• Membrane Journal
• /
• v.28 no.6
• /
• pp.388-394
• /
• 2018

Carbon nanotube (CNT) based membranes are promising candidates for separation membranes by showing high water transport rate and ion rejection rate according to their radii. The ion selectivity is an important factor to discover the full potential of CNT membranes, and it is affected by the functionalization of CNTs. With multivalent/size ion mixtures, the ion selectivity is affected by not only ion-functional groups interaction but also ion-ion interactions and ion size exclusion in a complex manner. In this study, molecular dynamics simulations are performed to study the ion selectivity of functionalized carbon nanotubes when multivalent/size ions are contained. The permeation energy barriers are calculated by plotting potential of mean force profiles, and various factors, such as CNT size and partial charges, affecting ion selectivity are investigated. The results presented here will be useful for designing CNT membranes for ion separation, biomimetic ion channels, etc.

• Applied Science and Convergence Technology
• /
• v.27 no.1
• /
• pp.19-22
• /
• 2018

The ion energy and angle distributions (IEADs) in the DC magnetron sputtering systems are investigated for the variation of gas pressure using particle-in-cell simulation. Even for the condition of collisionless ion sheath at low pressure, it is possible to change the IEAD significantly with the change of gas pressure. The bombarding ions to the target with low energy and large incident angle are observed at low pressure when the sheath voltage drop is low. It is because the electron transport is hindered by the magnetic field at low pressure because of few collisions per electron gyromotion while the ions are not magnetized. Therefore, the space charge effect is the most dominant factor for the determination of IEADs in low-pressure magnetron sputtering discharges.

• Applied Science and Convergence Technology
• /
• v.27 no.2
• /
• pp.26-29
• /
• 2018

The ion energy and angle distributions (IEADs) in the DC magnetron sputtering systems are investigated for the variation of gas pressure using particle-in-cell simulation. Even for the condition of collisionless ion sheath at low pressure, it is possible to change the IEAD significantly with the change of gas pressure. The bombarding ions to the target with low energy and large incident angle are observed at low pressure when the sheath voltage drop is low. It is because the electron transport is hindered by the magnetic field at low pressure because of few collisions per electron gyromotion while the ions are not magnetized. Therefore, the space charge effect is the most dominant factor for the determination of IEADs in low-pressure magnetron sputtering discharges.

• Ceramist
• /
• v.22 no.4
• /
• pp.381-392
• /
• 2019

Recently, demands for lithium-ion batteries (LIB) in various fields are increasing. In particular, understanding of the reaction mechanism occurring at the electrode-electrolyte surface/interface is significant for the development of advanced LIBs. Meanwhile, research and development of LIBs highly requires a new specific characterization approach. For example, atomic force microscopy (AFM) has been utilized to the LIB research field for various purposes such as investigation of topography, electrochemical reactions, ion transport phenomena, and measurement of surface potential at high resolution. Advances in the AFM analysis have made it possible to inspect various material properties such as surface friction and Young's modulus. Therefore, this technique is expected to be a powerful method in the LIB research field. Here, we review and discuss ways to apply AFM to LIB studies.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.21 no.4
• /
• pp.381-387
• /
• 2008

Neutron production rate in spherically convergent beam fusion(SCBF) device as a portable neutron source strongly depends on the ion current and the grid cathode structure. In this paper, as the process of design and analysis, Design of Experiment(DOE) based on the results by Finite Element Method-Flux Corrected Transport(FEM-FCT) method is employed to calculate the ion current. This method is very useful to find optimal design conditions in a short time. Number of rings, radius of rings, and distance between the grid cathode and center are selected as control factors. From the results in the optimized model, the higher ion current is calculated and deeper potential well is also observed.

• Membrane Journal
• /
• v.34 no.1
• /
• pp.58-69
• /
• 2024

Reverse electrodialysis (RED) is an electro-membrane process employing ion-exchange membranes (IEMs) that can harvest electric energy from the concentration difference between seawater and river water. Multivalent ions contained in seawater and river water bind strongly to the fixed charge groups of the IEM, causing high resistance and reducing open-circuit voltage and power density through uphill transport. In this study, a pore-filled anion-exchange membrane (PFAEM) with excellent monovalent ion selectivity and electrochemical properties was fabricated and characterized for RED application. The monovalent ion selectivity of the prepared membrane was 3.65, which was superior to a commercial membrane (ASE, Astom Corp.) with a selectivity of 1.27 under the same conditions. Additionally, the prepared membrane showed excellent electrochemical properties, including low electrical resistance compared to ASE. As a result of evaluating RED performance under seawater of 0.459 M NaCl/0.0510 M Na₂SO₄ and river water of 0.0153 M NaCl/0.0017 M Na₂SO₄, the maximum power density of 1.80 W/m² was obtained by applying the prepared membrane, which is a 40.6% improved output performance compared to the ASE membrane.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 1997.04a
• /
• pp.172-176
• /
• 1997

It is likely that the corona discharge appears due to the motion and the multiplication of electron and ion under the nonuniform electric field. Because the motion and the multiplication of electron and ion are the function of electric field, for the simulation of the corona discharge, we have to calculate the electric field, before the calculation of the motion and the multiplication of electron and ion. In this paper, the electric field is calculated on the assumption that the gap between a hyperboloidal needle and a plane is 1-dimension, and the motion and the multiplication of electron and ion are determined by Flux-Corrected Transport method. For this purpose, we solve the electron and ion continuity equation together with Poisson equation. We calculated the current density and the electron and ion density distributions between electrodes as well as electric field distortion due to the space charge assuming that the discharge channel radius is 100${\mu}{\textrm}{m}$. In this simulation, it is found that the current density has one peak as observed by experiment, and electric field distortion is important to the formation and the stability of the corona discharge.

• KSBB Journal
• /
• v.8 no.4
• /
• pp.370-374
• /
• 1993

In transportation the amount of metal ion by crown ethers, dibenzo-18-crown-6 were investigated using ultraviolet spectrometer. Transported the amount of one valence metal ion as $K^+ and Li^+}$ was not so much. On the other hand, two valence metal ion increased by dibenzo-18-crown-6, which means that the ionic charge and hydration of two valence metal ion affected the carrying ability of crown ethers. The carrying ability of dibenzo-18-crown-6 was, therefore, adequate for two valence metal ion as $Ca^{2+}$ and $Ba^{2+}$. It was also suggested that transport metal ion by crown ethers, which is related rather the catching ability than the selectivity of metalion.

• Journal of the Korean Society of Radiology
• /
• v.7 no.1
• /
• pp.85-91
• /
• 2013

The selective transport characteristics of $K^+$ and $Na^+$ of cell membrane model which irradiated by 60Co ${\gamma}$-ray was investigated. The cell membrane model used in this experiment was a Na+ type sulfonated copolymerized membrane of styrene and divinylbenezene. The initial flux of the ion was increased with increase of both $H^+$ ion concentration. In this experiment range(pH 0.5-3, temperature $15-65^{\circ}C$), first, the selectivity of $K^+$ and the ratio K+/Na+ of membrane which was not irradiated was about 1.06 - 1.13 and second, that of K+ and the ratio $K^+/Na^+$ of membrane which was irradiated was near about 0. And the driving force of pH of irradiated membrane was significantly increased about 4-5 times than membrane which was not irradiated. As selective transport of K+ and Na+ of cell membrane model were abnormal, cell damages were appeared at cell.

• Journal of the Korean GEO-environmental Society
• /
• v.7 no.3
• /
• pp.43-54
• /
• 2006

In this paper, the uniaxial, triaxial compression tests and consolidation tests on the clay sample substituted initial pore water for pollutant were performed to evaluate the change in geotechnical properties of the contaminated clay. The contaminant transport analysis on embankment type landfill using the MT3D model was also performed to evaluate the extent of transport and diffusion. There was tendency that strength, compressibility and permeability has increased with the increase in the concentration of NaCl solution. The increase in the strength and compressibility of sample saturated with leachate was higher than samples saturated with NaCl solution, but in the permeability coefficient was lower. As the result of contaminant transport analysis, the predicted concentration was in high with the increase in the initial concentration of $Cl^-$ ion and increased in a non-linear form. The transportation distance calculated with use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with the increase in the initial concentration.