage of the gas facilities. Nevertheless, very harsh explosions occurred in several domestic or foreign places. In this paper a gas detection and alarm system was developed for large facilities. A new concept for connecting many gas detectors was proposed and based upon that a system including hardware and software have been developed and tested. Although up to 16 gas detectors apart 1 km from main controller can be connected currently, this system can be easily expanded for more detectors because each gas detector receiver communicates with main controller using industrial standard RS-485 multi drop technique. Furthermore several additive functions was included for the installation and maintenance convenience.

• Journal of applied mathematics & informatics
• /
• v.4 no.2
• /
• pp.535-543
• /
• 1997

The application of Hadamard matrix to the paral-lel routings on the hypercube network was presented by Rabin. In this matrix every two rows differ from each other by exactly n/2 positions. A set of n disjoint paths on n-dimensional hypercube net-work was designed using this peculiar property of Hadamard ma-trix. Then the data is dispersed into n packets and these n packet are transmitted along these n disjoint paths. In this paper Rabin's routing algorithm is analyzed in terms of covering problem and as-signment problem. Finally we conclude that n packets dispersed are placed in well-distributed positions during transmisson and the ran-domly selected paths are almost a set of n edge-disjoint paths with high probability.

• Journal of the Korean Society of Safety
• /
• v.30 no.2
• /
• pp.21-26
• /
• 2015

For the safe handling of o-cresol, this study was investigated the explosion limits of o-cresol in the reference data. The flash points and AITs(auto-ignition temperatures) by ignition delay time were experimented. The lower flash points of o-cresol by using closed-cup tester were experimented in $77^{\circ}C$ and $80^{\circ}C$. The lower flash points of o-cresol by using open cup tester were experimented in $86^{\circ}C$ and $87^{\circ}C$. This study measured relationship between the AITs and the ignition delay times by using ASTM E659 tester for o-cresol. The AIT of o-cresol was experimented as $495^{\circ}C$. The lower explosion limit(LEL) by the measured the lower flash point for o-cresol was calculated as 1.27 Vol%.