• 제목/요약/키워드: Ion migration

검색결과 191건 처리시간 0.045초

제주도 한라산 남북측 사면 용천수의 수리지구화학

  • 이광식;박원배;현승규;김용제;문덕철;김구영
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2004년도 총회 및 춘계학술발표회
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    • pp.408-412
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    • 2004
  • A total of 23 springs distributed in the southern and northern sides of Mt. Hala in Jeju Island were seasonally sampled and analyzed for their major ion chemistry and oxygen and hydrogen isotope compositions to investigate their hydrogeochemical and isotopic characteristics. Dissolved ion concentrations of the south-side springs slightly increase with decreasing altitude. This indicates that dissolved ion concentrations of groundwater recharged at higher altitudes increase by water-rock interaction during the downgradient migration of groundwater through highly permeable volcanic aquifer. Dissolved ion concentrations of the north-side springs also slightly increase with decreasing altitude, but dramatically increase at ~300 m.a.s.l. This may indicate a sudden input of contaminants to the north-side groundwater system around ~300 m.a.s.l. Springs located in areas above ~300 m.a.s.l. have very low concentrations of dissolved ions, showing little seasonal variations. Whereas springs located in areas below ~300 m.a.s.l. show a big seasonal variation in the concentration of dissolved ions. Seasonal variation of oxygen isotope compositions of springs is ~3$\textperthousand$ for high-altitude springs (~1700 m.a.s.l.) and is ~2$\textperthousand$ near shore, indicating an attenuation of the variation through mixing with other groundwater bodies during migration.

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Zn-doped BaZrO3에서의 멀티-프로톤 전도와 상호작용 (Migration and Interaction of Multi-protons in Zinc-doped Barium Zirconate)

  • 정용찬;김대희;김병국;김영철
    • 대한금속재료학회지
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    • 제49권12호
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    • pp.977-982
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    • 2011
  • Migration and interaction of multi-protons in a zinc-doped barium zirconate (Zn-doped $BaZrO_3$) super cell were investigated using a density functional theory. O ions in the super cell form interconnected octahedrons with Zr or Zn ions positioned in their centers and Ba ions positioned among the eight octahedrons. When one proton was added to the super cell, the energy barrier of 0.80 eV for proton transfer from the first to second nearest O ion sites from the Zn ion reached its highest value. When two protons were added to the super cell, the two protons preferred the first nearest O ions from the Zn ion. The two protons were accommodated by pushing the neighboring Zn ion further away from the center of the octahedron. Energy barriers for proton transfer from the Zn-octahedron to the neighboring Zr-octahedron were spread in the range of 0.36 ~ 1.02 eV.

고온고습 전압인가(Biased HAST) 시험에서 인쇄회로기판의 이온 마이그레이션 불량 메커니즘 (Ion Migration Failure Mechanism for Organic PCB under Biased HAST)

  • 허석환;신안섭;함석진
    • 마이크로전자및패키징학회지
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    • 제22권1호
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    • pp.43-49
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    • 2015
  • 전자 제품의 경박 단소화 및 고집적화가 이루어 지면서 반도체 칩뿐만 아니라 유기 기판도 고집적화가 요구되고 있다. 본 연구는 인쇄회로기판의 미세 피치 회로에 대한 고온고습 전압인가 시험을 실시하여 불량 메커니즘을 연구하였다. $130^{\circ}C/85%RH/3.3V$$135^{\circ}C/90%RH/3.3V$ 시험조건에서 고온고습 전압시험(Biased HAST)의 가속 계수는 2.079로 계산되었다. 불량 메커니즘 분석을 위하여 집속이온빔(FIB) 분석이 이용되었다. (+)전극에서는 콜로이드 형태의 $Cu_xO$$Cu(OH)_2$가 형성되었으며, (-)전극에서는 수지형태의 Cu가 관찰되었다. 이를 통해 $Cu^{2+}$ 이온과 전자($e^-$)가 결합한 수지상 Cu에 의해 절연파괴가 일어난다는 것을 확인하였다.

공정조성 SnPb Solder 합금의 부식 및 Electrochemical Migration 특성에 미치는 SO42- 이온의 영향 (Effect of SO42- Ion on Corrosion and Electrochemical Migration Characteristics of Eutectic SnPb Solder Alloy)

  • 정자영;유영란;이신복;김영식;주영창;박영배
    • 한국재료학회지
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    • 제17권1호
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    • pp.43-49
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    • 2007
  • Electrochemical migration phenomenon is correlated with ionization of anode electrode, and ionization of anode metal has similar mechanism with corrosion phenomenon. In this work, in-situ water drop test and evaluation of corrosion characteristics for SnPb solder alloys in $Na_2SO_4$ solutions were carried out to understand the fundamental electrochemical migration characteristics and to correlate each other. It was revealed that electrochemical migration behavior of SnPb solder alloys was closely related to the corrosion characteristics, and Sn Ivas primarily ionized in ${SO_4}{^2-}$ solutions. The quality of passive film formed at film surface seems to be critical not only for corrosion resistance but also for electrochemical migration resistance of solder alloys.

Vertical Transport of Protons in Amorphous Ice

  • Moon, Eui-Seong;Kim, Young-Soon;Shin, Sung-Hwan;Kang, Heon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.279-279
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    • 2012
  • In order to estimate the average migration lengths of $H_3O^+$ ions in amorphous ice, we conducted experiments of reactive ion scattering (RIS), low energy sputtering (LES), and reflection absorption IR spectroscopy (RAIRS) with an ultra-high vacuum (UHV) chamber. Dopped water-ice films were grown on the clean surface of Ru single crystal and analyzed with RIS, LES and RAIRS methods. The population changes of probe molecules, which were buried at a controlled distance from the surface, were monitored by those methods so that we can mesure the migration efficiencies. From the measured efficiencies, we evaluated the average migration lengths. This result is expected to give the information about the dynamics of proton in water-ice film.

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무연솔더 내 마이그레이션 플럭스개발에 관한 연구 (A Study on Development of Flux to Restrict Occurrence of ion Migration in Lead-Free Solder)

  • 유동수;임재훈;우성우
    • 한국신뢰성학회:학술대회논문집
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    • 한국신뢰성학회 2005년도 학술발표대회 논문집
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    • pp.385-392
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    • 2005
  • The restriction of the use of hazardous substances in electrical and electronic equipment legislation mandates the substitution of lead and other hazardous substances in electronics products by July 2006. Due to this legislative pressure, the electronics industry is moving to adoption of lead free solders. In this paper, we investigated a flux to restrict generating electrochemical migration in lead-free solder. The lead-free solders used in this study were Sn-0.7Cu-0.01P and Sn-3.0Ag-0.5Cu. To measure the resistance of electrochemical migration, the dew-cycle test and water drop test were adopted. As the result, now flux having high durable of electrochemical migration was developed.

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First-principles Study of the Efficient Li-ion Insertion into TiO2 anatase Nanolayer for High Performance Li-ion Battery

  • Shin, Dong Jae;Kim, Yong Hoon
    • EDISON SW 활용 경진대회 논문집
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    • 제5회(2016년)
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    • pp.305-307
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    • 2016
  • We calculated Li ion migration energy barrier, applying three different models on Li ion insertion into $TiO_2$ nanolayers to elucidate the previously reported high rate of charge-discharge. With the existence of additional Li ion on the surface of $TiO_2$ structure, spontaneous insertion of Li ion into the second layer from the first layer was observed. Using this result, we showed the intrinsic property of $TiO_2$ structure and it has a contribution to the reported performance. In the end, we give a suggestion on the fabrication of $TiO_2-Graphene$ hybrid structure for Li ion battery electrode.

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고로슬래그를 다량 함유한 고강도 콘크리트의 재료적 특성 (Material Characteristics of High-Strength Concrete Incorporating High Replacement Level of Blast-Furnace Slag)

  • 이회근;정재홍;김한준;이승훈
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2010년도 춘계 학술대회 제22권1호
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    • pp.291-292
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    • 2010
  • 본 연구에서는 고로슬래그 미분말을 다량 사용한 고강도 콘크리트의 재료적 특성을 조사하기 위해 고로슬래그 미분말을 각각 50%와 70% 사용한 고강도 콘크리트에 대해 압축강도, 단열온도상승, 자기 수축 및 염소이온확산계수를 측정하였다. 실험결과, 슬래그 다량 치환 사용시 수화열 저감 및 염소이온확산계수 감소로 온도균열제어 및 고부식성 환경하 염해 저항성이 향상되는 것으로 나타났다.

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A study on heavy metal migration in fly ash/bentonite using a reactive transport model

  • Jung, Yoo-Jin;Cho, Hee-Chan
    • 한국지구물리탐사학회:학술대회논문집
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    • 한국지구물리탐사학회 2003년도 Proceedings of the international symposium on the fusion technology
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    • pp.629-636
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    • 2003
  • The retardation of heavy metals in a mixture of fly ash and bentonite was studied as a potential barrier material for a landfill. Column tests were conducted using synthetic leachate having 100 mg/L and 50 mg/L of lead (Pb) and cadmium (Cd), respectively. Results indicated that the mixture had obvious retardation ability for heavy metals. To investigate the retardation factor caused by adsorption, batch adsorption tests were conducted at various concentrations. Test results were correlated with both Langmuir and Freundlich isotherms. The adsorption of the lead ion was applicable to the Langmuir isotherm and the adsorption of the cadmium ion was applicable to the Freundlich isotherm. In addition, based on experimental results, the migration characteristics of heavy metals through the bed of fly ash and bentonite mixture were investigated using the PHREEQC, a reactive transport model, under the real conditions of the landfill liner.

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혼합 전도체 $\beta-LiAl$의 전자구조, 결합과 Li 이온 이동에 따른 영향 (Electronic Structure, Bonding and Kithium Migration Effects of the Mixed Conductor $\beta-LiAl$)

  • Jang, Gun-Eik;I.M Curelaru
    • 한국진공학회지
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    • 제5권3호
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    • pp.194-198
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    • 1996
  • Detailed expermental studies of theelectronic structure of the valence and conduction bands of the mixed conductor $\beta$-LiAlindicate that a quasi-gap opens at the Fermi level, and the conduction states are highlylocalized, as opposed to the theoretical band structure calculations that predict predominant metallic behavior. Evidence for complex lithium migration effects involving the surface of Lial , induced by particle (electron or ion) bombardment and mechanical treatment , has been obtained as a byproduct of these experiments.

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