• Advances in aircraft and spacecraft science
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• v.10 no.2
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• pp.107-125
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• 2023

Drag reduction is significant research in aircraft design due to its effect on the cost of operation and carbon footprint reduction. Aircraft currently use conventional solid winglets to reduce the induced drag, adding extra structural weight. Fluidic on-demand winglets can effectively reduce drag for low-speed flight regimes without adding any extra weight. These utilize the spanwise airflow from the wingtips using hydraulic actuators to create jets that negate tip vortices. This study develops a computational model to investigate fluidic on-demand winglets. The well-validated computational model is applied to investigate the effect of injection velocity and angle on the aerodynamic coefficients of a rectangular wing. Further, the turbulence parameters such as turbulent kinetic energy (TKE) and turbulent dissipation rate are studied in detail at various velocity injections and at an angle of 30°. The results show that the increase in injection velocity shifted the vortex core away from the wing tip and the increase in injection angle shifted the vortex core in the vertical direction. Further, it was found that a 30° injection is efficient among all injection velocities and highly efficient at a velocity ratio of 3. This technology can be adopted in any aircraft, effectively working at various angles of attack. The culmination of this study is that the implementation of fluidic winglets leads to a significant reduction in drag at low speeds for low aspect ratio wings.

• Atmosphere
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• v.33 no.4
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• pp.343-354
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• 2023

Turbulence produced on roadways is one of the major factors determining the dilution rates at the initial stage of traffic emissions of air pollutants and, thus, the distribution of air pollutants near the roadways. Field experiments were conducted on Gyeongbu Highway, one of the busiest highways in Korea, for 4~7 days in winter, spring, and summer. Two three-dimensional ultrasonic anemometers were installed on both sides of the highway to estimate turbulence intensities (vertical wind fluctuation and kinetic turbulence energy) induced by the roadway. Roadway-induced turbulence consists of three components: structural road-induced turbulence (S-RIT), thermal road-induced turbulence (T-RIT), and vehicle-induced turbulence (VIT). The contribution of T-RIT to the total RIT was insignificant (less than 10%), and the majority of RIT was S-RIT (by the highway embankment) and VIT. In this study, we propose the empirical relationships of VIT as a function of traffic density and wind speed under free-flow traffic conditions. Although this empirical relationship appears to underestimate the VIT, it can be applied to the air quality models easily because the relationship is simple and only needs readily obtainable input variables (wind speed and traffic information).

• Clean Technology
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• v.16 no.1
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• pp.33-38
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• 2010

The characteristics of desorption reaction and the heating values of used activated carbons collected from the companies of Shiwha/Banwal industrial complex were investigated. The desorption characteristics of used activated carbons were analyzed based on the data obtained from a thermogravimetric analyzer. The activation energies and reaction orders for desorption reaction of used activated carbons were calculated by employing Freeman-Carroll method. Heating values of volatile organic compounds(VOC) desorbed from used activated carbons were estimated based on the data obtained from a total hydrocarbon analyzer. It was found that the reaction orders of desorption of used activated carbons were 0.1~0.8, their desorption activation energies, 6.9~26.4 kJ/mol, and VOC heating values, 0.4~10.7 kcal/kg.

• Journal of Hydrogen and New Energy
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• v.33 no.6
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• pp.723-732
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• 2022

Cracking ammonia inside solid oxide fuel cell (SOFC) stack is a compact and simple way. To prevent sharp temperature fluctuation and increase cell efficiency, the decomposition reaction should be spread on whole cell area. This leading to a question that, how does anode thickness affect the conversion rate of ammonia and the cell voltage? Since the 0D model of SOFC is useful for system level simulation, how accurate is it to use equilibrium solver for internal ammonia cracking reaction? The 1D model of ammonia fed SOFC was used to simulate the diffusion and reaction of ammonia inside the anode electrode, then the partial pressure of hydrogen and steam at triple phase boundary was used for cell voltage calculation. The result shows that, the ammonia conversion rate increases and reaches saturated value as anode thickness increase, and the saturated thickness is bigger for lower operating temperature. The similar cell voltage between 1D and 0D models can be reached with NH₃ conversion rate above 90%. The 0D model and 1D model of SOFC showed similar conversion rate at temperature over 750℃.

• Journal of Electrochemical Science and Technology
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• v.14 no.1
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• pp.59-65
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• 2023

Sodium hydroxide solutions are often employed as sterilization agents in the pharmaceutical industry. Here, the chloride content is considered as a critical impurity. In this study, an electrochemical method was developed to remove chloride ions (Cl^-) through the oxidative deposition of AgCl on a Ag anode. The Cl^- content in the commercially available 50% w/w NaOH solution employed was approximately 100 mg Cl^-/kg NaOH. As the OH^- content is approximately 18,000 times higher than the Cl^- content, the formation of AgCl may be expected to be thermodynamically less favorable than the formation of Ag₂O. However, activation energies for AgCl and Ag₂O formation have been reported to be approximately 3.8 and 31.2 kJ/mol, respectively, and indicate that AgCl formation is favored. AgCl can be selectively produced by controlling the anode potential. Here, the Cl^- concentration was reduced to less than 50 mg Cl^-/kg NaOH when an anode potential of 0.18 or 0.19 V vs. Hg/HgO (reference electrode) was applied for one hour at 50℃. XRD analysis and visual monitoring of the Ag anode confirmed the oxidative deposition of AgCl on the anode surface as well as the electrochemical desalination of the concentrated NaOH solution.

• Korean Chemical Engineering Research
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• v.61 no.2
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• pp.226-233
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• 2023

To create an environmentally sustainable fuel with a low sulfur concentration, requires alternative sulfur removal methods. During the course of this study, a high surface gamma alumina-supported ZnO nanocatalyst with a ZnO/-Al₂O₃ ratio of 12% was developed and tested for its ability to improve the activity of the oxidative desulfurization (ODS) process for the desulfurization of kerosene fuel. Scanning electron microscopy (SEM) and Brunauer-Emmett-Teller (BET) were used to characterize the produced nanocatalyst. In a digital batch baffled reactor (20~80 min), the effectiveness of the synthesized nanocatalyst was tested at different initial concentrations of dibenzothiophene (DBT) of 300~600 ppm, oxidation temperatures (25~70 ℃), and oxidation periods (0.5, 1, and 2 hours). The baffles included in the digital baffled batch reactor resist the swirling of the reaction mixture, thus facilitating mixing. The ODS procedure yielded the maximum DBT conversion (95.5%) at 70 ℃ with an 80-minute reaction time and an initial DBT level of 600 ppm. The most precise values of kinetic variables were subsequently determined using a mathematical modelling procedure for the ODS procedure. The average absolute error of the simulation findings was less than 5%, demonstrating a good degree of agreement with the experimental results acquired from all runs. The optimization of the operating conditions revealed that 99.1% of the DBT can be removed in 140 minutes.

• Nuclear Engineering and Technology
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• v.19 no.3
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• pp.192-197
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• 1987

Two-point kinetic equations for a compact-core-with-bulky-D$_2$O-reflector system were developed. A unique feature of the system is that certain fission gammas create retarded photoneutrons in the D$_2$O reflector by (ｒ, n) reaction. Coupling effect between the core and the reflector was investigated by simulating power transients with various ramp reactivity insertions. Special attention was paid to the phenomenon associated with spatial separation of photoneutrons and their precursors. Simulations show that accuracy of the two-point model is comparable with that of space-dependent approach. Also it is found that the explicily expressed photoneutron terms in the reflector equation slow down the power transient compared to non-photoneutron expressions. Detectors for reactor power control purpose prefer to be deployed in the core zone to be able to accurately perdict transient power.

• Nuclear Engineering and Technology
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• v.54 no.11
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• pp.4013-4021
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• 2022

A kind of zirconium phosphate mesoporous coordination polymer Zr-EDTMPA was successfully synthesized and characterized using XRD, FTIR, TGA, EA, SEM-EDS, and N₂ sorption-desorption measurements. The prepared Zr-EDTMPA was first employed for the removal of Co(II) from an aqueous solution, and the effects of pH, contact time, temperature, initial Co(II) concentration, reusability, and sorption mechanism were systematically investigated. The results showed that the Zr-EDTMPA is a zirconium phosphate complex formed by the coordination of EDTMPA to Zr in a molar ratio of 1:1. The sorption of Co(II) by Zr-EDTMPA was a pH-dependent, spontaneous and endothermic process, which was better fitted to the pseudo-second-order kinetic model and Langmuir isotherm model. The Zr-EDTMPA was demonstrated to have excellent reusability and presented a high sorption capacity of 73.0 mg·g^-1 for Co(II) at pH 8.0. The sorption mechanism was mainly attributed to the strong coordination between cobalt and the untapped hydroxyl functional groups on Zr-EDTMPA, which was confirmed by XPS spectra. Therefore, as a candidate sorbent with high sorption capacity and excellent reusability, Zr-EDTMPA has a great potential for the removal of Co(II) from aqueous solutions.

• Microbiology and Biotechnology Letters
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• v.9 no.4
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• pp.225-230
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• 1981

The kinetic study of rifamycin B production in batch culture of Nocardia mediterranei was undertaken in part of our endeavor to optimize the fermentation condition. The growth parameters such as $\mu$$_{m}$ and Ks values for nitrogen source were evaluated by employing Monod equation. From the experiments, $\mu$$_{m}$ and Ks were 0.15hr$^{-1}$ and 8.35g/1, respectively. The growth kinetics in batch culture was found successfully interpreted by logistic law, i.e., the initial specific growth rate and the maximum cell mass concentration were determined as function of pH and both found to have maxima. For the production of rifamycin B, a non-growth associated production kinetics was employed and the specific productivity as a function of pH was found to have two maximum points. The yield coefficient and the specific productivity were calculated as mean values in production phase. Utilizing these experimental data as a function of pH, the optimal condition for the rifamycin B production was discussed with regad to the pH effect on the cell growth and production of the antibiotic. As a result, growth phase at pH 6.5 and production phase at pH 7.0 were found to be recommended.ded.

• The Bulletin of The Korean Astronomical Society
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• v.46 no.2
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• pp.47.3-48
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• 2021

We studied the large scale dynamo process in a system forced by helical magnetic field. The dynamo process is basically nonlinear, but can be linearized with 𝛼&𝛽 coefficients and large scale magnetic field $\bar{B}$. This is very useful to the investigation of solar (stellar) dynamo. A coupled semi-analytic equations based on statistical mechanics are used to investigate the exact evolution of 𝛼&𝛽. This equation set needs only magnetic helicity ${\bar{H}}_M({\equiv}{\langle}{\bar{A}}{\cdot}{\bar{B}}{\rangle},\;{\bar{B}}={\nabla}{\times}{\bar{A}})$ and magnetic energy ${\bar{E}}_M({\equiv}{\langle}{\bar{B}}^2{\rangle}/2)$. They are fundamental physics quantities that can be obtained from the dynamo simulation or observation without any artificial modification or assumption. 𝛼 effect is thought to be related to magnetic field amplification. However, in reality the averaged 𝛼 effect decreases very quickly without a significant contribution to ${\bar{B}}$ field amplification. Conversely, 𝛽 effect contributing to the magnetic diffusion maintains a negative value, which plays a key role in the amplification with Laplacian ∇²(= - k²) for the large scale regime. In addition, negative magnetic diffusion accounts for the attenuation of plasma kinetic energy E_V(= 〈 U² 〉/2) (U: plasma velocity) when the system is saturated. The negative magnetic diffusion is from the interaction of advective term - U • ∇ B from magnetic induction equation and the helical velocity field. In more detail, when 'U' is divided into the poloidal component U_pol and toroidal one U_tor in the absence of reflection symmetry, they interact with - B • ∇ U and - U • ∇ B from ∇ × 〈 U × B 〉 leading to 𝛼 effect and (negative) 𝛽 effect, respectively. We discussed this process using the theoretical method and intuitive field structure model supported by the simulation result.