• Journal of Environmental Science International
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• v.26 no.3
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• pp.363-371
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• 2017

This study evaluates the adsorption properties of Sr ions in an aqueous solution of the synthetic zeolite (Z-Y1) prepared using coal fly ash generated from a thermal power plant. In order to investigate the adsorption characteristics, the effects of various parameters such as the initial concentrations of Sr ion, contact time, and solution pH were investigated in a batch mode. The Langmuir and Redlich-Peterson model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacity of Sr ions, as determined the Langmuir model, was 181.68 mg/g. It was found that by varying the Sr ion concentration, pH, and temperature, the pseudo-second-order kinetic model describes the adsorption kinetics of the Sr ion better than the pseudo-first-order kinetic model. The calculated thermodynamic parameters of ${\Delta}H^0$ and ${\Delta}G^0$ showed that the adsorption of Sr ions on Z-Y1 was occurred through a spontaneous and an endothermic reaction. We found that the adsorption of Sr ions by Z-Y1 was more affected by pH than by temperature and Sr ion concentration.

• Journal of Korean Society of Water and Wastewater
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• v.29 no.6
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• pp.609-615
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• 2015

This study was carried out for characterization of MIO synthesized in our laboratory by co-precipitation method and applied isotherm and kinetic models for adsorption properties. XRD analysis were conducted to find crystal structure of synthesized MIO. Further SEM and XPS analysis was performed before and after phosphate adsorption, and BET analysis for surface characterization. Phosphate stock solution was prepared by KH2PO4 for characterization of phosphate adsorption, and batch experiment was conducted using 50 ml conical tube. Langmuir and Freundlich models were applied based on adsorption equilibrium test of MIO by initial phosphate solution. Pseudo first order and pseudo second order models were applied for interpretation of kinetic model by temperature. Surface area and pore size of MIO were found $89.6m^2/g$ and 16 nm respectively. And, the determination coefficient ($R^2$) value of Langmuir model was 0.9779, which was comparatively higher than that of Freundlich isotherm model 0.9340.

• Journal of the Korean Chemical Society
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• v.34 no.3
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• pp.227-231
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• 1990

Kinetic studies on the nucleophilic reactions of p-substituted benzylnitrates with substituted anilines have been conductometically carried out in 50-100% $CH_3CN-CH_3OH$ mixtures. From the kinetic data, Hammett ${\rho}_C$ and ${\rho}_N$ values, Bronsted $\beta$ values, and solvatochromic coefficients were determined in order to examine the transition state variations caused by changes in substituents and solvent properties. It is concluded that the reaction proceeds via a synchronous $S_N2$ mechanism in which bond formation is more advanced than bond cleavage.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.422.1-422.1
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• 2016

Graphene quantum dots (GQDs), a new kind of carbon-based photo luminescent nanomaterial from chemically modified graphene oxide (CMGO) or chemically modified graphene (CMG), has attracted extensive research attention in the last few years due to its outstanding chemical, optical and electrical properties. To further extended its potential applications as optoelectronic devices, solar cells, bio and bio-sensors and so on, intensive research efforts have been devoted to the CMG. However, the CMG, a suspension of aqueous, have problematic since they are prone to agglomeration after drying a solvent. In this study, we synthesized the GQDs from graphite and deposited on silicon substrate by kinetic spray. The photo luminescent properties of deposited GQD films were analyzed and compared with initial GQDs suspension. In addition, its carbon properties were investigated with GQDs solution properties. The properties of deposited GQD films by kinetic spray were similar to that of the GQDs suspension in water. We could provide a pathway for silicon-based silicon based device applications. Finally, the well-adjusted GQD films with photo luminescence effects will show Energy-Down-Shift layer effects on silicon solar cells. The GQD layers deposited at nozzle scan speeds of 40, 30, 20, and 10 mm/s were evaluated after they were used to fabricate crystalline-silicon solar cells; the results indicate that GQDs play an important role in increasing the optical absorptivity of the cells. The short-circuit current density (Jsc) was enhanced by about 2.94 % (0.9 mA/cm2) at 30 mm/s. Compared to a reference device without a GQD energy-down-shift layer, the PCE of p-type silicon solar cells was improved by 2.7% (0.4 percentage points).

• KIEAE Journal
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• v.15 no.2
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• pp.79-86
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• 2015

Purpose: The concept of the tectonic has researched to find out the identify of modern architecture. The meaning of traditional tectonic knowledge to emphasize structural joints and attention to detail in creativity has developed in various ways in contemporary architecture. The purpose of this study is to analyze the tectonic characteristics and architectural expressions of the light appeared in the works of Santiago Calatrava. Major features in his works could be found is to maximize structural beauties through deducing the architectural images from the nature and expressing the material properties and the kinetic structures, and thus, to ultimately create the functional space and form by connecting the light to the tectonic structure. Method: Accordingly, I tried to analyze the three works of Santiago Calatrava (the Milwaukee Art Museum, the Bodegas Ysios Winery and the City and Arts and Sciences) as following categories - the structural aesthetics, the expression of material properties, the relationship between he kinetic structures and the light. Result: According to the results of the study, Santiago Calatrava tried to create his own architectural aesthetic by combining structural tectonic with nature, material, regional place and culture. He also sought to express the tense and dynamic tectonic rather than the stable one in his works.

• Carbon letters
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• v.10 no.4
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• pp.305-313
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• 2009

In this study, the adsorption of toxic pollutants onto cetyltrimethylammonium kaolin (CTAB-Kaolin) is investigated. The organo-kaolin is synthesized by exchanging cetyltrimethylammonium cations (CTAB) with inorganic ions on the surface of kaolin. The chemical analysis, the structural and textural properties of kaolin and CTAB-kaolin were investigated using elemental analysis, FTIR, SEM and adsorption of nitrogen at $-196^{\circ}C$. The kinetic adsorption and adsorption capacity of the organo-kaolin towards o-xylene, phenol and Cu(II) ion from aqueous solution was investigated. The kinetic adsorption data of o-xylene, phenol and Cu(II) are in agreement with a second order model. The equilibrium adsorption data were found to fit Langmuir equation. The uptake of o-xylene and phenol from their aqueous solution by kaolin, CTAB-kaolin and activated carbon proceed via physisorption. The removal of Cu(II) ion from water depends on the surface properties of the adsorbent. Onto kaolin, the Cu(II) ions are adsorbed through cation exchange with $Na^+$. For CTAB-kaolin, Cu(II) ions are mainly adsorbed via electrostatic attraction with the counter ions in the electric double layer ($Br^-$), via ion pairing, Cu(II) ions removal by the activated carbon is probably related to the carbon-oxygen groups particularly those of acid type. The adsorption capacities of CTAB-kaolin for the investigated adsorbates are considerably higher compared with those of unmodified kaolin. However, the adsorption capacities of the activated carbons are by far higher than those determined for CTAB-kaolin.

• Nuclear Engineering and Technology
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• v.41 no.1
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• pp.11-20
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• 2009

Radiation effects on materials are inherently multiscale phenomena in view of the fact that various processes spanning a broad range of time and length scales are involved. A multiscale modeling approach to embrittlement of pressure vessel steels is presented here. The approach includes an investigation of the mechanisms of defect accumulation, microstructure evolution and the corresponding effects on mechanical properties. An understanding of these phenomena is required to predict the behavior of structural materials under irradiation. We used molecular dynamics (MD) simulations at an atomic scale to study the evolution of high-energy displacement cascade reactions. The MD simulations yield quantitative information on primary damage. Using a database of displacement cascades generated by the MD simulations, we can estimate the accumulation of defects over diffusional length and time scales by applying kinetic Monte Carlo simulations. The evolution of the local microstructure under irradiation is responsible for changes in the physical and mechanical properties of materials. Mechanical property changes in irradiated materials are modeled by dislocation dynamics simulations, which simulate a collective motion of dislocations that interact with the defects. In this paper, we present a multi scale modeling methodology that describes reactor pressure vessel embrittlement in a light water reactor environment.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.1
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• pp.35.1-35.1
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• 2018

Shock waves have been observed in the outskirts of galaxy clusters. They are commonly interpreted as being driven by mergers of sub-clumps, so are called "merger shocks". We here report a study of the properties of merger shocks in merging galaxy clusters with cosmological hydrodynamic simulations. As a representative case, we describe the case where sub-clusters with mass ratio ~ 2 go through an almost head-on, binary-like merger. Because of the turbulent nature of hierarchical clustering, shock surfaces are not uniform, but composed of parts with different Mach numbers. As merger shocks expand from the core to the outskirts, the average Mach number, < $M_s$ >, increases. The shocks propagating along the merger axis could be observed as X-ray shocks and/or radio relics. The kinetic energy through the shocks peaks at ~ 1 Gyr after shock launching, or at ~ 1 - 2 Mpc from the core. The most energetic shocks are found to have the kinetic-energy weighted Mach number, < $M_s$ > $_{\phi}{\simeq}2-3$, and the CR-energy weighted Mach number, < $M_s$ > $_{CR}{\simeq}3-4$. We then discuss the observational implications of our results.

• Journal of Biosystems Engineering
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• v.30 no.4 s.111
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• pp.229-234
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• 2005

Kinetic friction coefficient, bulk density, dynamic and static angle of repose, and terminal velocity of rice husk at the moisture range 7 to $23\%$ w.b. were determined. It could lead to better design and operation of the processing machinery and handling facilities. Friction coefficient was determined from the horizontal traction force measured by pulling the container holding a mass of rice husk on various plate materials. Dynamic angle of repose was calculated from the photos of bulk samples piled by gravity flow on a circular platform. Static angle of repose was determined by measuring the side angle of the bulk material which was left in a cylindrical container after natural discharge of the bulk sample through a circular hole in the bottom plate. Kinetic friction coefficients of rice husk were in the range of $0.254\~0.410,\;0.205\~0.520,\;0.229\~0.400,\;and 0.133\~0.420$ on PVC, mild steel, galvanized steel, and stainless steel, respectively. Bulk density, dynamic and static angle of repose, and terminal velocity were in the range of $91.7\~98.3$ $kg/m^3$, $40.2\~47.6^{\circ},\;52.8\~83.7^{\circ},$ and $1.36\~1.73$ m/s, respectively. These physical properties of rice husk increased linearly as the moisture content increased.

• Journal of Physiology & Pathology in Korean Medicine
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• v.22 no.5
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• pp.1196-1201
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• 2008

A examination of the kinetic properties of UDP-glucose : (1,3)-$\beta$-glucan (callose) synthase from mung bean seedings (Sorbus cortex) shows that these enzymes have a complex interaction with UDP-glucose and various effectors. Deoxynojirimycin increased the inhibitory effect of (1,3)-$\beta$-glucan synthase at the concentration-dependent manner by fluorescence assay. The inhibitory effect of Fr. 2-16 (97.15%) showed higher than that of deoxynojirimycin (80.63%). Fr. 2-3 inhibited the growth of the Candida albicans at 1 mm inhibition zone by disk diffusion method. These results suggest that Sorbus cortex extract can be used as a stable antifungal material.