• Title/Summary/Keyword: Ion Conductivity

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Ion Exchange Membrane for Desalination by Electrodialysis Process: A Review (전기투석법에 의한 담수화용 이온교환막: 총설)

  • Sarsenbek, Assel;Rajkumar, Patel
    • Membrane Journal
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    • v.32 no.2
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    • pp.91-99
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    • 2022
  • It is a global challenge to fulfill the demand for clean water at an affordable cost to all the strata of the population. Desalination of seawater as well as brackish water by the membrane separation process is a well-established and cost-efficient method. However, there is still inherent problem of membrane fouling, disposal of the reject as well as a capital-intensive process. While electrodialysis (ED) is a membrane-based separation process in which a driving force is the potential difference. The advantages of ED process are excellent efficiency and low operation cost. Ion exchange membrane (IEM) used in the ED process needs to have higher chemical and thermal stability along with excellent mechanical strength for long-term use without losing its efficiency. The ion exchange capacity of the ED membrane is largely dependent on the conductivity of IEMs. In this review, the modification strategy of the pristine membrane to enhance the stability and ion conductivity of cation exchange membrane (CEM) and anion exchange membrane (AEM) is discussed.

Performance Enhancement of Ion-Exchange Membranes Using Nanomaterials (나노물질을 이용한 이온교환막의 성능 향상)

  • Moon-Sung Kang
    • Membrane Journal
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    • v.33 no.6
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    • pp.315-324
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    • 2023
  • Ion-exchange membrane (IEM), is a key component that determines the performance of the electro-membrane processes. In this review, the latest research trends in improving the performance of IEMs used in various electro-membrane processes through modification using carbon-based and metal-based nanomaterials are investigated. The nanomaterials can be introduced into IEMs through various methods. In particular, carbon-based nanomaterials can strengthen their interaction with polymer chains by introducing additional functional groups through chemical modification. Through this, not only can the ion conductivity of IEM be improved, but also the permselectivity can be improved through the sieving effect through the layered structure. Meanwhile, metal-based nanomaterials can improve permselectivity through sieving properties using the difference in hydration radius between target ions and excluded ions within a membrane by using the property of having a layered or porous structure. In addition, depending on the characteristics of the binder used, ion conductivity can be improved through interaction between nanomaterials and binders. From this review, it can be seen that the properties of IEMs can be effectively controlled using carbon-based and metal-based nanomaterials and that research on this is important to greatly improve the performance of the electro-membrane process.

CHROMOSPHERIC MAGNETIC RECONNECTION ON THE SUN

  • CHAE JONGCHUL;CHOI BYUNG-Kyu;PARK MIN-JU
    • Journal of The Korean Astronomical Society
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    • v.35 no.1
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    • pp.59-65
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    • 2002
  • Solar observations support that magnetic reconnect ion ubiquitously occurs in the chromosphere as well as in the corona. It is now widely accepted that coronal magnetic reconnect ion is fast reconnect ion of the Petschek type, and is the main driver of solar flares. On the other hand, it has been thought that the traditional Sweet-Parker model may describe chromospheric reconnect ion without difficulty, since the electric conductivity in the chromoshphere is much lower than that in the corona. However, recent observations of cancelling magnetic features have suggested that chromospheric reconnect ion might proceed at a faster rate than the Sweet-Parker model predicts. We have applied the Sweet-Parker model and Petschek model to a well-observed cancelling magnetic feature. As a result, we found that the inflow speed of the Sweet-Parker reconnect ion is too small to explain the observed converging speed of the feature. On the other hand, the inflow speeds and outflow speeds of the Petschek reconnect ion are well compatible with observations. Moreover, we found that the Sweet-Parker type current sheet is subject to the ion-acoustic instability in the chromosphere, implying the Petschek mechanism may operate there. Our results strongly suggest that chromospheric reconnect ion is of the Petschek type.

Measurement of an Ion Concentration in Drinking Water by lon Chromatography (Ion Chromatography에 의한 음료수중 음이온 함량에 관한 연구)

  • Kim Hyung-Suk
    • Journal of environmental and Sanitary engineering
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    • v.4 no.1 s.6
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    • pp.7-15
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    • 1989
  • According to the increase of population and development of industrialization air and water pollution problems are still keeping going to great nuisance to human activities. Specially man should drink 2l clean water to maintain our health every day, but we afraid of drink the city tap water because of the contaminants like heavy metals, bacteria trihalomethane, etc. In the analysis of the anions in potable water, we usually adapt the Standard methods for the Examination of Water and Wastewater. But this method is tedious and time consuming, so the Ion Chromatography method is now used in research of water quality. Author worked with Ion Chromatography in measuring the anions in drinking water by attaching conductivity dector to normal High Performance Liquid Chromatograph. Low-capacity ion-exchange coulmn and dilute eluents, 0.00M phthalic aic was used in this study. The concentration of chloride ion was 1.55 ppm$\~$3 8.81ppm, nitrate ion was 5.45 ppm$\~$18.27ppm, and sulfate ion was 19.64 ppm$\~$28.86 ppm. The phosphate ion was detected only in Apt. tap water as 167.99 ppm whose amount was supposed to be used as a water pipe cleaner.

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Investigation of Microstructure and Ionic Conductivity of Li1.5Al0.5Ti1.5(PO4)3 Ceramic Solid Electrolytes by B2O3 Incorporation (Li1.5Al0.5Ti1.5(PO4)3 세라믹 고체전해질의 B2O3 첨가에 따른 미세구조 및 이온전도도에 대한 연구)

  • Min-Jae Kwon;Hyeon Il Han;Seulgi Shin;Sang-Mo Koo;Weon Ho Shin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.6
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    • pp.627-632
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    • 2023
  • Lithium-ion batteries are widely used in various applications, including electric vehicles and portable electronics, due to their high energy density and long cycle life. The performance of lithium-ion batteries can be improved by using solid electrolytes, in terms of higher safety, stability, and energy density. Li1.5Al0.5Ti1.5(PO4)3 (LATP) is a promising solid electrolyte for all-solid-state lithium batteries due to its high ionic conductivity and excellent stability. However, the ionic conductivity of LATP needs to be improved for commercializing all-solid-state lithium battery systems. In this study, we investigate the microstructures and ionic conductivities of LATP by incorporating B2O3 glass ceramics. The smaller grain size and narrow size distribution were obtained after the introduction of B2O3 in LATP, which is attributed to the B2O3 glass on grain boundaries of LATP. Moreover, higher ionic conductivity can be obtained after B2O3 incorporation, where the optimal composition is 0.1 wt% B2O3 incorporated LATP and the ionic conductivity reaches 8.8×10-5 S/cm, more than 3 times higher value than pristine LATP. More research could be followed for having higher ionic conductivity and density by optimizing the processing conditions. This facile approach for establishing higher ionic conductivity in LATP solid electrolytes could accelerate the commercialization of all-solid-state lithium batteries.

A Study on Ion Shower Doping in Si Thin Film (이온 도핑 방법에 의한 실리콘 박막의 도핑 연구)

  • Yoo, Soon-Sung;Jun, Jung-Mok;Lee, Kyung-Ha;Moon, Byeong-Yeon;Jang, Jin
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.31A no.5
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    • pp.106-112
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    • 1994
  • We have developed a large area ion shower doping system with an RF plasma ion source. The ion current density (i.e., doping concentration) increases with RF power and acceleration voltage. Using this technique, we investigated the optimum condition for ion doping of phosphorus in a-Si:H and poly-Si films. The optimum acceleration voltage and doping time are 6KV and 90sec, respectively, in a-Si:H films. Under this condition the electrical conductivity of ion-doped a-Si:H film is obtained ~10$^{-3}$/cm at room temperature. The sheet resistance decreases witnh acceleration voltage in ion-doped poly-Si, and a heavily-doped layer with a sheet resistance of 920$\Omega$/ㅁ is obtained by using ion doping and subsequent activation.

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Doping Diamond for Electronic Application

  • Kalish, R.
    • The Korean Journal of Ceramics
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    • v.2 no.4
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    • pp.188-192
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    • 1996
  • Diamond based electronic devices promise to exhibit unique properties. In order to realize devices diamond has to be doped to render it electrically conductive. In the present work the doping of diamond and of polycrystalline CVD diamond films are reviewd with particular emphasis to ion-implantation doping and to attempts to dope diamond by in-diffusion of the dopants. The quest for finding ways to obtain n-type conductivity in diamond will be critically examined.

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Synthesis and Characterization of Organosilane Electrolyte Containing Silphenylene

  • Kim, Jongjun;Sohn, Honglae
    • Journal of Integrative Natural Science
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    • v.10 no.4
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    • pp.197-201
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    • 2017
  • Organosilicon compound containing silphenylene unit as an eletrolyte for the application of lithium-ion batteries was synthesized by hydrosilylation method between 1,4-bis(dimethylsilylhydro)benzene and 3-[2-(2-methoxyethoxy)ethoxy]-1-propene. As-prepared new organosilicon compounds containing spacer such as propyl group with ethylene glycol are synthesized to improve thermal stability and to promote conductivity. The products are characterized by spectroscopic analysis.

Linear and network structures of polymer electrolyte based on phosphate and polyether copolymers

  • Kim, Jun-Young;Kim, Seong-Hun
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.10a
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    • pp.232-235
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    • 1998
  • ion conducting polymers have been extensively investigated because of their potential application as an electrolyte in solid state batteries [1]. Among the polymer electrolytes, solid polymer electrolytes (SPEs) composed of ion conducting polymer and alkali metal salt have many advantages such as high ionic conductivity, high energy density and light weight. This made them suitable replacement for liquid electrolytes. (omitted)

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