• Mass Spectrometry Letters
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• 제1권1호
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• pp.33-36
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• 2010

Wood charcoal was investigated to determine its potential as an alternative matrix for matrix-assisted laser desorption/ionization of various samples. Wood charcoal was an effective matrix for analyzing glucose, sucrose, arginine, and polyethylene glycols (PEGs), with detection levels of 100 pmol for glucose, 1 nmol for sucrose, 100 pmol for arginine, 100 pmol for PEG 400, 1 pmol for PEG 1540, and 10 pmol for PEG 3350. No analyte signal was observed for peptides or proteins.

• 오토저널
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• 제13권5호
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• pp.89-94
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• 1991

In the quantitative analysis of oxygenated exhaust emissions (unburned methanol, formal- dehyde) from methanol fueled vehicles, the oxygen contained in oxygenated exhaust gases lowers the FID (Flame Ionization Detector) response factor of conventional THC analyzer and leads to erroneous HC reading. For correct measurement of various HCs including oxygenated HCs emitted from FFV(Flexible Fuel Vehicle), first of all, the measurement technique of real HC emissions should be established. GC and HPLC-DNPH measuring methods specified by the EPA are used in this paper to analyze unburned methanol and formaldehyde components in the exhaust emissions. In emission test of FFV, unburned methanol and formaldehyde are emitted mostly during cold transient period, and it is shown that formaldehyde emission level is proportional to engine displacements. In view of the HC emission level, vehicle using M85 has 40% advantage over gasoline-fueled vehicle in OMHCE and has a good potential of a low emission vehicle.

• 한국자동차공학회논문집
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• 제11권2호
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• pp.22-30
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• 2003

Engine-out HC emissions were investigated during cold and hot start. The tests were conducted according to engine cooling temperatures which were controlled by simulated coolant temperatures of cold and hot start, on a 1.5L, 4-cylinder, 16 valve, multipoint-port-fuel-injection gasoline engine. Real time engine-out HC emissions were measured at a exhaust port and cylinder head using Fast Response Flame Ionization Detector(FRFID). Unburned hydrocarbons emitted at the cold coolant temperature were much higher than those of the hot coolant temperatures. And the main source of the high HC emission was confirmed as misfire at cold coolant temperature. In addition, the effect of intake valve timing on engine-out HC emissions was investigated. The results obtained indicate that optimized intake phasing provides the potential for start-up engine-out HC emissions reduction.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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• pp.167-170
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• 2005

The mechanism of striation in the coplanar- and matrix-type plasma display panel (PDP) cells has been studied using the particle-in-cell Monte-Carlo Collision (PIC-MCC) model. The striation formation is related to the ionization energy of neutral atoms and the well-like deformation of space potential by space charge distribution. Negative wall charge accumulation by electrons on the MgO surface of the anode region is also one of the key factors for the formation of striation. The clearness of the striation phenomenon in PIC-MCC code in comparison with fluid code can be explained by using nonlocal electron kinetic effect.

• Bulletin of the Korean Chemical Society
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• 제23권10호
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• pp.1389-1393
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• 2002

The non-spectroscopic interference effects that occurred in inductively coupled plasma/mass spectrometry were studied for Ge, As and Se in human urine and serum. Many biological samples contain Na, K, Cl and organic compounds, which may cause the enhancement and depression on the analyte signal. The effect of 1% concomitant elements such as N, Cl, S, P, C, Na, and K on a 100 ㎍/L germanium, arsenic and selenium signal has been investigated by ICP/MS. The interference effects were not in the same direction. It appeared that concomitant elements such as Cl, S, and C induce an enhancement effect, whereas N and P did not show any significant effect. And, Na and K caused a depression. We have found a link between the abundance of analytes and the ionization potential of concomitant elements (eV), except carbon and nitrogen.

• Fibers and Polymers
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• 제3권4호
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• pp.140-146
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• 2002

Non-genotoxic diamines 2,2'-dimethyl-5,5'-dipropoxybenzidine and 5,5'-dipropoxy-benzidine were employed as potential alternatives to benzidine in the synthesis and evaluation of new direct dyes for cotton. Assessment of the resultant dyes indicated that both diamines can be used to prepare new direct dyes having colors and fastness properties that make them comparable to commercial direct dyes, and that the structures of the new direct dyes can be confirmed by negative ion electrospray mass spectrometry (ESMS). The mutagenic properties of new direct dyes were established using the standard Ames Salmonella mammalian mutagenicity assay.

• 전기학회논문지
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• 제59권7호
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• pp.1276-1281
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• 2010

To analyze the gas discharge phenomena in parallel-plane electrodes, the fully coupled finite element method (FEM) considering secondary electron emission effects in discharge column was adopted in this paper. Two coupled equations of the hydrodynamic diffusion-drift equations for three carriers and the Poisson's equation for electric scalar potential should be solved as a system equation. The proposed method including two secondary electron processes of the photoemission and background ionization has been successfully applied to evaluating the breakdown voltage in parallel-plane electrodes and is verified by comparing its numerical results with the experimental ones. From the obtained results, it is inferred that the proposed numerical scheme will be useful for predicting and understanding streamer transient phenomena.

• 전기학회논문지
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• 제61권12호
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• pp.1872-1876
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• 2012

A calculation method of the breakdown voltage for the drain region with the cylindrical structure in LDMOS is proposed. The depletion region of the drain is divided into many smaller regions and the doping concentration of each split region is assumed to be uniformly distributed. The field and potential in each split region is calculated by the integration of the Poisson equation and the ionization integral method is used to compute the breakdown voltage. The breakdown voltage resulted from the proposed method shows the maximum relative error of 2.2% compared with the result of the 2-dimensional device simulation using BANDIS.

• 한국전기전자재료학회논문지
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• 제11권7호
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• pp.571-580
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• 1998

The numerical model that can describe the ignition of pseudospark discharge using hybrid fluid-particle(Monte Carlo )method has been developed. This model consists of the fluid expression for transport of electrons and ions and Poisson's equation in the electric field. The fluid equation determines the spatiotemporal dependence of charged particle densities and the ionization source term is computed using the Monte carlo method. This model has been used to study the evolution of a discharge in Argon at 0.5 torr, with an applied voltage if 1kV. The evolution process of the discharge has been divided into four phases along the potential distribution : (1) Townsend discharge, (2) plasma formation, (3) onset of hollow cathode effect, (4) plasma expansion. From the numerical results, the physical mechanisms that lead to the rapid rise in current associated with the onset of pseudospark could be identified.

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3693-3696
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• 2010

We experimentally measure the kinetic energy and angular distributions of photoelectrons of $N_2$ as a function of 410 nm femtosecond laser intensity by using velocity map imaging technique. The strong-field multiphoton ionization of molecules shares many of the characteristics with those of atoms. Electron kinetic energies are nearly independent of laser intensities. The independence suggests that the electron peaks in the photoelectron spectrum actually result from a two-step process, indicative of the occurrence of real population in the intermediate states. The relative amplitudes of electron peaks indicate that in the two-step process, nonresonant population transfer dominates for low intensities, while resonant population transfer dominates for higher intensities.