• Title/Summary/Keyword: Ionization potential

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A spectroscopic study of the effect of humidity on the atmospheric pressure helium plasma jets

  • Han, Duksun
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1375-1380
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    • 2018
  • Atmospheric-pressure plasma has a great potential in many applications due to its simplicity rather than low pressure plasmas. In material processing, biomedical applications, and many other applications, the input power, gas flow rate, and the geometry of electrode have been mainly considered and studied as important external parameters of atmospheric-pressure plasma control. Besides, since the atmospheric-pressure plasmas are typically generated in an open air, the relative humidity is difficult to control and can change day by day. Therefore, the relative humidity cannot be ignored for plasmas. Thus, in this work, the atmospheric-pressure plasma jet was characterized by changing relative humidity, and it was found that the increase in electron density and OH radicals are due to Penning ionization between helium metastable and water vapors at higher humidity condition.

Growth of and Bacterial Counts on Several Edible Sprouts Exposed to Spray Ionization (음이온 처리된 몇 가지 새싹채소의 생장과 세균 수)

  • Song, Min-Jeong;Jeon, Yu-Min;Oh, Myung-Min
    • Journal of Bio-Environment Control
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    • v.24 no.1
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    • pp.45-50
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    • 2015
  • Edible sprouts are highly nutritious, containing numerous health-promoting phytochemicals and nutrients. However, the process of sprouting is subject to potential contamination by microorganisms attached to the seed coat. The objective of this study was to determine the effects of air anions generated by spray ionization on growth and sterilization of edible sprouts. Treatment with air anions has positive effects on plant growth and sterilization in 4 kinds of sprouts. Hypocotyl length in red cabbage and kale increased approximately 1.26-fold and radicle length of lettuce, red cabbage, and kale increased 1.4 to 1.6-fold compared to the control. The fresh weight of sprouts in the spray-ionization treatment was significantly (16.0-38.5%) higher than that of the controls. Radicle activity in sprouts exposed to anions was higher than that of the control in all species. Bacterial counts on lettuce, red cabbage, and tatsoi decreased significantly (by 41%, 66%, and 19%, respectively), and bacterial colonies also declined in drainage water. Our findings suggest that spray-ionization treatment is useful for improving sprout growth and for sterilizing sprouts.

A Study of De-electrification Characteristics of Charged Body By Soft X-Ray Ionizer (연X선 Ionizer에 의한 대전물체의 제전특성에 관한 연구)

  • 이동훈
    • Journal of the Korean Society of Safety
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    • v.13 no.3
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    • pp.67-73
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    • 1998
  • The technology for neutralizing static electricity by soft X-ray radiation has been newly developed. This technology involves ionization of gas molecules in the vicinity of a charged substrate to generate ions and electrons to reduce electrostatic potential. The ULSI device substrate and liquid crystal display substrate tend to get charged instantly to a high potential level when they are handled in the manufacturing process. Soft X-ray radiation is adequate in air or $O_2$ gas at atmospheric pressure. This newly developed neutralization method is effective to be superior to the conventional technique, i.e., an ionizer by using corona discharge ,in every aspect. The new method features excellent neutralization capability and is able to completely reduce electrostatic potential to 0 V within a short time. Moreover, this is a very clean antistatic technology free from particle generation ,ozone generation, and electromagnetic noise, which are problems in using the corona discharge ionizer.

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A Potential Application of Ge (Li) Detectors in Fast Neutron Leakage Spectrum Determination

  • Kang, Chang-Sun
    • Nuclear Engineering and Technology
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    • v.11 no.2
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    • pp.133-136
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    • 1979
  • In the paper it is proposed to use Ge(Li) detectors in determining fast neutron spectra. The spectrum at 691.4 KeV which is produced by the internal conversion of Ge nuclei being broadened by the coincident ionization energy deposited by recoil Ge atoms is proposed to be analysed in estimating the fast neutron spectra.

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The isobaric effect correction and measurement of the Ru isotopes by thermal ionization mass spectrometry (열 이온화 질량분석기를 이용한 Ru 동위원소 측정 및 동중원소 영향 보정)

  • Jeon, Young-Shin;Kim, Jung-Suk;Han, Sun-Ho;Song, Kyu-Seok
    • Analytical Science and Technology
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    • v.23 no.5
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    • pp.498-504
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    • 2010
  • It is very difficult to get stable ion peak intensity of ruthenium by thermal ionization mass spectrometry because of its high ionization potential and high volatility of its oxides which causes to lose much of ruthenium ions, so the intensity of the signal decrease quickly. Accordingly, a study was performed in oder to increase the ionization efficiency and to prevent sample losses due to volatilization and to check with isobaric effect by impurities in filament for the measurement of ruthenium isotopes. Both single filament and double filament were tested. The former was proved to be more efficient for the stable and strong intensity of signal and revealed less isobaric effect from the molybdenum (Mo) as a filament impurity. Also, when the temperature of filament increased too high, the isobaric effect from Mo greatly appeared. That is, Mo impurity from filament gave a serious effect for measuring the ruthenium isotopes. It was proved to be of importance that filament current should be slowly increased with time interval. Finally, ruthenium isotopes were accurately measured by correction with measuring $^{94}Mo/^{99}Ru$.

Numerical Modeling of Very High Frequency Multi Hollow Cathode PECVD (Very High Frequency Multi Hollow Cathode PECVD 장치의 수치모델링)

  • Joo, Jung-Hoon
    • Journal of the Korean Vacuum Society
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    • v.19 no.5
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    • pp.331-340
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    • 2010
  • 3D fluid based numerical modelling is done for a VHF multi hollow cathode array plasma enhanced chemical vapor deposition system. In order to understand the fundamental characteristics of it, Ar plasma is analyzed with a condition of 40 MHz, 100 Vrf and 1 Torr. For hole array of 6 mm diameter and 20 mm inter-hole distance, plasma is well confined within the hole at an electrode gap of 10 mm. The peak plasma density was $5{\times}10^{11}#/cm^3$ at the center of the hole. When the substrate was assumed at ground potential, electron temperature showed a peak at the vicinity of the grounded walls including the substrate and chamber walls. The reaction rate of metastable based two step ionization was 10 times higher than the direct electron impact ionization at this condition. For $H_2$, the spatial localization of discharge is harder to get than Ar due to various pathways of electron impact reactions other than ionization.

Novel analysis procedure for red ginseng polysaccharides by matrix-assisted laser desorption/ionization time-of-flight/time-offlight mass spectrometry

  • Jin, Ye Rin;Oh, Myung Jin;Yuk, Heung Joo;An, Hyun Joo;Kim, Dong Seon
    • Journal of Ginseng Research
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    • v.45 no.5
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    • pp.539-545
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    • 2021
  • Background: Red ginseng polysaccharides (RGPs) have been acknowledged for their outstanding immunomodulation and anti-tumor activities. However, their studies are still limited by the complexity of their structural features, the absence of purification and enrichment methods, and the rarity of the analytical instruments that apply to the analysis of such macromolecules. Thus, this study is an attempt to establish a new mass spectrometry (MS)-based analysis procedure for RGPs. Methods: Saponin pre-excluded powder of RG (RG-SPEP, 10 mg) was treated with 200 µL of distilled water and centrifuged for 5 h at 1000 rpm and 85 ℃. Ethanol-based precipitation and centrifugation were applied to obtain RGPs from the heated extracts. Further, endo-carbohydrase treatments were performed to produce specific saccharide fragments. Solid-phase extraction (SPE) processes were implemented to purify and enrich the enzyme-treated RGPs, while matrix-assisted laser desorption/ionization time-of-flight/time-of-flight (MALDI-TOF/TOF) MS was employed for the partial structural analysis of the obtained RGPs. Results: Utilizing cellulase, porous graphitized carbon (PGC), hydrophilic interaction chromatography (HILIC), and MALDI-TOF/TOF MS, the neutral and acidic RGPs were qualitatively analyzed. Hexn and Hexn-18 (cellulose analogs) were determined to be novel neutral RGPs. Additionally, the [Unknown + Hexn] species were also determined as new acidic RGPs. Furthermore, HexAn (H) was determined as another form of the acidic RGPs. Conclusion: Compared to the previous methods of analysis, these unprecedented applications of HILIC-SPE and MALDI-TOF/TOF MS to analyze RGPs proved to be fairly effective for fractionating and detecting neutral and acidic components. This new procedure exhibits great potential as a specific tool for searching and determining various polysaccharides in many herbal medicines.

MALDI Mass Spectrometric Analysis of Nonderivatized Steroids Using Cyclodextrin-supported 2,5-Dihydroxybenzoic Acid as Matrix

  • Son, Jeongjin;Cha, Sangwon
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1409-1412
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    • 2014
  • Sex hormones are important metabolites in vertebrates' development and reproduction. For rapid screening sex hormones, matrix-assisted laser desorption/ionization (MALDI) mass spectrometry (MS) is one of the promising analytical platforms, but MALDI MS faces many challenges in detecting steroids such as low ionization efficiency and matrix background interference. One potential strategy to overcome matrix interference in the low m/z region is using a cyclodextrin (CD)-supported matrix for steroid analysis since CD-supported matrixes are known to effectively suppress matrix-related ion signals. In this study, we aimed to find the optimal CD-supported matrix for the analysis of the nonderivatized sex steroids. Our results showed that the ${\alpha}CD$-supported 2,5-dihydroxybenzoic acid (DHB) matrix efficiently ionized all three major classes of sex hormones, estrogens, androgens, and progestagens, with low or no matrix background and also with high sensitivity. In addition, the ${\alpha}CD$-supported DHB matrix mainly generated molecular ions or protonated ions of sex hormones, and this enabled us to obtain information-rich tandem mass spectra which potentially lead to unambiguous identification of steroid species from complex metabolite mixtures.

Instability of Magnetized Ionization Fronts

  • Kim, Woong-Tae;Kim, Jeong-Gyu
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.78.1-78.1
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    • 2014
  • An ionization front (IF) surrounding an H II region is a sharp interface through which a cold neutral gas makes transition to a warm ionized phase by absorbing UV photons from central massive stars. We investigate the structure and instability of a plane-parallel D-type IF threaded by magnetic fields parallel to the front. We find that magnetic fields increase the maximum propagation speed of the IFs, while reducing the expansion factor, defined as the density ratio of neutral to ionized phases. IFs become unstable to distortional perturbations due to gas expansion across the fronts, exactly analogous to the Darrieus-Landau instability of ablation fronts in terrestrial flames. The growth rate of the IF instability is proportional linearly to the perturbation wavenumber as well as the upstream flow speed. The IF instability is stabilized by gas compressibility and becomes completely quenched when the front is D-critical. The instability is also stabilized by magnetic pressure when the perturbations propagate in the direction perpendicular to the fields. When the perturbations propagate in the direction parallel to the fields, on the other hand, it is magnetic tension that reduces the growth rate, completely suppressing the instability when ${\beta}$ < 1.5, with ${\beta}$ denoting the square of the ratio of the sound speed to the Alfven speed in the pre-IF region. When the front experiences an acceleration, the IF instability cooperates with the Rayleigh-Taylor instability to make the front more unstable. We discuss potential effects of IF instability on the evolution and dynamics of IFs in the interstellar medium.

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