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http://dx.doi.org/10.5012/bkcs.2002.23.10.1389

The Matrix Effect of Biological Concomitant Element on the Signal Intensity of Ge, As, And Se in Inductively Coupled Plasma/Mass Spectrometry  

Park, Kyung-Su
Kim, Sun-Tae
Kim, Young-Man
Kim, Yun-je
Lee, Won
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.10, 2002 , pp. 1389-1393 More about this Journal
Abstract
The non-spectroscopic interference effects that occurred in inductively coupled plasma/mass spectrometry were studied for Ge, As and Se in human urine and serum. Many biological samples contain Na, K, Cl and organic compounds, which may cause the enhancement and depression on the analyte signal. The effect of 1% concomitant elements such as N, Cl, S, P, C, Na, and K on a 100 ㎍/L germanium, arsenic and selenium signal has been investigated by ICP/MS. The interference effects were not in the same direction. It appeared that concomitant elements such as Cl, S, and C induce an enhancement effect, whereas N and P did not show any significant effect. And, Na and K caused a depression. We have found a link between the abundance of analytes and the ionization potential of concomitant elements (eV), except carbon and nitrogen.
Keywords
Matrix effect; Serum; Urine; ICP/MS;
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1 Munro, S.; Ebdon, L.; McWeeny, D. J. J. Anal. At. Spectrom. 1986, 1, 211.   DOI
2 Abdallah, M. H.; Mermet, J. M. J. Quant. Spectrosc. Radiat. Transfer 1978, 19, 83.   DOI   ScienceOn
3 Alves, L. C.; Wiederin, D. R.; Houk, R. S. Anal. Chem. 1992, 64, 1164.   DOI
4 Branch, S.; Ebdon, L.; Ford, M.; Foulkes, M.; Oneill, P. J. Anal. At. Spectrom. 1991, 6, 151.   DOI
5 Gray, A. L. Spectrochim. Acta, Part B 1986, 41, 151.   DOI   ScienceOn
6 McLaren, J. W.; Beauchemin, D.; Berman, S. S. J. Anal. At. Spectrom. 1987, 2, 277.   DOI
7 Lyon, T. D. B.; Fell, G. S.; Hutton, R. C.; Eaton, A. N. J. Anal. At. Spectrom. 1988, 3, 265.   DOI
8 Doherty, W. Spectrochim. Acta, Part B 1989, 44, 263.   DOI   ScienceOn
9 Gilson, G. R.; Douglas, D. J.; Fulford, J. E.; Halligan, K. W.; Tanner, S. D. Anal. Chem. 1988, 60, 1472.   DOI
10 Olivares, J. A.; Houk, R. S. Anal. Chem. 1986, 58, 20.   DOI
11 Ridout, P. S.; Jones, H. R.; Williams, J. G. Analyst 1988, 113, 1383.   DOI
12 Buckley, W. T.; Budac, J. J.; Godfrey, D. V.; Koenig, K. M. Anal. Chem. 1992, 64, 299.
13 Beauchemin, D.; Mclaren, J. W.; Berman, S. S. Spectrochim. Acta, Part B 1987, 42, 467.   DOI   ScienceOn
14 Beauchemin, D.; Craig, J. M. Spectrochim. Acta, Part B 1991, 46, 603.   DOI   ScienceOn
15 Sheppard, B. S.; Caruso, J. A.; Heitkemper, D. T.; Wolnik, K. A. Analyst 1992, 117, 971.   DOI
16 Hansen, S. H.; Larsen, E. H.; Pritzl, G.; Cornett, C. J. Anal. At. Spectrom. 1992, 7, 629.   DOI
17 Thompson, J. J.; Houk, R. S. Appl. Spectrosc. 1987, 41, 801.   DOI   ScienceOn
18 Munro, S.; Ebdon, L.; McWeeny, D. J. J. Anal. At. Spectrom. 1986, 1, 211.   DOI
19 Tan, S. H.; Horlick, G. Appl. Spectrosc. 1986, 40, 445.   DOI   ScienceOn
20 Branch, S.; Corns, W. R.; Ebdon, L.; Hill, S.; Oneill, P. J. Anal. At. Spectrom. 1991, 6, 155.   DOI
21 Vanhoe, H.; Goossens, J.; Moens, L.; Dams, R. J. Anal. At. Spectrom. 1994, 9, 177.   DOI
22 Tan, S. H.; Horlick, G. Appl. Spectrosc. 1988, 40, 445.
23 Date, A. R.; Cheung, Y. Y.; Stuart, M. E. Spectrochim. Acta, Part B 1987, 42, 3.   DOI   ScienceOn
24 Gregoire, D. C. Spectrochim. Acta, Part B 1987, 42, 895.   DOI   ScienceOn
25 Evans, E. H.; Giglio, J. J. J. Anal. At. Spectrom. 1993, 8, 1.   DOI
26 Vanhaecke, F.; Vanhoe, H.; Dams, R.; Vandecasteele, C. Talanta 1992, 39, 373.
27 Evans, E. H.; Ebdon, L. J. Anal. At. Spectrom. 1990, 5, 425.   DOI
28 Evans, E. H.; Ebdon, L. J. Anal. At. Spectrom. 1989, 4, 299.   DOI
29 Vaughan, M. A.; Horlick, G. Appl. Spectrosc. 1986, 40, 434.   DOI   ScienceOn
30 Lyon, T. D. B.; Fell, G. S.; Hutton, R. C.; Eaton, A. N. J. Anal. At. Spectrom. 1988, 3, 601.   DOI
31 Amarasiriwardena, C. J.; Lupoli, N.; Korrick, S.; Hu, H.; Potula, V. Analyst 1998, 123, 441.   DOI   ScienceOn