Membrane Journal (멤브레인)

The Membrane Society of Korea (한국막학회)
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Ion Exchange Membrane for Desalination by Electrodialysis Process: A Review

전기투석법에 의한 담수화용 이온교환막: 총설

  • Sarsenbek, Assel (Nano Science and Engineering (NSE), Integrated Science and Engineering Division (ISED), Underwood International College, Yonsei University) ;
  • Rajkumar, Patel (Energy and Environmental Science and Engineering (EESE), Integrated Science and Engineering Division (ISED), Underwood International College, Yonsei University)
  • 살센벡 아샐 (연세대학교 언더우드국제대학 융합과학공학부 나노과학공학) ;
  • 라즈쿠마 파텔 (연세대학교 언더우드학부 융합과학공학부 에너지환경융합전공)
  • Received : 2022.04.05
  • Accepted : 2022.04.22
  • Published : 2022.04.30
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Abstract

It is a global challenge to fulfill the demand for clean water at an affordable cost to all the strata of the population. Desalination of seawater as well as brackish water by the membrane separation process is a well-established and cost-efficient method. However, there is still inherent problem of membrane fouling, disposal of the reject as well as a capital-intensive process. While electrodialysis (ED) is a membrane-based separation process in which a driving force is the potential difference. The advantages of ED process are excellent efficiency and low operation cost. Ion exchange membrane (IEM) used in the ED process needs to have higher chemical and thermal stability along with excellent mechanical strength for long-term use without losing its efficiency. The ion exchange capacity of the ED membrane is largely dependent on the conductivity of IEMs. In this review, the modification strategy of the pristine membrane to enhance the stability and ion conductivity of cation exchange membrane (CEM) and anion exchange membrane (AEM) is discussed.

모든 인구 계층에 저렴한 비용으로 깨끗한 물의 수요를 충족시키는 것은 해결해야 할 세계적인 문제이다. 막 분리 공정을 통한 해수 및 기수의 탈염은 효율이 높고 확립된 방법이다. 그러나 막 분리 공정은 막 오염, 제거된 오염물의 처리, 그리고 자본집약적 공정이라는 본질적인 문제가 있다. 전기투석은 전위차가 구동력인 막 기반 분리 공정이다. 전기투석막의 장점은 뛰어난 효율과 저렴한 운영 비용이다. 전기투석공정에서 사용되는 이온교환막은 장기간 효율을 잃지 않기 위해 내화학성과 내열성, 그리고 기계적 안정성이 필요하다. 이 때, 전기투석막의 이온교환용량은 이온교환막의 전도도에 따라 크게 달라진다. 본 리뷰에서는 이온 전도도과 안정성을 향상시키기 위한 양이온 교환막과 음이온 교환막의 개조를 중점적으로 논의하였다.

Keywords

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