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Cesium and strontium recovery from LiCl-KCl eutectic salt using electrolysis with liquid cathode

  • Jang, Junhyuk;Lee, Minsoo;Kim, Gha-Young;Jeon, Sang-Chae
    • Nuclear Engineering and Technology
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    • v.54 no.10
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    • pp.3957-3961
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    • 2022
  • Deposition behaviors of Sr and Cs in various liquid cathodes, such as Zn, Bi, Cd, and Pb, were examined to evaluate their recovery from LiCl-KCl eutectic salt. Cations in the salt were deposited on the liquid cathode, exhibiting potential of -1.8 to -2.1 V (vs. Ag/AgCl). Zn cathode had successful deposition of Sr and exhibited the highest recovery efficiency, up to 55%. Meanwhile, the other liquid cathodes showed low current efficiencies, below 18%, indicating LiCl-KCl salt decomposition. Sr was recovered from the Zn cathode as irregular rectangular SrZn13 particles. A negligible amount of Cs was deposited on the entire liquid cathode, indicating that Cs was hardly deposited on liquid cathodes. Based on these results, we propose that liquid Zn cathode can be used for cleaning Sr in LiCl-KCl salt.

Measurement of Liquid-Metal Flow with a Dynamic Neutron Radiography (중성자 래디오그래피를 이용한 액체금속 유동장 측정)

  • Cha, Jae-Eun;Saito, Yasushi
    • Journal of the Korean Society of Visualization
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    • v.9 no.4
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    • pp.63-68
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    • 2011
  • The flow-field of a liquid-metal system is very important for the safety analysis and the design of the steam generator of liquid-metal fast breeder reactor. Dynamic neutron radiography (DNR) is suitable for a visualization and measurement of a liquid metal flow and a two-phase flow in a metallic duct. However, the three dimensional DNR techniques is not enough to obtain the velocity information in the wide channel up to now. In this research, a high speed DNR technique was applied to visualize the heavy liquid-metal flow field in the narrow channel with the HANARO-beam facility. The images were taken with a high frame-rate neutron radiography at 250 fps and analyzed with a Particle Image Velocimetry(PIV) method. The images were compared with the results of the commercial CFX code to study the feasibility of DNR technique for the measuring the heavy liquid-metal flow field. The PIV images could discern the turbulent vortex flow in the two-dimensional narrow channel.

The Analytical Study on Synthesis and Optimization of Purification of Ionic Liquid, 1-ethyl-3-methylimidazolium Tetrafluoroborate (이온성 액체 1-ethyl-3-methylimidazolium Tetrafluoroborate의 정제 최적화 조건에 따른 특성 변화 분석 연구)

  • Yang, Kyung-Chul;Chun, Kyung-Soo
    • Journal of the Korean Ceramic Society
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    • v.50 no.2
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    • pp.103-107
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    • 2013
  • In this study, the ionic liquid 1-ethyl-3-methylimidazolium tetraflouroborate (EMI-BF4) was synthesized and purified using the liquid/liquid fractional distillation method to apply a supercapacitor. EMI-BF4 was extracted with dichloromethane from the liquid/liquid extraction method in acidic, neutral, and alkali conditions for removal of impurity, and then the electrical capacities of the purified ionic liquids were measured and compared. The electrical capacities of ionic liquids under acidic condition showed higher value than those of neutral or alkali conditions. As the ratio of ionic liquid to solvent became higher, the electrical capacity value was increased.

액체미립화에 관한 실험적 연구

  • 이규영;신명순;양옥룡
    • Journal of the korean Society of Automotive Engineers
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    • v.7 no.4
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    • pp.57-66
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    • 1985
  • This paper deals with an experimental study on a liquid atomization to investigate the break- up mechanism of a liquid film flow which is formed by a high speed air flow in parallel direction and an atomization characteristics of a liquid film flow in order to provide the basic data for the development of the twin fluid atomizer. Authors had built the simplified, transparent new devices which can form a uniform thickness of liquid film and an electrical measuring circuit of the liquid film thickness. By introducing the new devices and the measuring circuit, the time variation of a liquid film thickness the mean diameter of the droplets, the droplet size distribution, the degree of the dispersion and the atomization rate of a liquid film are measured experimentally. As the analysis of the study, it can be said the experimental investigation will fairly contribute for further study in this field of study.

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Experimental Study on Combustion Characteristics of Porous Ceramic Liquid Fuel Combustor (다공 세라믹 액체 연료 연소기의 연소 특성에 관한 실험적 연구)

  • Chung, K.H.;Lim, I.G.
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.85-93
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    • 1999
  • Experimental study on a porous ceramic liquid fuel combustor is performed. Compact burner with low pollutant emission and high combustion efficiency is realized through the use of porous ceramic materials of high porosities. The use of porous ceramic materials in burner material results in rapid vaporization of liquid fuel and enhancement in mixing process, and thus nearly premixed combustion of liquid fuel is achieved instead of diffusion and partially premixed combustion method, which is often used and apt to produce high pollutant emissions such as CO, NOx and soot. With this enhanced vaporization and premixing method of liquid fuel vapor and air, it is found that enhanced combustion process with intense radiation output and better emission characteristics in NOx, CO and soot emission, compared to other conventional liquid fuel burning method, are possible.

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A Study on Behavior of Rectangular Liquid Storage Structures (직사각형 단면을 갖는 유체 저장 구조물의 거동에 관한 연구)

  • 박장호
    • Journal of the Korean Society of Safety
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    • v.18 no.1
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    • pp.101-107
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    • 2003
  • Dynamic behavior of flexible rectangular liquid storage structures is analysed by the developed method. The rectangular liquid storage structures are assumed to be fixed to the ground and a moving coordinate system is used. The irrotational motion of invicid and incompressible ideal fluid is represented by two analytic solutions. One is the solution of the fluid motion in the rigid rectangular liquid storage structure due to ground motions and the other is the solution of the fluid motion by the motion of the wall in the flexible rectangular liquid storage structure. The motion of structure is modeled by finite elements. The fluid-structure interaction effect is reflected into the coupled equation of motion as added fluid mass matrix. The free surface sloshing motion and hydrodynamic pressure acting on the wall in the flexible rectangular liquid storage structure due to the horizontal ground motion are obtained by the developed method and verified.

The Experimental Study of Liquid Phase Mixing Mechanism of Split Triplet Impinging Spray (분리 충돌형 분사기의 액상 혼합 메커니즘에 관한 실험적 고찰)

  • 이성웅;조용호;윤웅섭
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2002.04a
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    • pp.18-23
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    • 2002
  • Liquid phase mixing of impinging injector is a resultant byproduct from the momentum exchange between a pair of impinging jets and penetration of opponent jet. Principal aim of the present study is revealing the liquid phase mixing mechanism of split triplet impinging injection sprays, and thus extending our understanding on this particular injection element. Overall mixing extent is estimated from patternation tests by the use of purified tap water and kerosene to simulate the real propellant components, respectively, and with the liquid jet momentum ratio, a controlling mixing parameter, in the range of 0.5 to 6.0. Emphasis is placed on the effect of liquid sheet superposition and disintegration, and the results with detailed spray visualization revealed the fact that superposed liquid sheet disintegration is the main pathway of liquid phase mixing of split triplet impinging injector to yield enhanced mixing qualities.

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A Study on Liquid Limit Results by Dynamic and Static Liquid Limit Tests (동적액성한계시험과 정적액성한계시험 결과의 상관성 연구)

  • Ryu, Je-Soo;Lee, Gye-In;Lee, Jae-Ho;Jeon, Woo-Jeong
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.207-210
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    • 2003
  • This study, using Pyongteak & Tangjin soil, examined a relationship between Dynamic and Static Liquid Limit Tests. The Liquid Limit Tests were carried out based on BS and KS. The results of the study are summarized as follows. The liquid limit value of the Static Liquid Limit Test was greater than that of the Dynamic Liquid Limit Test be 4% - 14%. The following equation shows the relationship between the two values.(Coefficient of Correlation = 0.88) $$BS(LL)=0.7519{\times}KS(LL)+19.174$$

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Liquid Moisture Management and Surface Properties of the Fabric in Transient Condition (작업복 소재 직물의 액상 수분 전달 특성 및 표면특성 연구)

  • 유신정
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.1
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    • pp.61-70
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    • 2001
  • As important factors determining human sensorial comfort, liquid moisture management and surface properties of heat resistant workwear materials were examined. To figure out liquid moisture management properties of the test materials, absorption capacity, rate of absorption, and evaporation properties were assessed. A modified GATS(Gravimetric Absorbency Testing System) was used to measure the liquid moisture accumulation associated with the wicking of liquid moisture from sweating skin. The GATS procedure measures demand wettability of materials to take up liquid in a direction perpendicular to the fabric surface and it was modified to incorporate a special test cell and cover to assess absorption behavior in the presence of evaporation. Fabric stiffness, smoothness, number and the length of surface fibers, and an estimate of the contact area between the skin and fabric surface were measured to characterize the mechanical and surface properties of the test materials. Also an estimate of the force with which a fabric clings to moist skin was made using as wet-cling index.

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Discussions on the Leak Phenomena of Liquid Butane in the Open Air (액화석유가스(butane)의 대기중 누출현상에 대한 고찰)

  • Yoon, Jae-Kun
    • Journal of the Korean Society of Safety
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    • v.15 no.2
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    • pp.59-62
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    • 2000
  • Almost accidents related with gas have started with the leakage of LPG(Liquefied Petroleum Gas) in the open air. But experimental data of LPG leak jet are difficult to find because the safety of experiment is hard to secure and its phenomenon is not steady but transitional. This study is focused on the phenomena of injection jet of liquid butane to the open air. Simple experiment shows that only liquid butane jet in the open air is possible due to the slow vaporization because of low temperature difference between the liquid and air and low vapor pressure of liquid butane. Comparing with the water, 25~40% more liquid butane flow through the tube under the same pressure difference driving.

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