• 한국기계가공학회지
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• 제7권2호
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• pp.45-51
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• 2008

The objective of this study is to develop an automatic object changer unit to improve processing problems existed in the conventional horizontal machining center. In order to perform this objective, a upward and downward traverse unit in which a unit that consists of a motor and reducer, chain and sprocket wheel, and upper and lower base employed in an automatic object changer unit performs sliding contact motion in a frame was designed. To achieve this design, constraint conditions for the upward and downward traverse unit first designed. Then, an operation mechanism was designed and that was introduced as a sum of kinetic energy for the sprocket wheel and upper and lower base based on the moment of inertia, which is the kinetic energy of the converted upward and downward traverse unit in the side of the reducer. In addition, The work required to rotate the converted upward and downward traverse unit in the side of the reducer by one revolution can be calculated using the sum of work that is required in the sprocket wheel and upper and lower base that is a part of the upward and downward traverse unit. Furthermore, the converted equation of motion in the side of the motor can be introduced using the equation of motion using the converted upward and downward traverse unit in the side of the motor. Then, Then, a proper motor can be determined using predetermined specifications employed in the motor and several parameters in the upward and downward traverse unit in order to verify such predetermined specifications. Also, a design of a horizontal traverse unit that performs sliding motion on a upward and downward traverse unit and simulation that verifies the results of this design are required as a future study.

• 한국포장학회지
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• 제20권3호
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• pp.97-102
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• 2014

TTI 상용제품인 Fresh-check을 명태의 냉장유통 중 품질예측에 사용할 때 그 성능이 항상 최적화되어 있을 수 없다는 가정하에서, TTI를 냉장유통의 어느 시점에서 부착하는 것이 가장 바람직한지를 수학적으로 분석하였다. TTI 부착시점으로 크게 '어획 후 선상에서, '부산국제수산물도매시장에서', '마트에서'의 세 경우로 나누었다. 먼저, 등온 실험을 통하여 TTI의 색 변화와 명태의 Pseudomonas spp.에 관한 kinetic과 Arrhenius 온도의존성 모델 식을 완성하였다. 얻어진 모델 식을 사용하여 냉장유통에 해당하는 dynamic 온도조건에 대하여 수리적으로 TTI의 색 변화와 명태의 품질변화를 계산하였다. 그 결과, 마트에서 부착했을 때 TTI 색 변화가 종료 점에 도달한 시간이 명태의 부패시간과 가장 일치하였다. 따라서 상용 TTI 제품을 사용할 경우 부착시점의 선택이 중요함을 알 수 있었다.

• Applied Biological Chemistry
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• 제47권1호
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• pp.33-40
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• 2004

Ubiquitin 폴딩 반응의 초기에 나타나는 transient 폴딩 intermediate 상태의 열역학적인 특성을 연구하였다. 온도와 화학변성제의 농도를 바꾸어주면서 측정한 폴딩 kinetics의 결과로부터 unfolded 상태와 intermediate 상태의 평형상수 및 자유에너지를 quantitative kinetic modeling을 통하여서 구하였으며 또한 온도에 따른 자유에너지의 변화로부터 unfolded 상태에서 intermediate 상태로 전환될 때의 열역학적 함수인 ${\Delta}H,\;{\Delta}S,\;{\Delta}C_p$를 구하였다. Ubiquitin이 unfolded 상태에서 intermediate 상태가 될 때의 ${\Delta}C_p$는 unfolded 상태에서 native 상태로 되는 과정의 ${\Delta}C_p$의 약 80% 정도 되었다. 이것은 intermediate가 native 상태에 가까운 매우 조밀한 구조를 이루고 있는 ensemble state임을 나타낸다. 상온에서의 ${\Delta}H$는 양의 값을 보였다. 이는 ubiquitin의 unfolded 상태에서 소수성 잔기 주위에 위치한 물 분자의 규칙적인 구조가 intermediate 상태가 될 때 와해되기 때문이라고 여겨진다. 이러한 양의 enthalpy는 자유로워진 물 분자에 의한 전체 계의 entropy의 증가에 의하여서 보상되어 unfolded 상태에서intermediate 상태로의 전환은 음의 자유에너지를 갖게 되며 폴딩 반응의 초기에 관찰되는 것으로 여겨진다.

• Macromolecular Research
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• 제16권2호
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• pp.155-162
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• 2008

We report the successful synthesis of poly(NBECOOH-b-NBEPOSS) copolymers, taking advantage of the sequential, living ring opening metathesis polymerization of NBETMS and NBEPOSS using the $RuCl_2(=CHPh)(PCY_3)_2$/$CH_2Cl_2$/$20^{\circ}C$ system, followed by the hydrolysis of trimethylsilyl groups in poly(NBETMS-b-NBEPOSS) copolymers. The living behavior of ROMP of NBETMS was first investigated using two diagnostic plots, a first order kinetic plot and a $\bar{M}_n$ vs. conversion plot. The plots confirmed that no termination and chain transfer reaction had occurred during polymerization. Poly(NBECOOH-b-NBEPOSS) copolymers were prepared using the sequential monomer addition of NBEPOSS to living poly(NBETMS) chain ends, followed by the hydrolysis of trimethylsilyl groups in the poly(NBETMS-b-NBEPOSS) copolymers. The high structural integrity of poly(NBE-COOH-b-NBEPOSS) copolymers was confirmed by $^1H$-NMR, $^{13}C$-NMR spcctroscopy and GPC.

• Macromolecular Research
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• 제15권1호
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• pp.31-38
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• 2007

Pentamethylcyclopentadienyltitanium trichloride, bis(cyclopentadienyl)titanium dichloride ($Cp_2TiCl_2$), and bis(pentamethylcyclopentadienyl)titanium dichloride were used in the polymerization of styrene without the aid of Group I-III cocatalysts. The properties of the resulting polymer indicated that polymerization was more controlled than in thermal polymerization. The kinetic studies indicated that a lower level of termination is present and that the polymer chain can be extended by adding an additional monomer. To elucidate the mechanism of polymerization, a series of experiments was performed. All results supported the involvement of a radical mechanism in the polymerization using $Cp_2TiCl_2$. The possibility of atom transfer radical polymerization (ATRP) mechanism was investigated by isolating the intermediate species. We could confirm the activation step from the reaction of 1-PEC1 with $Cp_2TiCl$ by detecting the coupling product of the generated active radicals. However, the reversible deactivation reaction competes with other side reactions, and it detection was difficult with our model system.

• 재활복지공학회논문지
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• 제7권1호
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• pp.21-27
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• 2013

수동 휠체어의 추진은 추진 동작의 낮은 효율로 인하여 사용자의 상지 관절에 고통과 부상까지 유발할 수 있다. 이에 따라 수동 휠체어 추진 중에 발생하는 상지 관절의 운동역학적 해석이 필요하다. 본 연구에서는 수동 휠체어 추진 중 상지 관절에 작용하는 토크를 구할 수 있는 2차원 역동역학 모델을 개발하였다. 개발한 모델은 시상면에서 상완, 하완, 손에 해당하는 3개의 체절로 상지를 구성하였고 몸통으로부터 3개의 체절을 회전조인트로 연결한 개방연쇄구조를 갖는다. 역동역학 해는 뉴턴-오일러 방법으로 구하였고 요구되는 입력자료는 실험을 통하여 획득하였다. 수동 휠체어 추진에 필요한 상지 거동의 운동학적 자료는 3차원 동작분석 시스템에서 추출하였고 역동역학 모델의 외력에 해당하는 운동역학적 자료는 브레이크식 다이나모미터에서 추출하였다. 역동역학 모델을 이용한 해석을 통하여 수동 휠체어 추진에 따른 상지 관절의 회전각과 관절 토크를 구하였다. 개발된 모델은 상지 관절에 관한 생체역학적 해석 도구이며 적은 노력으로 3차원 역동역학 모델로 확장하는 토대가 된다.

• Journal of Microbiology and Biotechnology
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• 제25권11호
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• pp.1928-1935
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• 2015

Microbial growth kinetics is often used to optimize environmental processes owing to its relation to the breakdown of substrate (contaminants). However, the quantification of bacterial populations in the environment is difficult owing to the challenges of monitoring a specific bacterial population within a diverse microbial community. Conventional methods are unable to detect and quantify the growth of individual strains separately in the mixed culture reactor. This work describes a novel quantitative PCR (qPCR)-based genomic approach to quantify each species in mixed culture and interpret its growth kinetics in the mixed system. Batch experiments were performed for both single and dual cultures of Pseudomonas putida and Escherichia coli K12 to obtain Monod kinetic parameters (μ_max and K_s). The growth curves and kinetics obtained by conventional methods (i.e., dry weight measurement and absorbance reading) were compared with that obtained by qPCR assay. We anticipate that the adoption of this qPCR-based genomic assay can contribute significantly to traditional microbial kinetics, modeling practice, and the operation of bioreactors, where handling of complex mixed cultures is required.

• 대한기계학회논문집A
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• 제33권10호
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• pp.1014-1022
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• 2009

A biped robot in locomotion can be regarded to be kinetically redundant in that the link-chain from its foot on the ground to its swing foot has more degrees of freedom that needed to realize stable bipedal locomotion. This paper proposes a new method to generate a trajectory for bipedal locomotion based on this redundancy, which directly generates a locomotion trajectory at the joint level unlike some other methods such as LIPM (linear inverted-pendulum mode) and GCIPM (gravity-compensated inverted-pendulum mode), each of which generates a trajectory of the center of gravity or the hip link under the assumption of the dominance of the hip-link inertia before generating the trajectory of the whole links at the joint level. For the stability of the trajectory generated in the proposed method, a stability condition based on the ZMP (zero-moment point) is used as a constraint as well as other kinetic constraints for bipedal motions. A 6-DOF biped robot is used to show how a stable locomotion trajectory can be generated in the sagittal plane by the proposed method and to demonstrate the feasibility of the proposed method.

• 한국운동역학회지
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• 제30권2호
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• pp.165-172
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• 2020

Objective: The purpose of this study was to provide quantitative and objective data of throwing movement in baseball catcher through biomechanical analysis. Method: Eight high school baseball catchers (age: 17.3±0.7 yrs, height: 175.3±4.5 cm, weight: 82.5±9.0 kg, Career: 7.4±2.1 yrs) participated and 3-dimentional motion capture system and electromyography (EMG) were used in this study. Results: The maximum center of mass position displacement was observed in forward direction. The linear velocity magnitude of the upper extremity segments were showed as "wrist>elbow>shoulder" which is indicative of kinematic chain. For kinetic EMG data, we also observed the greater muscle activation in the left brachioradial and erector spine muscles muscle that during throwing movement. Conclusion: We expect that biomechanical data from this study will provide important training implications to baseball coaches and trainers in order to effectively train their baseball catchers.

• 한국전문물리치료학회지
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• 제21권1호
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• pp.47-54
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• 2014

The aim of this study was to compare the duration of hamstring flexibility improvement after 3 stretching interventions in people with limited hamstring flexibility. Twenty-two subjects (12 men, 10 women) with limited hamstring flexibility of the dominant leg received 3 stretching interventions- modified dynamic stretching (MDS), hold-relax (HR), and static stretching (SS)-in a random order. All the subjects received all 3 interventions at intervals of at least 24 hours to minimize any carry-over effect. Modified dynamic stretching was applied as a closed kinetic chain exercise in the supine position by using the sling suspension system (Redcord Trainer(R)). The SS and HR interventions were individually performed in the straight leg raising (SLR) position, and all 3 interventions were performed for 3 minutes. Outcome measures included passive knee extension (PKE) measurements. Five post-test measurements were recorded for all subjects at 3, 6, 9, 15, and 30 minutes after the interventions. MDS was associated with a significant increase in knee extension range of motion even at 30 minutes post-treatment. In contrast, the HR and SS stretching methods showed increased hamstring flexibility for only 6 minutes post-treatment. Improvements in the range of motion of knee extension (indicating enhancement in hamstring flexibility) with MDS were maintained longer than those with the HR and SS interventions. Therefore, MDS may be more effective than the other interventions for maintaining hamstring flexibility.