• The Korean Journal of Ceramics
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• v.4 no.3
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• pp.254-259
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• 1998

A kinetic model predicting the oxidation of carbon fiber reinforced glass matrix composites has been described. The weight loss of composites during oxidation implied that a gasification of carbon fiber takes place and the transport of reactants $(O_2)$ or product (CO or $CO_3$) in the glass matrix was partially the rate controlling step. The kinetic model in this study was based on the work of Sohn and Szekely which may be regarded as a generalization of numerous models in the gas-solid reaction system. A comparison of this model with experimental data is also presented.

• Transactions of the Korean Society of Automotive Engineers
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• v.7 no.7
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• pp.1-14
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• 1999

In the present study, the flame factor which primarily influence the simulation accuracy of the combustion process in a gasoline engine was modeled as a nonlinear function of turbulent intensity to laminar flame speed ratio. Multi-length-scale production rate model for turbulent kinetic energy equation was introduced to consider the different length scales of the swirling and tumbling motions in cylinder on the production rte of turbulent kinetic energy. By7 introducing the multi-length-scale production rate model for the turbulent kinetic energy equation, the predictions of turbulent burning velocity , cylinder pressure, mass burning rate and engine performance of a gasoline engine can much be improved.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 1993.11a
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• pp.31-36
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• 1993

Three different methods were employed to measure the degree of aerial oxidation in coal and the resulting oxidation/weathering indices were applied to obtain kinetic parameters of aerial oxidation processes, The index (i.e., slurry pH, Free Swelling Index, weight gain) values were subjected to kinetic analysis based on power-law Arrhenius type reaction model. The results show that activation energy of the aerial oxidation in 20-29$0^{\circ}C$ is in the range of 12-16 ㎉/㏖ and the agreement among three techniques is remarkable. The first order kinetic model is suitable in describing low temperature aerial oxidation process, except in the FSI case where the zero order expression is the best one.

• Transactions of the Korean Society of Mechanical Engineers
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• v.16 no.10
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• pp.1940-1954
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• 1992

Fine grid computations were attempted to analyze the turbulent flows in the near wall low Reynolds number region and the numerical analyses were incorporated by a finite-volume discretization with full find grid system and low Reynolds number k-.epsilon. model was employed in this region. For the improvement of low Reynolds number k-.epsilon. model, modification coefficient of eddy viscosity $f_{\mu}$ was derived as a function of turbulent Reynolds number $R_{+}$ and nondimensional length $y^{+}$ from the concept of two length scales of dissipation rate of turbulent kinetic energy. The modification coefficient $f_{\epsilon}$ in .epsilon. transport equation was also derived theoretically. In the turbulent kinetic energy equation, pressure diffusion term was added in order to consider low Reynolds number region effect. The main characteristics of this low Reynolds number k-.epsilon. model were founded as : (1) In high Reynolds number region, the present model has limiting behavior which approaches to the high Reynolds number model. (2) Present low Reynolds number k-.epsilon. model dose not need additional empirical constants for the transport equations of turbulent kinetic energy and dissipation of turbulent kinetic energy in order to consider wall effect. Present low Reynolds number turbulence model was tested in the pipe flow and obtained improved results in velocity profiles and Reynolds stress distributions compared with those from other k-.epsilon. models.s.s.

• Journal of computational fluids engineering
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• v.20 no.3
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• pp.54-61
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• 2015

In the present study, a flow solver using a kinetic BGK scheme was developed for the compressible Navier-Stokes equation. The kinetic BGK scheme was used to simulate flow field from the continuum up to the transitional regime, because the kinetic BGK scheme can take into account the statistical properties of the gas particles in a non-equilibrium state. Various numerical simulations were conducted by the present flow solver. The laminar flow around flat plate and the hypersonic flow around hollow cylinder of flare shape in the continuum regime were numerically simulated. The numerical results showed that the flow solver using the kinetic BGK scheme can obtain accurate and robust numerical solutions. Also, the present flow solver was applied to the hypersonic flow problems around circular cylinder in the transitional regime and the results were validated against available numerical results of other researchers. It was found that the kinetic BGK scheme can similarly predict a tendency of the flow variables in the transitional regime.

• Transactions of the Korean hydrogen and new energy society
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• v.30 no.2
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• pp.178-187
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• 2019

Due to the increasing demand of high rank coal, the use of low rank coal, which has economically advantage, is rising in various industries using carbonaceous solid fuels. In addition, the severe disaster of global warming caused by greenhouse gas emissions is becoming more serious. The Republic of Korea set a goal to reduce greenhouse gas emissions by supporting the use of biomass from the Paris International Climate Change Conference and the 8th Basic Plan for Electricity Supply and Demand. In line with these worldwide trends, this paper focuses on investigating the combustibility of high rank coal Carboone, low rank coal Adaro from Indonesia, Baganuur from Mongolia and, In biomass, wood pellet and herbaceous type Kenaf were simulated as kinetic reactivity model. The accuracy of the pore development model were compared with experimental result and analyzed using carbon conversion and tau with grain model, random pore model, and flexibility-enhanced random pore model. In row lank coal and biomass, FERPM is well-matched kinetic model than GM and RPM to using numerical simulations.

• Environmental Engineering Research
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• v.11 no.5
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• pp.250-256
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• 2006

The combustion kinetics of poly(ethylene terephthalate) (PET) was studied by the dynamic model which accounts for the thermal decomposition of polymer at any time. The kinetic analysis was performed by a conventional nonisothermal thermogravimetric (TG) technique at several heating rates between 10 and 40 K/min in air atmosphere. The thermal decomposition of PET in air atmosphere was found to be a complex process composed of at least two stages for which kinetic values can be calculated. The combustion kinetic analysis of PET gave apparent activation energy for the first stage of $257.3{\sim}269.9\;kJ/mol$, with a value of $140.5{\sim}213.8\;kJ/mol$ for the second stage. To verify the effectiveness of the kinetic analysis method used in this work, the kinetic analysis results were compared with those of various analytical methods. The kinetic parameters were also compared with values of the pyrolysis of PET in nitrogen atmosphere.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.24 no.11
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• pp.929-934
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• 2011

The adsorption kinetic study of ruthenium complex, N3, onto nanoporous titanium dioxide ($TiO_2$) photoanodes has been carried out by measuring dye uptake in-situ. Three simplified kinetic models including a pseudo first-order equation, pseudo second-order equation and intraparticle diffusion equation were chosen to follow the adsorption process. Kinetic parameters, rate constant, equilibrium adsorption capacities and related coefficient coefficients for each kinetic model were calculated and discussed. It was shown that the adsorption kinetics of N3 dye molecules onto porous $TiO_2$ obeys pseudo second-order kinetics with chemisorption being the rate determining step. Additionally the heterogeneous surface and the pore size distribution of porous $TiO_2$ adsorbents were also discussed.

• Journal of the Korean GEO-environmental Society
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• v.11 no.1
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• pp.45-51
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• 2010

Cadmium (Cd) adsorption by the activated carbon containing hydroxyapatite (HAP) was investigated. Cd adsorption with different HAP mass ranged from 10% to 30%. With more HAP, more Cd was adsorbed. These results suggest that the higher HAP dose causes an increase of the ion exchange potential in HAP sorbent. Kinetics and equilibrium studies were investigated in series of batch adsorption experiments. Langmuir and Freundlich isotherm models were fit to the equilibrium data and Cd adsorption on HAP sorbent were found to follow the Freundlich isotherm model well in the initial adsorbate concentration range. The simple kinetic model, the pseudo first order kinetic model and the pseudo second order kinetic model, were used to investigate the adsorption. The adsorption reaction of Cd followed the pseudo second order kinetic model, and the adsorption pseudo second order kinetic constants ($k_2$) increased with increasing initial HAP amounts onto activated carbon. Also, intraparticle diffusion model was used to investigate the adsorption mechanism between adsorbate and adsorbent in the aqueous phase. Surface adsorption reaction and intraparticle diffusion occur simultaneously Cd adsorption mechanism from aqueous phase in this study.

• Journal of Environmental Science International
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• v.27 no.3
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• pp.167-177
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• 2018

The removal characteristics of As and Se ions from aqueous solution by hexadecyl trimethyl ammonium bromide (HTMAB) modified anthracite (HTMAB-AT) were investigated under various conditions of contact time, pH and temperature. When the pH is 6, the zeta potential value of anthracite (AT) is -24 mV and on the other hand, the zeta potential value of the HTMAB-AT is +44 mV. It can be seen that the overall increase of about 60 mV. Increasing the (+) potential value indicates that the surface of the adsorbent had a stronger positive charge, so adsorption for the anion metal was increased. The isotherm data was well described by Langmuir and Temkin isotherm model. The maximum adsorption capacity was found to be 7.81 and 6.89 mg/g for As and Se ions from the Langmuir isotherm model at 298 K, respectively. The kinetic data was tested using pseudo first and pseudo second order models. The results indicated that adsorption fitted well with the pseudo second order kinetic model. The mechanism of the adsorption process showed that adsorption was dependent on intra particle diffusion model according to two step diffusion. The thermodynamic parameters(${\Delta}G^{\circ}$, ${\Delta}H^{\circ}$, and ${\Delta}S^{\circ}$) were also determined using the equilibrium constant value obtained at different temperatures. The thermodynamic parameters indicated that the adsorption process was physisorption, and also an endothermic and spontaneous process.