• Title/Summary/Keyword: Irradiation performance

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Atomistic simulations of defect accumulation and evolution in heavily irradiated titanium for nuclear-powered spacecraft

  • Hai Huang;Xiaoting Yuan;Longjingrui Ma;Jiwei Lin;Guopeng Zhang;Bin Cai
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2298-2304
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    • 2023
  • Titanium alloys are expected to become one of the candidate materials for nuclear-powered spacecraft due to their excellent overall performance. Nevertheless, atomistic mechanisms of the defect accumulation and evolution of the materials due to long-term exposure to irradiation remain scarcely understood by far. Here we investigate the heavy irradiation damage in a-titanium with a dose as high as 4.0 canonical displacements per atom (cDPA) using atomistic simulations of Frenkel pair accumulation. Results show that the content of surviving defects increases sharply before 0.04 cDPA and then decreases slowly to stabilize, exhibiting a strong correlation with the system energy. Under the current simulation conditions, the defect clustering fraction may be not directly dependent on the irradiation dose. Compared to vacancies, interstitials are more likely to form clusters, which may further cause the formation of 1/3<1210> interstitial-type dislocation loops extended along the (1010) plane. This study provides an important insight into the understanding of the irradiation damage behaviors for titanium.

Advanced Optical and Electrical Properties of TIO Thin Films by Thermal Surface Treatment of Electron Beam Irradiation (전자빔 열 표면처리에 따른 TIO 박막의 투명전극 특성 개선 효과)

  • Yeon-Hak Lee;Min-Sung Park;Daeil Kim
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.4
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    • pp.193-197
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    • 2023
  • Transparent and conducting titanium (Ti) doped indium oxide (TIO) thin films were deposited on the poly-imide (PI) substrate with radio frequency magnetron sputtering and then electron irradiation was conducted on the TIO film's surface to investigate the effect electron irradiation on the crystallization and opto-electrical properties of the films. All x-ray diffraction (XRD) pattern showed two diffraction peaks of the In2O2 (431) and (444) planes with regardless of the electron beam irradiation energy. In the AFM analysis, the surface roughness of as deposited films was 3.29 nm, while the films electron irradiated at 700 eV, show a lower RMS roughness of 2.62 nm. In this study, the FOM of as deposited TIO films is 6.82 × 10-3 Ω-1, while the films electron irradiated at 500 eV show the higher FOM value of 1.0 × 10-2 Ω-1. Thus, it is concluded that the post-deposition electron beam irradiation at 500 eV is the one of effective methods of crystallization and enhancement of opto-electrical performance of TIO thin film deposited on the PI substrate.

Photocatalytic Degradation of Algae and its By-product using Rotating Photocatalytic Oxidation Disk Reactor

  • Son, Hee-Jong;Jung, Chul-Woo;Bae, Sang-Dae
    • Environmental Engineering Research
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    • v.14 no.3
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    • pp.170-173
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    • 2009
  • This study examined the special technique of photocatalytic degradation (RPODisk) for removal of taste and odor causing materials, algae, and algal toxin. The RPODisk was effective for removal of these troublesome contaminants. It outperformed the fixed media and the UV irradiation for geosmin removal. The RPODisk performance was comparable to the combination of the UV irradiation with TiO2. The RPODisk performance was affected by the rotating speed. The faster the speed was, the better the performance. The RPODisk was also effective for removal of algae and algal toxin. The algal activity reduced by 80% after 30 mins of the treatment. More toxic microcystin (MC)-LR was more difficult to remove than MC-RR. The times for 50% removal were 23.7 mins for MC-LR and 14.1 mins for MC-RR. Almost 100 mins of the contact time was required to completely remove MC-LR at the rotating speed of 260 rpm.

A surrogate model for the helium production rate in fast reactor MOX fuels

  • D. Pizzocri;M.G. Katsampiris;L. Luzzi;A. Magni;G. Zullo
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.3071-3079
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    • 2023
  • Helium production in the nuclear fuel matrix during irradiation plays a critical role in the design and performance of Gen-IV reactor fuel, as it represents a life-limiting factor for the operation of fuel pins. In this work, a surrogate model for the helium production rate in fast reactor MOX fuels is developed, targeting its inclusion in engineering tools such as fuel performance codes. This surrogate model is based on synthetic datasets obtained via the SCIANTIX burnup module. Such datasets are generated using Latin hypercube sampling to cover the range of input parameters (e.g., fuel initial composition, fission rate density, and irradiation time) and exploiting the low computation requirement of the burnup module itself. The surrogate model is verified against the SCIANTIX burnup module results for helium production with satisfactory performance.

Quality Prediction of Eggs Treated in Combination with Gamma Irradiation and Chitosan Coating Using Response Surface Methodology

  • Lee, Kyung-Heang;Jung, Samooel;Ham, Jun-Sang;Lee, Jun-Heon;Lee, Soo-Kee;Jo, Cheo-Run
    • Journal of Animal Science and Technology
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    • v.53 no.3
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    • pp.253-259
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    • 2011
  • The aim of this work was to determine the method and predict the optimum conditions for egg quality stored for 7 days when combination treatments of irradiation and chitosan coating were applied using response surface methodology (RSM). A central composite design was chosen for the RSM in this study and the factors were irradiation dose (0~2 kGy) and concentration of chitosan coating material (0~2%). Performance of the irradiation and chitosan coating were evaluated by analyzing the egg quality and functional property factors. The predicted maximum level of Haugh units and foaming ability calculated by a developed model were 74.19 at 0 kGy of irradiation with coating by 0.96% chitosan solution and 50.83 mm at 2.0 kGy with 1.01%, respectively. The predicted minimum value of foam stability and 2-thiobarbituric acid reactive substances (TBARS) value were 2.97 mm at 0.39 kGy with 0.21% and 0.54 mg malonaldehyde/kg egg yolk at 0 kGy with 0.90% of chitosan solution, respectively. Results clearly showed that gamma irradiation negatively affected the Haugh unit and TBARS but positively affected the foaming capacity. The estimated value from the developed model by RSM was verified by no statistical difference with observed value. Therefore, RSM can be a good tool for optimization and prediction of egg quality when 2 or more treatments are combined. However, one should decide the target quality first to achieve a successful implementation of this technology.

Effect of Glucose on Listeria monocytogenes Survival under Sequential Sublethal Stresses of Gamma Irradiation and NaCl

  • Yoon, Yo-Han;Kim, Gyeong-Yeol;Nam, Min-Ji;Shim, Won-Bo;Seo, Eun-Kyoung;Kim, Jae-Hun;Lee, Ju-Woon;Byun, Myung-Woo;Chung, Duck-Hwa
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.162-166
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    • 2009
  • This study evaluated glucose effect on Listeria monocytogenes survival under gamma irradiation and NaCl stress. L. monocytogenes in phosphate buffered saline (PBS) plus glucose (0-4%) was treated with gamma irradiation (0-0.5 kGy), and the samples were then exposed to NaCl (0-9%) in tryptic soy agar plus 0.6% yeast extract. $D_{10}$ and $t_{3D}$ values were determined, and a model for prediction of $D_{10}$ values was developed. Cell counts of L. monocytogenes reduced as irradiation dose increased, and L. monocytogenes in PBS (no glucose) was more sensitive to irradiation and NaCl compared to those in PBS (2 or 4% glucose). $D_{10}$ values were 0.07-0.1, 0.12-0.16, and 0.13-0.15 kGy for 0, 2, and 4% glucose, respectively. The $t_{3D}$ values were 0.22-0.3 (0% glucose), 0.35-0.48 (2% glucose), and 0.40-0.44 (4% glucose). A model performance was acceptable. These results indicate that glucose in foods would increase the resistance of L. monocytogenes to gamma irradiation and NaCl stress.

Modelling of effective irradiation swelling for inert matrix fuels

  • Zhang, Jing;Wang, Haoyu;Wei, Hongyang;Zhang, Jingyu;Tang, Changbing;Lu, Chuan;Huang, Chunlan;Ding, Shurong;Li, Yuanming
    • Nuclear Engineering and Technology
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    • v.53 no.8
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    • pp.2616-2628
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    • 2021
  • The results of effective irradiation swelling in a wide range of burnup levels are numerically obtained for an inert matrix fuel, which are verified with DART model. The fission gas swelling of fuel particles is calculated with a mechanistic model, which depends on the external hydrostatic pressure. Additionally, irradiation and thermal creep effects are included in the inert matrix. The effects of matrix creep strains, external hydrostatic pressure and temperature on the effective irradiation swelling are investigated. The research results indicate that (1) the above effects are coupled with each other; (2) the matrix creep effects at high temperatures should be involved; and (3) ranged from 0 to 300 MPa, a remarkable dependence of external hydrostatic pressure can be found. Furthermore, an explicit multi-variable mathematic model is established for the effective irradiation swelling, as a function of particle volume fraction, temperature, external hydrostatic pressure and fuel particle fission density, which can well reproduce the finite element results. The mathematic model for the current volume fraction of fuel particles can help establish other effective performance models.

VERIFICATION OF COSMOS CODE USING IN-PILE DATA OF RE-INSTRUMENTED MOX FUELS

  • Lee, Byung-Ho;Koo, Yang-Hyun;Cheon, Jin-Sik;Oh, Je-Yong;Joo, Hyung-Kook;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 2002.05a
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    • pp.242-242
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    • 2002
  • Two MIMAS MaX fuel rods base-irradiated in a commercial PWR have been reinstrumented and irradiated at a test reactor. The fabrication data for two MOX roda are characterized together with base irradiation information. Both Rods were reinstrumented to be fitted with thermocouple to measure centerline temperature of fuel. One rod was equipped with pressure transducer for rod internal pressure whereas the other with cladding elongation detector. The post irradiation examinations for various items were performed to determine fuel and cladding in-pile behavior after base irradiation. By using well characterized fabrication and re-instrumentation data and power history, the fuel performance code, COSMOS, is verified with measured in-pile and PIE information. The COMaS code shows good agreement for the cladding oxidation and creep, and fission gas release when compared with PIE dad a after base irradiaton. Based on the re-instrumention information and power history measured in-pile, the COSMOS predicts re-instrumented in-pile thermal behaviour during power up-ramp and steady operation with acceptable accuracy. The rod internal pressure is also well simulated by COSMOS code. Therfore, with all the other verification by COSMOS code up to now, it can be concluded that COSMOS fuel performance code is applicable for the design and license for MaX fuel rods up to high burnup.

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PERFORMANCE EVALUATION OF U-Mo/Al DISPERSION FUEL BY CONSIDERING A FUEL-MATRIX INTERACTION

  • Ryu, Ho-Jin;Kim, Yeon-Soo;Park, Jong-Man;Chae, Hee-Taek;Kim, Chang-Kyu
    • Nuclear Engineering and Technology
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    • v.40 no.5
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    • pp.409-418
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    • 2008
  • Because the interaction layers that form between U-Mo particles and the Al matrix degrade the thermal properties of U-Mo/Al dispersion fuel, an investigation was undertaken of the undesirable feedback effect between an interaction layer growth and a centerline temperature increase for dispersion fuel. The radial temperature distribution due to interaction layer growth during irradiation was calculated iteratively in relation to changes in the volume fractions, the thermal conductivities of the constituents, and the oxide thickness with the burnup. The interaction layer growth, which is estimated on the basis of the temperature calculations, showed a reasonable agreement with the post-irradiation examination results of the U-Mo/Al dispersion fuel rods irradiated at the HANARO reactor. The U-Mo particle size was found to be a dominant factor that determined the fuel temperature during irradiation. Dispersion fuel with larger U-Mo particles revealed lower levels of both the interaction layer formation and the fuel temperature increase. The results confirm that the use of large U-Mo particles appears to be an effective way of mitigating the thermal degradation of U-Mo/Al dispersion fuel.

Effect of gamma irradiation on the color values and physiological properties of spent coffee ground extraction (감마선 조사가 커피박 추출물의 색도 및 생리활성에 미치는 영향)

  • Song, Ha-Yeon;Kim, Hye-Min;Kim, Woo Sik;Yang, Mi-So;Byun, Eui-Hong;Jang, Beom-Su;Choi, Dae Seong;Byun, Eui-Baek
    • Korean Journal of Food Science and Technology
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    • v.49 no.5
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    • pp.544-549
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    • 2017
  • The spent coffee grounds (SCG) are considered valuable by-products because they contain various bioactive compounds. The SCG extraction (SCGE) was irradiated at doses ranging between 30 and 50 kGy. The deep dark-brown color of SCGE was changed to a bright yellow color by gamma irradiation. The content of the bioactive compounds of gamma-irradiated SCGE was analyzed by high-performance liquid chromatography. Interestingly, the content of quinic acid was increased by gamma irradiation, whereas other compounds were decreased. Although the contents of bioactive compounds were changed by gamma irradiation, the biological activities (radical scavenging activity and whitening effects) of SCGE were unaffected. Our findings suggest that gamma irradiation can effectively improve the color values of SCGE without the loss of biological activities. Consequently, gamma irradiation can be a useful tool for improving the utilization of SCGE in the cosmetic industry.