• Journal of Conservation Science
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• v.32 no.2
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• pp.101-108
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• 2016

Lead isotope ratio of bronze artifacts excavated from Dongchon Site in Sunchang have determined by TIMS. As results of comparison lead isotope ratio of bronze objects with the provenance data of galenas of Korea, China, and Japan, the provenance of three material of bronze objects were turned out to originate from the southern and northern part of China. On the other hands, data were plotted either in zone 3 of the South Korean galena map. The results of these scientific analysis of bronze objects can be used as basic data in comparison researches on manufacturing technology, provenance of bronze objects to be found in the future.

• 보존과학연구
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• s.36
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• pp.4-10
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• 2015

This paper confirms characteristics of lead isotopes of bronze artifacts excavated from Korea peninsula using 673 data classified according to Age, type and region. Lead isotopes data in Early iron ages are distributed in the southern Korean peninsula, but data in Joseon ages are concentrated in zone 3. Also Bronze artifacts excavated from Seoul, Gyeonggi, Chungcheong, Jeolla and Gyeonsang are manufactured using raw materials of the entire Korea peninsula, but bronzes excavated from North Korea aren't produced using raw materials of Gyeonsang provinces. Lead isotopes data will be able to find moving routes of raw materials and to separate the period of mixing and recycling of lead.

• 보존과학연구
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• s.33
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• pp.33-43
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• 2012

The corrosion phenomena of the iron artifacts was studied by morphology observation and instrumental analysis(EDS, XRD, Raman) with various corrosion factors in oder to verify to confirm the danger of corrosion factors. Corrosion compounds were collected by depositing pure Fe powder(99%) into a HCl, $HNO_3$, $H_2SO_4$, and $H_2O$ solution which contained the corrosion factors. Stereoscopic-microscope observations were then conducted determine the colors and shapes of the collected corrosion compounds, and SEM-EDS analysis was conducted to confirm the corrosion factors and the growth of these compounds. X-ray diffraction (XRD), Raman analyses were conducted to examine the crystal structure and compositions of the created corrosion compounds. The results of the experiment revealed that corrosion speed was faster in an acidic environment and corrosion of HCl and $H_2SO_4$ was greater than that of $HNO_3$. The corrosion compounds of HCl grew into a needle or chestnut-like shape after being affected by Cl- ion, and XRD and Raman analyses detected goethite and lepidocrocite. The corrosion compounds of $H_2SO_4$ was affected by S ion and grew into a slender-needle-like or cylindrical shape, and the XRD and Raman analyses detected goethite and lepidocrocite. The corrosion compounds of $HNO_3$ grew into a spherical or plate-like shape after being affected by O ion and the XRD and Raman analyses detected magnetite and lepidocrocite. Although the corrosion compounds of $H_2O$ grew into a spherical or plate-like shape after being affected by O ion, most of them were observed to have had spherical shapes, and the XRD and Raman analyses failed to detect corrosion compounds in them. It was found in the study that corrosion characteristics and compounds are diversely displayed according to the corrosion factor.

• Korean Journal of Heritage: History & Science
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• v.53 no.4
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• pp.216-233
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• 2020

This study set out to review tomb culture in the Gyeongju region during the Bronze Age, and also examine the patterns of dolmens during their end phase. For these purposes, the study analyzed 18 tomb relics from the Bronze Age and nine from the early Iron Age. Gyeongju belongs to the Geomdan-ri cultural zone. Approximately 120 tombs from the Bronze Age have been excavated in the Gyeongju region. There are fewer tombs than dwellings in the region, which is a general characteristic of the Geomdan-ri cultural zone. Although the number of tombs is small, the detailed structure of the dead body is varied. During the Bronze Age, tombs in the Gyeongju region were characterized by more prolific construction of pit tombs, dolmens with boundaries, and stacked stone altars than were the cases in other areas. There is a great possibility that the pit tombs in the Gyeongju region were influenced by their counterparts in the northeastern parts of North Korea, given the spindle whorl artifacts buried at the Dongsan-ri sites. Dolmens with boundaries and stacked stone altars are usually distributed in the Songguk-ri cultural zone, and it is peculiar that instances of these are found in large numbers in the Gyeongju region as part of the Geomdanri cultural zone. Even in the early Iron Age, the building of dolmens with boundaries and stacked stone altars continued in the Gyeongju region under the influence of the Bronze Age. A new group of people moved into the area, and they crafted ring-rimmed pottery and built wooden coffin tombs. In the early Iron Age, new rituals performed in high places also appeared, and were likely to provide venues for memorial services for heavenly gods in town-center areas. The Hwacheon-ri Mt. 251-1 relic and the Jukdong-ri relic are ruins that exhibit the aspect of rituals performed in high places well. In these rituals performed in high places, a stacked stone altar was built with the same form as the dolmens with boundaries, and a similar rock to the cover stone of a dolmen was used. People continued to build and use dolmens with boundaries and stacked stone altars while sustaining the Bronze Age traditions, even into the early Iron Age, because the authority of dolmens was maintained. Some dolmens with boundaries and stacked stone altars, known as being Bronze Age in origin, would have continued to be used in ritual practices until the early Iron Age. Entering the latter half of the second century B.C., wooden coffin tombs began to propagate. This was the time when the southern provinces, including the Gyeongju region, were included in the East Asian network, with the spread of ironware culture and the arrival of artifacts from central China. Around this time, dolmen culture faded into history with a new era beginning in its place.

• Korean Journal of Heritage: History & Science
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• v.51 no.4
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• pp.224-233
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• 2018

Thirty-three Early Iron Age bronzes at the sites of Hoam-dong in Chungju and Cheongsong-ri in Buyeo were investigated in order to study the manufacturing technique and the provenance of lead. Chemical analysis using X-ray fluorescence showed that 33 bronzes consist of copper(Cu), tin(Sn) and lead(Pb) served as major elements. Major and minor elemental analyses by EPMA were performed on two mirrors and 2 weapons of the bronzes investigated. The results shows that bronze mirrors from Chungju and Buyeo were high-tin bronzes(> 30 wt%). And 20% of tin and 5% of lead were founded in bronze weapons. Iron, zinc, arsenic, silver, nickel, sulfur and cobalt detected in four bronzes as minor and trace elements. The four bronzes were alloyed considering their function and were not heat treated after casting due to their high tin content. Lead isotope analysis using TIMS indicates that thirty-three bronzes were distributed southern Korea peninsula except Zone 1. As a result, lead raw materials came from various regions in Korean Peninsula not from Gyeongsang-do regions. The manufacturing techniques of bronze ware generalized at this age, and bronze was produced in various sites using raw materials from various sources.

• Conservation Science in Museum
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• v.7
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• pp.11-24
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• 2006

Plate armour is an important cultural property that reflects the ancient weaponry and the manufacturing technology of ironware as they are. Among the kinds of iron armour, horizontal plate armour has been very rarely excavated, and there are a few artifacts in their unimpaired shape like the plate armour excavated from Mangisanseong. This report reviews the manufacturing technology of ancient plate armour through its radiograph using appliable nondestructive irradiation and scientific conservation treatment. The seven-tiered plate armour excavated from Mangisanseong has ring hinge to open and shut the right side neck guard. The readout result of radiograph proved iron safety guard of Godaepan (a plate that links neck plate and horizontal plate) and leather safety guard of the right armpit with plate overlap and perforation interval; perforations that seem to have linked shoulder strap on wearing the armour are also observed. In particular, it is identified that the perforation and riveting technique avoided the connection of more than three plates with a rivet. This is an important material to illustrate the best use of function of plate armour overcoming its limit.

• Journal of the Architectural Institute of Korea Planning & Design
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• v.36 no.5
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• pp.117-124
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• 2020

This study examined ornamental metals used as architectural members among metal artifacts excavated from ancient Buddhist temples and palaces in Korea. Through this, we approached the decorative characteristics of ancient architecture eaves. 1. The decorations used in eaves of Korean ancient architecture include roof-end tiles and ornamental metal. Through excavation examples, the technique of attaching ornamental metal to the rafters and corner rafters of high-ranking architectures in the 7th and 8th centuries (ornamental metal for rafter end, ornamental metal for corner rafter end), and tosu iron in the 10th century It seems to be fashionable. 2. Several buildings were built in ancient Buddhist temples and palaces. At this time, they differentiated ornamental metal according to the hierarchy of the building. The higher the hierarchy, the greater the difference in the number of ornamental metal installations, materials, and decoration techniques. In addition, ornamental metal used in eaves is an important factor in the discrimination of the times as the type, number of members, and patterns change depending on the era. 3. The great feature of the eaves metal decoration excavated in the 7th and 8th centuries is the attachment of ornamental metal to the rafters and horsetails. This seems to create a sense of grandeur by removing the weight of the roof and giving the impression constructed regardless of gravity by supporting it with non-material materials.

• Korean Journal of Heritage: History & Science
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• v.36
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• pp.157-179
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• 2003

The smith's tool is a tool used for the forging that directly heat-treats and treats ironware. Smith's tools have been thus far excavated from 58 archaeologic sites in Korea, which include 46 hammers, 40 nippers, 5 tweezers, 17 chisels, and 12 anvils, totaling to 120 items. The historic sites from which smith's tools have been excavated indicate 2 sites in Nangnang, 6 in Goguryo, 30 in Silla, 3 in Baekjae, 15 in Gaya, and other 2 sites. Those smith's tools excavated from tumuli in the Three Kingdoms period in Korea are known to be those from the Silla and Gaya areas, and some have been found in the Goguryo and Baekjae areas but require more accumulation of artifacts. Furthermore, the result of having investigated those smith's tools burnt with the corpse in tumulus revealed that smith's tool owners are classified into the blacksmiths who were directly engaged in manufacture and the ruling class who controlled them. Moreover, the smith's tools excavated from large-sized tumulus are presumed to have the potential that symbolically exhibits smithy-iron working, as compared with other funerary objects. Key words: smith's tool, blacksmith, manager.

• KOMUNHWA
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• no.69
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• pp.63-89
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• 2007

The Archaeological sites of so called Round Clay Rim Pottery (Jeomtodaetogi : 점토대토기) culture in Kangwon region have been rarely excavated in proper form. Since most cases belong to those of ground surface gatherings, it is difficult to certify the nature and the association with other artifacts. Therefore, researches on that culture have been limited to simply set the chronological order in the Bronze Age in realtion with the Plain Pottery culture. However, a comparative study trying to explain the Round Clay Rim Pottery culture in both Yeongseo(영서) and Yeongdong(영동) has become possible thanks to recent excavation results from the sites of Chilgeon-dong(칠전동) in Chunchon City(춘천시) and Songrim-ri(송림리) in Kangneung City(강릉시), for example. Certain difference can be observed in form and amount of artifacts in between Yeongseo and Yeongdong. Such difference can be seen as individual localization in different places diffused from a common source, rather than showing different stages of unilineal developmental process of one culture. The Round Clay Rim Pottery culture seems to have been coexisted with the Rim-Perforated Pottery(공렬토기) and Dolmen(지석묘) culture. According to the radiocarbondatings, the upper time limit of the Round Clay Rim Pottery culture goes back considerably beyond the alleged upper limit of either the late fourth century or the second century B.C.. However, both cultures absorbed into the Iron Culture during the same period.

• Journal of Conservation Science
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• v.33 no.4
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• pp.241-254
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• 2017

The Stone Guardian and Memorial Tablets from the Muryeong Royal Tomb are composed of the same kind of plutonic igneous rocks, the so-called hornblendite. Color of the rocks show greenish gray, and both of them occurred with medium-grained granular texture. The rock-forming minerals composed mainly of amphibole and plagioclase. Magnetic susceptibility of the Stone Guardian is 0.15 to 0.63 (mean $0.42{\times}10^{-3}SI\;unit$), the King's Stone Memorial Tablet is 0.11 to 0.38 (mean $0.24{\times}10^{-3}SI\;unit$) and the Queen's Stone Memorial Tablet ranges from 0.10 to 0.33 (mean $0.18{\times}10^{-3}SI\;unit$). The rocks of the artifacts are hard to find in the Gongju area. Large scaled out crop of hornblendite is not distributed, but found in many places that the form of dike. The lithology and occurrences indicate that the artifacts are made of plutonic rock rather than dike. Reddish brown and pale brown contaminants, are also distributed on the surface of the Stone Guardian and Memorial Tablets. The reddish brown color is due to Fe oxide, and the pale brown color occurs due to the elution of Ca. The reddish brown contaminants are influenced by the internal components of the rock and oxidation of burial iron accessories. In contrast, the pale brown contaminants are considered to have flown from the carbonate materials used in the Royal Tomb, with a little added Fe oxide. Physical and chemical deterioration operate intricately in the Stone Guardian and Memorial Tablets. Physical deterioration is extremely rare and chemical deterioration is stable except for a part of the Stone Guardian and the front of the Queen Stone Memorial Tablet.