• Title/Summary/Keyword: Ionic components

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Tolerance Range Analysis of Fish on Chemical Water Quality in Aquatic Ecosystems

  • Kim, Jeong-Kyu;Han, Jeong-Ho;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.43 no.4
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    • pp.459-470
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    • 2010
  • In this study, we analyzed fish tolerance guilds in mainstems and tributaries of 65 streams and rivers arid their relations to water quality using dataset sampled from April to November, 2009. For the study, water quality parameters including biochemical oxygen demand (BOD), electric conductivity (EC), total nitrogen (TN), total phosphorus (TP), ammonia nitrogen ($NH_3$-N), nitrate nitrogen ($NO_3$-N) and phosphate phosphorus ($PO_4$-P) were analyzed in the laboratory and also tolerance ranges in 3 category fishes of sensitive, intermediate, and tolerant species with high abundance were analyzed. According to fish guild analysis, tolerant species was 58% of the total community and the proportion of omnivore species was 63% of the total, indicating a degradation of habitats and water quality. Water quality was shown typical longitudinal gradients from the headwater to the down-river; TN and TP increased toward the down-rivers except for the big point-source area and ionic contents, based on, electric conductivity showed same pattern. Tolerance guild analysis of 9 major species with high abundance indicated that sensitive groups had narrower tolerance range in the water quality than the groups of intermediate and tolerant species. In contrast, tolerant groups including Zacco platypus, Carassius auratus, and Opsarichthys uncirostris amurensis had wider tolerance ranges than the groups of sensitive and intermediate species. Thus, each group was evidently segregated from the tolerance levels. Principal Component Analysis (PCA) employed for the relations of water quality to fish species in each groups suggests that water quality had highest eigenvalues with fish species in the 1st axis of the PCA and nitrogen (TN, $NH_3$-N, $NO_3$-N) and phosphorus (TP) were key components differentiating three groups of sensitive, intermediate and tolerance guilds.

A Study on the Extraction of Thermostable Pectinesterase from Valencia Orange (Valencia 오렌지로부터 내열성 Pectinesterase의 추출)

  • Hou, Won-Nyoung;Walker, Brigdet L.
    • Korean Journal of Food Science and Technology
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    • v.27 no.5
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    • pp.658-665
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    • 1995
  • Low yield of a thermostable pectinesterase(TSPE) from citrus fruits has made its detailed study extremely tedious and difficult; therefore, maximizing TSPE extraction is desirable. It is assumed that TSPE is bound to the cell components via ionic linkage and covalent bonds. Therefore, in this study, variations in extraction time, pH, NaCl concentration and commercial enzyme preparations were used to increase the yield of TSPE from Valencia orange. The largest recovery of TSPE, obtained by heating extracted pectinesterase(PE) at $70^{\circ}C\;for\;5{\sim}10$ minute, was achieved using actate buffer(pH 4.14) with 1 M NaCl and 0.2% $Cytolase^{TM}$ 104(a mixture of cellulase, hemicellulase and pectinase; Genecor, Inc). The two aquous phase partitioning with 5.0% Triton X-114 could be used as a tool for separation of thermolabile pectinesterase(TLPE) and TSPE from crude PE. Also, water extraction and $0{\sim}0.3$ ammonium sulfate fractionation could be used for removing non-pectinesterase protein.

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Skin Brightening Effect of Gel Essence Containing High Concentrated-Marine Minerals in Silicon Copolyol Network Film in vivo (고농도의 미네랄을 실리콘 네트워크 필름에 포집한 젤 에센스 제형의 피부 밝기 개선 효과)

  • Kim, Sun-Kyong;Kim, Young-So;Joo, Kyung-Mi;Kim, Eun-Joo;Lee, Ji-Eun;Chae, Byung-Gun;Cho, Jun-Cheol;Han, Sang-Hoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.37 no.3
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    • pp.283-288
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    • 2011
  • Since minerals are in ionic forms in aqueous phase (like deep sea water), it is very hard to incorporate concentrated minerals in gel like cosmetic formulations which are generally composed of carbomer or acrylates polymer. In this study, we invented a salt-resistant network formulation made of silicon copolyol. It was found that the network formulation traps minerals (especially from marine) in a mesh-like silicone copolyol structure. Since the mineral-containing formulation makes a very thin film on the skin, minerals could be easily absorbed into stratum corneum. In 6 weeks in vivo test, it was found that the novel mineral formulation increased the amounts of amino acids, major components of natural moisturizing factors (NMFs), as well as levels of minerals. It was also found that the moisture contents and the brightness of the skin increased.

Advanced Formulation and Pharmacological Activity of Hydrogel of the Titrated Extract of C. Asiatica

  • Hong Soon-Sun;Kim Jong-Ho;Li Hong;Shim Chang-Koo
    • Archives of Pharmacal Research
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    • v.28 no.4
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    • pp.502-508
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    • 2005
  • Titrated extract of Centella asiatica (TECA) contains three principal ingredients, asiaticoside (AS), asiatic acid (AA), and madecassic acid (MA). These components are known to be clinically effective on systemic scleroderma, abnormal scar formation, and keloids. However, one problem associated with administration of TECA is its low solubility in aqueous as well as oil medium. In this study, various nonionic surfactants and bile salts as anionic surfactant were tested and screened for solubilizing TECA with a view to developing topical hydrogel type of ointment which is stable physicochemically, and has better pharmacological effects. When TECA was incorporated into various nonionic surfactant systems, labrasol had the most potent capacity for solubilizing TECA. In cases of bile salt systems, Na-deoxycholate (Na-DOC) had foremost solubilizing capacity, even more than labrasol. In differential scanning calorimetric study, the peaks of AA, MA, AS and Na-DOC disappeared at the coprecipitate of $1\%$ TECA and $1\%$ Na-DOC, suggesting the optimum condition of Na-DOC for solubilizing TECA. When the physicochemical stability of hydrogel containing this mixture was assessed, it was stable at room temperature for at least one month. Pharmacologically it significantly decreased the size of wound area at the $9^{th}$ day when applied to the wound area of rat dorsal skin. Taken together, solubility of TECA was dramatically improved by using non ionic and anionic surfactant systems, and Na-DOC was found to be the most effective solubilizer of TECA in formulating a TECA-containing hydrogel typed ointment. Moreover this gel was considered to be applicable to clinical use for wound healing effect.

Composition of Lipids Associated with Dense Coat-enriched Fractions of Bovine Milk Fat Globule Membrane (우유 지방구막의 고밀도 표피에 결합된 지질의 조성)

  • Kwak, Hae-Soo;Chung, Choong-Il;Lee, Jae-Young
    • Korean Journal of Food Science and Technology
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    • v.21 no.5
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    • pp.726-734
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    • 1989
  • To analyze the components of dense coat fractions associated with fat globule membrane, The membrane was treated with various concentrations of Triton X-100, a non-ionic detergent, and the composition of lipids associated to the detergent insoluble material was analyzed. The amount of protein, phospholipid, cholesterol and ganglioside in milk fat globule membrane was reduced consistently with increasing concentrations of Triton X-100. Butyrophilin (band 12), xanthine oxidase (band 3) and band 16 as constituents of insoluble coat materials was revealed after electrophorisis on SDS-polyacrylamide gels. Phosphatidyl ethanolamine, phosphatidyl choline, phosphatidyl serine, phosphatidyl inositol and sphingomyelin were identified as the major phospholipids of the coat materials without selective concentration relative to the original membranes. Percentages of total phospholipid were not changed by any of the treatments. Fatty acids of total lipid were myristate, palmitate, stearate (major saturated acids), oleate and linoleate (major unsaturated acids). Cholesterol contents on a protein basis were slightly reduced with increasing concentrations of Triton X-100. Cholesterol adhered to protein more tightly than other constituents The contents of gangliosides was proportionally refuted with increasing concentration of Triton X-100.

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Characteristics of Chemical Species in Gaseous and Aerosol Phase Measured at Gosan, Korea During ABC-EAREX2005 (ABC-EAREX2005 기간 동안 제주도 고산지역 대기 중 가스상 및 입자상 물질의 분포특성)

  • Moon K.J.;Han J.S.;Kong B.J.;Lee M.D.;Jung I.R.
    • Journal of Korean Society for Atmospheric Environment
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    • v.21 no.6
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    • pp.675-687
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    • 2005
  • In this study, the cyclone/denuder/filter pack sampling system was used to measure the daily concentrations of water soluble inorganic compounds of fine ($D_{p}< 2.5\;{\mu}m$) and coarse ($D_{p}<10{\mu}m$m) size fractions of aerosol and related gases at Gosan super site during ABC-EAREX 2005. The mean concentrations for $HNO_{3},\;HNO_{2},\;NH_{3}$, were 0.39, 0.08, and $0.29\;{\mu}g/m^3$. respectively. Average concentrations of sulfate, nitrate, and ammonium in $PM_{2.5}$ were 3.39, 1.06, and $1.04\;{\mu}g/m^3$, which occupied about $26\%$ of total $PM_{2.5}$ mass. In particular, more than half of these ionic species were found in size of less than $2.5\;{\mu}m$. Gas phase nitric acid concentrations have shown high correlation coefficient with $HNO_{2}$(R=0.80) and $O_{3}$(R=0.78), implying the active photochemical reactions from its precursors. Equivalent molar ratios between major ion components, $NH_{4}\;^{+}/nss\;SO_4\;^{2-},(0.83\;for\;PM_{2.5},\;0.86\;for\;PM_{10})$, revealed that the existing forms of the secondary aerosols were probably $(NH_{4})_{2}SO_{4}\;and\;(NH_{4})_{3}H\;(SO_{4})_{2}$. Especially, $(NH_{4}\;^{+}+K^{+}+Ca^{2+}+Mg^{2+})/(NO_{3}\;^{-}+nss\;SO_{4}\;^{2-}) (0.99\;for\;PM_{2.5},\;1.05\;for\;PM_{10})$ indicated that some of them existed not only as $NH_{4}NO_{3}$ but also as $CaSO_{4}\;or\;KNO_{3}$, which pointed out the probability of influences from the abundant soil components during Asian dust (AD) periods. These neutralized types of secondary aerosols showed that pollutants could be aged and transported from a distance.

Identification of Atmospheric PM10 Sources and Estimating Their Contributions to the Yongin-Suwon Bordering Area by Using PMF (PMF모델을 이용한 용인.수원 경계지역에서 PM10 오염원의 확인과 상대적 기여도의 추정)

  • Lee, Hyung-Woo;Lee, Tae-Jung;Yang, Sung-Su;Kim, Dong-Sool
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.4
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    • pp.439-454
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    • 2008
  • The purpose of this study was to extensively identify $PM_{10}$ sources and to estimate their contributions to the study area, based on the analysis of the $PM_{10}$ mass concentration and the associated inorganic elements, ions, and total carbon. The contribution of $PM_{10}$ sources was estimated by applying a receptor method because identifying air emission sources were effective way to control the ambient air quality. $PM_{10}$ particles were collected from May to November 2007 in the Yongin-Suwon bordering area. $PM_{10}$ samples were collected on quartz filters by a $PM_{10}$ high-volume air sampler. The inorganic elements (Al, Mn, V, Cr, Fe, Ni, Cu, Zn, Cd, Pb, Si, Ba, Ti and Ag) were analyzed by an ICP-AES after proper pre-treatments of each sample. The ionic components of these $PM_{10}$ samples ($Cl^_$, $NO_3^-$, $SO_4^{2-}$, $Na^+$, $NH_4^+$, $K^+$, $Ca^{2+}$, and $Mg^{2+}$) were analyzed by an IC. The carbon components (OC1, OC2, OC3, OC4, OP, EC1, EC2 and EC3) were also analyzed by DRI/OGC analyzer. Source apportionment of $PM_{10}$ was performed using a positive matrix factorization (PMF) model. After performing PMF modeling, a total of 8 sources were identified and their contribution were estimated. Contributions from each emission source were as follows: 13.8% from oil combustion and industrial related source, 25.4% from soil source, 22.1% from secondary sulfate, 12.3% from secondary nitrate, 17.7% from auto emission including diesel (12.1%) and gasoline (5.6%), 3.1% from waste incineration and 5.6% from Na-rich source. This study provides information on the major sources affecting air quality in the receptor site, and therefore it will help us maintain and manage the ambient air quality in the Yongin-Suwon bordering area by establishing reliable control strategies for the related sources.

An Analysis of High School Students' Analogy Generating Processes Using Think-Aloud Method (발성사고법을 활용한 고등학생의 비유 생성 과정 분석)

  • Kim, Minhwan;Kwon, Hyeoksoon;Lee, Donghwi;Noh, Taehee
    • Journal of The Korean Association For Science Education
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    • v.38 no.1
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    • pp.43-55
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    • 2018
  • In this study, we investigated high school students' analogy generating processes using the think-aloud method. Twelve high school students in Seoul participated in this study. The students were asked to generate analogies on ionic bonding and were also interviewed after their activities. Their activities and interviews were recorded and videotaped. After classifying the analogy generating processes into the three stages-encoding, exploring sources, and mapping, several process components were identified. The analyses of the results indicated that they checked the target concept given and selected one for a salient attribute among many attributes of the target concept at the stage of encoding. After selecting the salient attribute, they translated the salient attribute that is a scientific term into an everyday term, which is named as 'extracting salient similarities.' At the stage of exploring sources, they chose the sources based on salient similarities and chose the final source through circular processes, which included the process components of 'evaluating the sources' and 'discarding the sources.' At the final stage, they added the attributes to analogs and mapping them to the attributes of the target concept, which is named as 'mapping shared attributes.' There were some cases that 'mapping shared attributes' appeared after they specified the situation of analogs or assumed new situation, which is named as 'specifying the situations.' Some students recognized unshared attributes in their analogs.

Performance Analysis of Pyrotechnic Devices on the Reliability of Thermal Batteries (열전지의 신뢰성에 미치는 파이로테크닉 부품의 특성분석)

  • Cheong, Hae-Won;Kang, Sung-Ho;Kim, Kiyoul;Cho, Jang-Hyeon;Ryu, Byungtae;Baek, Seung-Su
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.1
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    • pp.116-123
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    • 2019
  • Thermal batteries are also called molten-salt batteries as the electrolyte is mainly composed of molten salt. The molten-salt electrolyte is a solid that does not conduct electricity at room temperature, but when it is melted by a pyrotechnic heat source, it becomes an excellent ionic conductor. Thermal batteries are a kind of pyrotechnic battery because they operate only when the solid electrolyte is melted by the heat energy provided by pyrotechnic materials. Pyrotechnic components used in a thermal battery include heat sources, fuse strips, and an igniter. The reliability of these pyrotechnic components critically affects the reliability and performance of the battery that must supply electricity stably to guided munitions even under extreme environmental conditions. Different igniter types offer different advantages: notch-type igniters offer improved ignition probability, whereas film-type igniters offer improved safety. The addition of metal oxides to the heat paper could improve the burn rate, and the ignition reliability could be greatly improved by using it with a flame igniter at the same time. Using a two-step reduction process, high-purity Fe particles in coral form can be safely obtained.

A Study on Chemical Composition of Fine Particles in the Sungdong Area, Seoul, Korea (서울 성동구 지역 미세먼지의 화학적 조성에 관한 연구)

  • 조용성;이홍석;김윤신;이종태;박진수
    • Journal of Environmental Science International
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    • v.12 no.6
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    • pp.665-676
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    • 2003
  • To investigate the chemical characteristics of PM$\_$2.5/ in Seoul, Korea, atmospheric particulate matters were collected using a PM$\_$10/ dichotomous sampler including PM$\_$10/ and PM$\_$2.5/ inlet during the period of October 2000 to September 2001. The Inductively Coupled Plasma-Mass Spectromety (ICP-MS), ion Chromatography (IC) methods were used to determine the concentration of both metal and ionic species. A statistical analysis was performed for the heavy metals data set using a principal component analysis (PCA) to derived important factors inherent in the interactions among the variables. The mean concentrations of ambient PM$\_$2.5/ and PM/sub10/ were 24.47 and 45.27 $\mu\textrm{g}$/㎥, respectively. PM$\_$2.5/ masses also showed temporal variations both yearly and seasonally. The ratios of PM$\_$2.5/PM$\_$10/ was 0.54, which similar to the value of 0.60 in North America. Soil-related chemical components (such as Al, Ca, Fe, Si, and Mn) were abundant in PM$\_$10/, while anthropogenic components (such as As, Cd, Cr, V, Zn and Pb) were abundant in PM2s. Total water soluble ions constituted 30∼50 % of PM$\_$2.5/ mass, and sulfate, nitrate and ammonium were main components in water soluble ions. Reactive farms of NH$_4$$\^$+/were considered as NH$_4$NO$_3$ and (NH$_4$)$_2$SO$_4$ during the sampling periods. In the results of PCA for PM$\_$2.5/, we identified three principal components. Major contribution to PM$\_$2.5/ seemed to be soil, oil combustion, unidentified source. Further study, the detailed interpretation of these data will need efforts in order to identify emission sources.