• Journal of Korea Foundry Society
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• v.26 no.1
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• pp.27-33
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• 2006

Phase evolutions involving nucleation stages together with diffusional growth have been examined in order to provide a guideline for determining rate limiting stages during phase evolutions. In multiphase materials systems in coatings, composites or multilayered structures, diffusion treatments often result in the development of metastable/intermediate phases at the reaction interfaces. The development of metastable phases during solid state interdiffusion demonstrates that the nucleation reaction can be one controlling factor. Also, the concentration gradient and the relative magnitudes of the component diffusivities provide a basis for a phase selection and the application of a kinetic bias strategy in the phase selection. For multicomponent alloy systems, the identification of the operative diffusion pathway is central to control phase formation. Experimental access to the nucleation and growth stage is discussed in thin film multi layers and bulk samples.

• Journal of the Korean Electrochemical Society
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• v.3 no.1
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• pp.25-30
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• 2000

The relation between the phase-shift profile for the intermediate frequencies and the Langmuir adsorption isotherm at the poly-$Pt/0.1\;M\;H_2SO_4$ aqueous electrolyte interface has been studied using ac impedance measurements, i.e., the phase-shift methods. The suggested interfacial equivalent circuit consists of the serial connection of the electrolyte resistance ($R_S$), the faradaic resistance $(R_F)$ and the equivalent circuit element $(C_P)$ of the adsorption pseudocapacitance $(C_\varphi)$. The delayed phase shift $(\varphi)$ depends on both the cathode potential (E) and frequency (f), and is given by $\varphi=-tan^{-1}[1/2{\pi}f(R_s+R_F)C_p]$. The phase-shift profile $(\varphi\;vs.\;E)$ for the intermediate frequency (ca. 6Hz) can be used as an experimental method to determine the Langmuir adsorption isotherm (9 vs. E). The equilibrium constant (K) for H adsorption and the standard free energy $({\Delta}G_{ads})$ of H adsorption at the poly-$Pt/0.1\;M\;H_2SO_4$ electrolyte interface are $1.8\times10^{-4}\;and\;21.4kJ/mol$, respectively. The H adsorption is attributed to the over-potentially deposited hydrogen (OPD H).

• KIEE International Transactions on Electrophysics and Applications
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• v.4C no.6
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• pp.306-309
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• 2004

This paper presents a new active antenna consisting of a microstrip patch for the passive radiator, a mixer for frequency conversion, a voltage controlled oscillator (VCO) and a phase detector for phase control. The microwave signal frequency has been converted into intermediate frequency (IF) on the antenna elements by the mixer. The active antenna consists of two ports, the IF port has a transmitted IF signal via power combined to the baseband and the dc control port is under the control of the phase-detector. The input voltage of the VCO is controlled by the phase detector. The scan range of the array is determined by the phase detector and the VCO and is obtained between 30$^{\circ}$ and - 30$^{\circ}$

• Journal of KSNVE
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• v.10 no.6
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• pp.949-954
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• 2000

Applicability of the vibration signal phase for predicting the modal damping properties of structures is investigated. For uniform plates with different internal damping levels, the phase delay as a function of the frequency span as well as a function of the distance between the excitation and response measurement points are experimentally obtained. Dependence of the phase characteristics on the amount of structural damping is elucidated -more heavily damped plate shows notably reduced phase delay at intermediate distances. The experimental results compare favorably with analytical predictions, and show much promise for further refinement as a tool for estimating structural properties.

• ETRI Journal
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• v.18 no.3
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• pp.147-160
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• 1996

We investigate noise-induced phase transitions in globally coupled active rotators with multiplicative and additive noises. In the system there are four phases, stationary one-cluster, stationary two-cluster, moving one-cluster, and moving two-cluster phases. It is shown that multiplicative noise induces a bifurcation from one-cluster phase to two-cluster phase. Pinning force also induces a bifurcation from moving phase to stationary phase suppressing the multiplicative noise effect. Additive noise reduces both effects of multiplicative noise and pinning force urging the system to the stationary one-cluster phase. The frustrated effects of pinning force and additive and multiplicative noises lead to a reentrant transition at intermediate additive noise intensity. Nature of the transition is also discussed.

• Journal of the Korean Electrochemical Society
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• v.6 no.2
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• pp.119-129
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• 2003

The Langmuir adsorption isotherms of the over-potentially deposited hydrogen (OPD H) fur the cathodic $H_2$ evolution reaction (HER) at the poly-Au and $Rh|0.5M\;H_2SO_4$ aqueous electrolyte interfaces have been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1{\geq}{\theta}{\geq}0)$ at the interfaces. The phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, i.e., the phase-shift method, can be used as a new electrochemical method to determine the Langmuir adsorption isotherm $({\theta}\;vs.\;E)$ of the OPD H for the cathodic HER at the interfaces. At the poly-Au|0.5M $H_2SO_4$ aqueous electrolyte interface, the equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.3\times10^{-6}$ and 32.2kJ/mol, respectively. At the poly-Rh|0.5M $H_2SO_4$ aqueous electrolyte interface, K and ${\Delta}G_{ads}$ of the OPD H are $4.1\times10^4\;or\;1.2\times10^{-2}$ and 19.3 or 11.0kJ/mol depending on E, respectively. In contrast to the poly-Au electrode interface, the two different Langmuir adsorption isotherms of the OPD H are observed at the poly-Rh electrode interface. The two different Langmuir adsorption isotherms of the OPD H correspond to the two different adsorption sites of the OPD H on the poly-Rh electrode surface.

• Journal of the Korean Institute of Telematics and Electronics
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• v.27 no.8
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• pp.1211-1220
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• 1990

This paper describes and implements a design method of register allocation as a required module of RISC compiler systems. It compiles a C program to a machine-independent intermediate language, translates each variable into symbolic register. After local allocation process for the symbolic registers, global register allocation is executed by applying the graph coloring algorithm. This register allocation phase is designed for a system with the large register file like RISC machines.

• Proceedings of the KIEE Conference
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• 1987.11a
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• pp.86-89
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• 1987

This paper treats with the design and fabrication of a frequency synthesizer for the generation of intermediate frequency of a HF band transceiver. The synthesizer is designed to control frequencies using a phase-locked loop and it is shown that method improved the performance of frequency accuracy and locking time then that of the crystal-reference system.

• Proceedings of the KIEE Conference
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• 2007.07a
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• pp.234-235
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• 2007

We have fabricated superconductor ceramics by chemical process. A high Tc superconductorwith a nominal composition of $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_y$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductor phase may be the most important factor. During the sintering, doped $Ag_{2}O$ was converted to Ag particles which were finely dispersed in superconductor samples.

• Journal of the Korean Ceramic Society
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• v.34 no.11
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• pp.1182-1186
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• 1997

La0.8Ca0.2Cr0.98O3 powder was prepared using the modified Pechini process. Various crystalline phases formed during thermal decomposition were investigated. (La,Ca)CrO4 phase, first formed from the precursor, was transformed to (La,Ca)CrO3 and CaCrO4 above 80$0^{\circ}C$, which remained up to 110$0^{\circ}C$. However, only (La,Ca)CrO3 phase consisting of orthorhombic and intermediate rhombohedral polymorphs was observed after sintering at 125$0^{\circ}C$. The specimens sintered at 140$0^{\circ}C$ exhibited 98% of relative density and rather wide grain size distribution with average grain size of 3-4 ${\mu}{\textrm}{m}$. Densification and grain growth of the specimens observed above 125$0^{\circ}C$ were presumably attributed to liquid phase sintering resulted from melting of Ca3(CrO4)2 phase.