• Bulletin of the Korean Chemical Society
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• 제33권9호
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• pp.2955-2960
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• 2012

Product ion yields in the in- and post-source decays of three peptide ions, $[Y_5X+H]^+$ (X = Y (tyrosine), K (lysine), and R (arginine)), generated by matrix-assisted laser desorption ionization (MALDI) were measured at six wavelengths, 307, 317, 327, 337, 347, and 357 nm, using ${\alpha}$-cyano-4-hydroxycinnamic acid (CHCA) and 2,5-dihydroxybenzoic acid (DHB) as the matrices. The temperatures of the early and late plumes generated by MALDI were estimated via kinetic analysis of the product ion yield data. For both matrices, the temperature drop (${\Delta}T$), i.e. the difference in the temperature between the early and late plumes, displayed negative correlation with the absorption coefficient. This was in agreement with the previous reasoning that deeper laser penetration and larger amount of material ablation arising from smaller absorption coefficient would result in larger extent of expansion cooling. The results support the postulation of the expansion cooling occurring in the plume presented previously.

• 전기의세계
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• 제28권4호
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• pp.39-46
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• 1979

The effective ionization coefficient in $SF_{6}$/$N_{2}$ mixtures was attempted to derive from the pure gases. Measurements of static breakdown voltage were made under the uniform field at pressures up to 4 bar in order to compare with the results obtained from this assumption. The relative performance of $SF_{6}$/$N_{2}$ mixtures to pure $SF_{6}$ was also investigated. The effect of surface roughness on discharge thresholds in $SF_{6}$/$N_{2}$ mixtures was calculated employing the simplified model and mesurements of breakdown voltages for a gap with an artificial protrustion were also made. The experimental results show that the effective ionization coefficient in gas mixtures can not be reliably estimated from the values measured for the pure gases. Therefore, basic parameters for $SF_{6}$/$N_{2}$ mixtures must be measured by investigation of the mixtures themselves. The relative performance of mixtures to pure $SF_{6}$ could be considered with the values of pR.

• 약학회지
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• 제22권3호
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• pp.157-162
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• 1978

Total organic carbon(TOC) can be determined by means of combustion and flame ionization detector. The principle of string method is that a sample acidified to pH2 and transferred into combustion tube by string is oxidized with air. Another combustion tube method is that organic compounds are oxidized in the combustion tube charged with CuO and cobalt asbestos after the acidified sample is injected directly by microsyringe. Carbon dioxide evolved was reduced under specially treated nickel catalyst and hydrogen, the methane produced was detected by flame ionization detector. Linear relationship was found between concentration and the peak height by the string method. The peak area in the case of combustion tube method is in the range of 1-200ppm. The coefficient of variation by string method was 2.3% and that by combustion tube method was 1.8%. The lower detectable limit was about 10mol. Advantages of the latter are simplicity, sensitivity and reproducibility. TOC in contineous stream can also be determined automatically by means of the string method.

• 조명전기설비학회논문지
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• 제22권8호
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• pp.104-108
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• 2008

플라즈마 현상의 정량적 이해를 위해서는 원자나 분자기체가 가지고 있는 정확한 전자충돌단면적과 그 전자수송 계수의 값을 필요로 한다. 본 연구에서 사용하고 있는 Kr과 Xe 원자기체는 PDP와 무전각램프 등 다양한 산업 응용분야에 이용되고 있다. 따라서 2항 근사 볼츠만 해석에 의해 기체압력 1[torr]의 조건에 $0.001{\sim}500$[Td]의 광범위한 E/N에서 순수 Kr과 Xe 원자기체의 전자이동속도 W, 종 횡축확산계수 $ND_L$과 $ND_T$, 전리계수 $\alpha$/N의 전자수송 계수를 계산하고 물성 해석하였다.

• Mass Spectrometry Letters
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• 제15권1호
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• pp.54-61
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• 2024

An improved voltage modulation method (VMM) was used to control the heat release and adsorption properties of the adsorbent. In this work, the voltage and flux modulation methods were considered under unified experimental conditions of dissociative surface ionization (SI) of polyatomic organic molecules, the criteria were found when under VMM conditions the current relaxation of SI carries information about the kinetic properties of thermal desorption of ionizable dissociation particles arriving on the surface of polyatomic molecules. Conditions were found under which the relaxation of the ionic current in the flux modulation method is determined by the kinetics of the heterogeneous dissociation reaction of the original polyatomic molecules. The values of the thermal desorption rate constant K⁺ and the activation energy E⁺ obtained with VMM for desorption of (CH₃)₂NCH⁺₂ ions with m/z 58 by adsorption of imipramine and amitriptyline molecules agree well with each other and with the results for the desorption of the same ions by adsorption of other molecules. This confirms one of the basic conditions for the equilibrium process SI - the a degree (β coefficient) of the same particles SI on the same emitter surface is the same and does not depend on the way these particles are formed on the emitter surface.

• 한국방사선학회논문지
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• 제10권8호
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• pp.591-596
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• 2016

본 연구의 목적은 실험으로 6 MV X-선 빔의 등가에너지를 결정하는 데 있다. 6 MV X-선 빔에 대한 납의 반가층은 전리함을 사용하여 측정하였다. 선감쇠계수는 측정된 반가층을 사용하여 계산하였다. 그리고 질량감쇠계수는 납의 밀도로 선감쇠계수를 나누어 얻었다. 얻어진 질량감쇠계수의 등가에너지는 미국표준기술연구소에서 주어진 납의 광자에너지 대 질량감쇠계수 자료를 사용하여 결정하였다. 그 결과로서, 6 MV X-선 빔에 대한 등가에너지는 1.61 MeV로 결정되었다. 이 등가에너지는 Reft가 보고한 것 보다 약 30% 낮게 결정되었다. 그 원인은 납 감쇠기 사이의 공기공동의 존재에 기인한 것으로 추정된다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2009년도 제40회 하계학술대회
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• pp.1481_1482
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• 2009

Pure Xe, Kr and Ne atoms and Mixures of Xe-Ne used in fluorescent induction lamps(FILs). However standard regulation of FILs is not made up until now. Therefore, the electron transport coefficients, the electron drift velocity W, the longitudinal diffusion coefficient NDL and the ionization coefficient $\alpha$/N in pure Xe, Kr, Ne gases and Xe-Ne mixtures(1:9, 5:5, 7:3) were calculated over the wide E/N range from 0.01 to 500 Td at 1 Torr by two-term approximation of the Boltzman equation.

• 대한전자공학회논문지SD
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• 제45권6호
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• pp.22-27
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• 2008

4H-SiC의 전자와 정공의 이온화계수 $\alpha$와 $\beta$로부터 유효이온화계수 $\gamma$를 추출함으로써 4H-SiC 쇼트키 다이오드의 항복전압과 온-저항을 위한 해석적 모델을 유도하였다. 해석적 모델로부터 구한 항복전압을 실험 결과와 비교하였고, 도핑 농도 함수의 온-저항도 이미 발표된 결과와 비교하였다. 항복전압은 $10^{15}{\sim}10^{18}\;cm^{-3}$의 도핑 농도 범위에서 실험 결과와 10% 이내의 오차로 잘 일치하였다. 온-저항을 위한 해석적 결과는 $3{\times}10^{15}{\sim}2{\times}10^{16}\;cm^{-3}$의 범위에서 실험 결과와 매우 잘 일치하였다.

• Bulletin of the Korean Chemical Society
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• 제23권2호
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• pp.189-194
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• 2002

Two-photon resonant third photon ionization of atomic bromine $(4p^5\;^2P_{3/2}\;and\;^2P_{1/2})$ has been studied using a photoelectron imaging spectroscopy in the wavelength region 250 - 278 nm. The technique has yielded simultaneously both relative branching ratios to the three levels of $Br^+(^3P_2,\;^3P_{0.1}\;and^1D_2)$ with $4p^4$ configuration and the angular distributions of outgoing photoelectrons. The product branching ratios reveal a strong propensity to populate particular levels in many cases. Several pathways have been documented for selective formation of $Br^+(^3P_2)$ and $Br^+(^3P_{0.1})$ ions. In general, the final ion level distributions are dominated by the preservation of the ion core configuration of a resonant excited state. Some deviations from this simple picture are discussed in terms of the configuration interaction of resonant states and the autoionization in the continuum. The photoelectron angular distributions are qualitatively similar for all transitions, with a positive $A_2$ anisotropy coefficient of 1.0-2.0 and negligible $A_4$ in most cases, which suggests that the angular distribution is mainly determined by the single-photon ionization process of a resonant excited state induced from the third photon absorption.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2006년도 학술대회 논문집 전문대학교육위원
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• pp.159-162
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• 2006

In this paper energy distribution function in $SiH_4$ has been analysed over the E/N range 0.5${\sim}$300Td and Pressure value 0.5, 1.0, 2.5 Torr by a two-term approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, diffusion coefficient, electron ionization, mean energy and the electron energy distribution function. The electron energy distribution function has been analysed in $SiH_4$ at E/N=30, 50Td for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values.