• Membrane and Water Treatment
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• v.14 no.1
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• pp.1-10
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• 2023

This study explored the feasibility of calcium-rich food waste, Mactra veneriformis shells (MVS), as an adsorbent for phosphate removal, and its removal efficiency was enhanced by the thermal activation process. The CaCO3 in MVS was converted to CaO by thermal activation (>800 ℃), which is more favorable for adsorbing phosphate. Thermal activation did not noticeably influence the specific surface area of MVS. The MVS thermally activated at 800 ℃ (MVS-800), showed the highest phosphate adsorption capacity, was used for further adsorption experiments, including kinetics, equilibrium isotherms, and thermodynamic adsorption. The effects of environmental factors, including pH, competing anions, and adsorbent dosage, were also studied. Phosphate adsorption by MVS-800 reached equilibrium within 48h, and the kinetic adsorption data were well explained by the pseudo-first-order model. The Langmuir model was a better fit for phosphate adsorption by MVS-800 than the Freundlich model, and the maximum adsorption capacity of MVS-800 obtained via the Langmuir model was 188.86 mg/g. Phosphate adsorption is an endothermic and involuntary process. As the pH increased, the phosphate adsorption decreased, and a sharp decrease was observed between pH 7 and 9. The presence of anions had a negative impact on phosphate removal, and their impact followed the decreasing order CO₃^2- > SO₄²- > NO₃^- > Cl^-. The increase in adsorbent dosage increased phosphate removal percentage, and 6.67 g/L of MVS-800 dose achieved 99.9% of phosphate removal. It can be concluded that the thermally treated MVS-800 can be used as an effective adsorbent for removing phosphate.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.22 no.3
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• pp.139-143
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• 2022

In this study, Among the electromagnetic induction power generation (EMG) techniques, the design specifications of the RFPM were set, and a suitable test prototype was manufactured through finite element analysis (FEM, 2D) required for characteristic calculation. In addition, a dedicated testing device (Dynamo-Tester) was designed and manufactured to measure and analyze the test prototype. The test product was measured with a test device and the result is analyzed to suggest a method that can be applied by generating as much output power as possible to charge the battery of the wearable IT device using actual kinetic energy of the human body. As a result of the test, the output power was 1.679W and the efficiency was 79.31% under the conditions of rotation speed of 780.9rpm, torque of 0.264kgf/cm, and load current of 73.6~73.9mA. Therefore, it was analyzed that it was possible to charge the wearable device with the output of the ultra-small RFPM pendulum generator.

• Korean Journal of Environmental Agriculture
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• v.40 no.4
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• pp.239-247
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• 2021

BACKGROUND: Enormous amounts of the wood biomass wastes have been produced through various wood processing. This study characterizes the surface characteristics of biomass powders of Cornus controversa (CC) and Quercus mongolica (QM) and investigates their removal efficiency and mechanism for Pb (II) in aqueous solution on which to base potential recycling alternative of the wood biomass. METHODS AND RESULTS: Batch experiments were conducted under different conditions of Pb concentrations, temperatures, time and solid/solution ratios. Adsorption isotherm of Pb by CC and QM biomass was explained significantly by the Langmuir model, indicating Pb was likely adsorbed on the monolayer of the surfaces. The adsorption kinetics were fitted significantly to the double first-order model consisting of rapid and slow steps. The respective rate constants (k1) of CC and QM for the rapid adsorption kinetic steps were 0.051 and 0.177 min^-1, and most of the sorption reactions proceeded rapidly within 6-20 minutes. The maximum adsorption quantities (q_max) of Pb were 17.25 and 23.47 mg/g for CC and QM, respectively. Thermodynamic parameters revealed that adsorption of Pb on the biomass of CC and QM was a spontaneous endothermic reaction. CONCLUSION(S): Results demonstrate that biomass wastes of CC and QM can be used as Pb adsorbents judging from adsorption isotherm, kinetics, and thermodynamic parameters.

• Journal of Electrochemical Science and Technology
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• v.13 no.1
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• pp.128-137
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• 2022

For this study, the sol gel method was used to synthesize the spinel LiNi_0.5Mn_1.5O₄ (LNMO) electrode material. Structural, morphological, electrochemical, and kinetic aspects of the LNMO have been characterized. The synthesized LNMO was indexed with the Fd3m cubic space group. The excellent capacity retention indicates that the spinel framework of LNMO has the ability to withstand high rate charge-discharge throughout long cycle tests. The Li diffusion coefficient (D_Li) changes non-monotonically across three orders of magnitude, from 10^-9 to 10^-12 cm² s^-1 determined from GITT method. The variation of D_Li seemed to be related to three oxidation reactions that happened throughout the charging process. A small dip in D_Li at the beginning stage of Li deintercalation is correlated with the oxidation of Mn³⁺ to Mn⁴⁺. While two pronounced D_Li minima at 4.7 V and 4.75 V are due to the oxidation of Ni²⁺/Ni³⁺ and Ni³⁺/Ni⁴⁺ respectively. The depletion of D_Li at the high voltage region is attributed to the occurrence of two successive phase transformation phenomena.

• Advances in concrete construction
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• v.14 no.1
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• pp.71-77
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• 2022

Creep phenomenon affects the stability and integrity of concrete structures. An inaccurate prediction of these strains may lead to the appearance of cracks and excessive deflections which may cause in some cases the demolition of structures. In fact, the measured values of these uncontrolled strains appear often to be clearly different and larger than the expected ones. Therefore, an accurate prediction of concrete deformations is a necessity. As a matter of fact, the codified descriptions of this phenomenon are unreliable and don't consider the effect of admixtures. The physical nature of creep is not well understood and almost all creep models are mainly of empirical nature. To overcome this issue, a study of the correlation between different parameters affecting concrete creep is performed and a new model for predicting creep of concrete is elaborated. This new model considers the effect of admixtures, specifically the silica fume, in predicting concrete creep and allows an accurate prediction of this phenomenon. The proposed model is based on the observation of physical behavior of creep phenomenon. It targets at expressing creep compliance in terms of structural and environmental parameters. In fact, the experimental observations show that creep curves follow two kinetic regimes leading to a model called Phenomenological Creep Model. By adequate regressions and substitutions, and according to this model, we can express creep compliance in terms of structural, environmental parameters and admixture types and percentage. The proposed new Phenomenological Creep Model Silica Fume (PCM19SF) calculates accurately creep of concrete by considering the effect of silica fume.

• Journal of Environmental Science International
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• v.31 no.8
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• pp.691-706
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• 2022

Magnetic activated carbon was prepared by adding a magnetic material to activated carbon that had been prepared from waste citrus peel in Jeju. The adsorption characteristics of an aqueous solution of the antibiotic trimethoprim (TMP) were investigated using the magnetic activated carbon, as an adsorbent, and response surface methodology (RSM). Batch experiments were carried out according to a four-factor Box-Behnken experimental design affecting TMP adsorption with their input parameters (TMP concentration: 50~150 mg/L; pH: 4~10; temperature: 293~323 K; adsorbent dose: 0.05~0.15 g). The significance of the independent variables and their interaction was assessed by ANOVA and t-test statistical techniques. Statistical results showed that TMP concentration was the most effective parameter, compared with others. The adsorption process can be well described by the pseudo-second-order kinetic model. The experimental isotherm data followed the Langmuir isotherm model. The maximum adsorption capacities of TMP, estimated with the Langmuir isotherm model were 115.9-130.5 mg/g at 293-323 K. Also, both the thermodynamic parameters, ΔH and ΔG, have both positive values, indicating that the adsorption of TMP by the magnetic activated carbon is an endothermic reaction and proceeds via an involuntary process.

• Atmosphere
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• v.31 no.5
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• pp.511-523
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• 2021

This study explores the optimal ensemble size to improve the prediction performance of the Korea Meteorological Administration's operational climate prediction system, global seasonal forecast system version 5 (GloSea5). The GloSea5 produces an ensemble of hindcast data using the stochastic kinetic energy backscattering version2 (SKEB2) and timelagged ensemble. An experiment to increase the hindcast ensemble from 3 to 14 members for four initial dates was performed and the improvement and effect of the prediction performance considering Root Mean Square Error (RMSE), Anomaly Correlation Coefficient (ACC), ensemble spread, and Ratio of Predictable Components (RPC) were evaluated. As the ensemble size increased, the RMSE and ACC prediction performance improved and more significantly in the high variability area. In spread and RPC analysis, the prediction accuracy of the system improved as the ensemble size increased. The closer the initial date, the better the predictive performance. Results show that increasing the ensemble to an appropriate number considering the combination of initial times is efficient.

• Journal of the Society of Disaster Information
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• v.17 no.4
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• pp.829-838
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• 2021

Purpose: The Air Spring Damper System (ASDS) is proposed when existing concrete structures that have not been seismic resistant for economic and technical reasons or low-rise concrete structures that are difficult to earthquake. Method: To conduct a study on the damping force antigen in the kinetic equation of free vibration, we analyze whether this device has damping ability as a damper experimentally and theoretically, and examine the possibility of field application. Result: The air damper system is considered to be more economical than steel hysteresis dampers even if the number of dampers increases due to its easy manufacture and construction and low restrictions on shape, size, material, etc. Conclusion: In an air spring damper system, it is essential to reduce the diameter of the air inlet/outlet hole to improve the damping ratio, and in this case, if the diameter exceeds a certain lower limit, consideration of the compressibility of air is required, so further research is needed.

• Journal of Electrochemical Science and Technology
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• v.13 no.2
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• pp.292-307
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• 2022

The study presents kinetics of degradation and mineralization of an anti-epileptic drug Lamotrigine (LAM) in the aqueous matrix by electrochemical advanced oxidation process (EAOP) on Ti/DSA (Ta₂O₅-Ir₂O₅) and Stainless Steel (SS) anodes using sodium sulphate as supporting electrolyte. On both the anodes, kinetic behaviour was pseudo-first-order for degradation as well as mineralization of LAM. On Ti/DSA anode, maximum LAM degradation of 75.42% was observed at an associated specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm² and 100 ppm Na₂SO₄ concentration. Maximum mineralization attained was 44.83% at an associated specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm² and 50 ppm concentration of Na₂SO₄ with energy consumption of 2942.71 kWh/kgTOC. Under identical conditions on SS anode, a maximum of 98.92% LAM degradation was marked after a specific charge (Q) of 3.1 (Ah/litre) at a current density of 1.38 mA/cm² and 100 ppm concentration of Na₂SO₄. Maximum LAM mineralization on SS anode was 98.53%, marked at a specific charge of 3.1 (Ah/litre) at a current density of 1.38 mA/cm² and 75 ppm concentration of Na₂SO₄, with energy consumption of 1312.17 kWh/kgTOC. Higher Mineralization Current Efficiency (MCE) values were attained for EAOP on SS anode for both degradation and mineralization due to occurrence of combined electro-oxidation and electro-coagulation process in comparison to EAOP on Ti/DSA anode due to occurrence of lone electro-oxidation process.

• The Journal of Korean Academy of Orthopedic Manual Physical Therapy
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• v.28 no.2
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• pp.67-75
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• 2022

Background: Scapular winging is a rare disorder that is commonly caused by nerve damage of the dorsal scapular nerve, spinal accessory nerve, or the long thoracic nerve. This affects the scapulohumeral rhythm which may cause abnormal kinetic motion of the shoulder. The purpose of this case report is to describe a self-exercise oriented management incorporating shoulder strengthening to reduce symptoms in a shoulder pain patient with winging scapular. Methods: A 45 year old male patient complained of pain in his both shoulders without any trauma. Shoulders were treated with steroid injections for supraspinatus tendonitis, but although pain improved to some extent, pain and disability continued for 3 months. Both shoulders had pain, decreased active range of motions, muscles weakness, and scapular winging. The patient underwent 9 interventional sessions over 3 months and was managed mainly by self-exercise. The intervention method involved push up plus, sling, muscle strengthening, and stabilization exercises. Loads were increased as symptoms improved. Results: Clinical outcomes were measured at every session. Pain in both shoulders reduced to 0 on a numerical pain rate scale by the 4th session, and the active range of motion was fully recovered. During the 9th session, the strength of the serratus anterior had improved from grade P to G on the right side and grade G to N grade on the left. Conclusion: In this case study, the self-exercise program was effective in reducing pain, increasing active range of motion, and improving muscle strength in subjects with scapular winging.