• Title/Summary/Keyword: Intermediate phase

검색결과 492건 처리시간 0.027초

중간주파수에서 위상이동 변화와 Langmuir흡착등온식 사이의 관계 (The Relation between the Phase-Shift Profile for the Intermediate Frequencies and the Langmuir Adsorption Isotherm)

  • 천장호;문경현;조종덕
    • 전기화학회지
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    • 제3권1호
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    • pp.25-30
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    • 2000
  • 다결정 Pt/0.1 M $H_2SO_4$수성 전해질 계면에서 중간주파수 구간의 위상이동 변화와 Langmuir흡착등온식 사이의 관계를 교류임피던스 방법 즉 위상이동 방법을 이용하여 연구 조사하였다. 제안된 계면등가회로는 전해질저항($R_S$), Faraday저항$(R_F)$, 흡착유사용량$(C_\varphi)$의 등가회로 요소($C_P$)의 직렬접속으로 구성된다 지연되는 위상이동$(\varphi)$은 음전위(E) 및 주파수(f)에 따르며, $\varphi=-tan^{-1}[1/2{\pi}f(R_s+R_F)C_p]$이다. 중간주파수(6Hz)에서 위상이동 변화$(\varphi\;vs.\;E)$는 Langmuir흡착등온식$(\theta\;vs.\;E)$의 결정에 적용할 수 있는 실험적인 방법이다. 다결정 $Pt/0.1\;M\;H_2SO_4$ 전해질 계면에서 수소의 흡착평형 상수(K)와 흡착표준자유에너지$({\Delta}G_{ads})$는 각각 $1.8\times10^{-4}$와 21.4kJ/mol이며 과전위 수소흡착(OPD H)에 기인한다.

Phased Array Antenna Using Active Device

  • Seo, Chul-Hun
    • KIEE International Transactions on Electrophysics and Applications
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    • 제4C권6호
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    • pp.306-309
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    • 2004
  • This paper presents a new active antenna consisting of a microstrip patch for the passive radiator, a mixer for frequency conversion, a voltage controlled oscillator (VCO) and a phase detector for phase control. The microwave signal frequency has been converted into intermediate frequency (IF) on the antenna elements by the mixer. The active antenna consists of two ports, the IF port has a transmitted IF signal via power combined to the baseband and the dc control port is under the control of the phase-detector. The input voltage of the VCO is controlled by the phase detector. The scan range of the array is determined by the phase detector and the VCO and is obtained between 30$^{\circ}$ and - 30$^{\circ}$

위상신호를 이용한 단순평판의 진동계측 (Measurement of Plate Vibration by Using Phase Signals)

  • 함연수;김정수;김관주
    • 소음진동
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    • 제10권6호
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    • pp.949-954
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    • 2000
  • Applicability of the vibration signal phase for predicting the modal damping properties of structures is investigated. For uniform plates with different internal damping levels, the phase delay as a function of the frequency span as well as a function of the distance between the excitation and response measurement points are experimentally obtained. Dependence of the phase characteristics on the amount of structural damping is elucidated -more heavily damped plate shows notably reduced phase delay at intermediate distances. The experimental results compare favorably with analytical predictions, and show much promise for further refinement as a tool for estimating structural properties.

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Nonequilibrium Phenomena in Globally Coupled Active Rotators with Multiplicative and Additive Noises

  • Kim, Seung-Hwan;Park, Seon-Hee;Ryu, Chang-Su
    • ETRI Journal
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    • 제18권3호
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    • pp.147-160
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    • 1996
  • We investigate noise-induced phase transitions in globally coupled active rotators with multiplicative and additive noises. In the system there are four phases, stationary one-cluster, stationary two-cluster, moving one-cluster, and moving two-cluster phases. It is shown that multiplicative noise induces a bifurcation from one-cluster phase to two-cluster phase. Pinning force also induces a bifurcation from moving phase to stationary phase suppressing the multiplicative noise effect. Additive noise reduces both effects of multiplicative noise and pinning force urging the system to the stationary one-cluster phase. The frustrated effects of pinning force and additive and multiplicative noises lead to a reentrant transition at intermediate additive noise intensity. Nature of the transition is also discussed.

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귀금속(Au, Rh) 전극계면에서 Langmuir 흡착등온식에 관한 위상이동방법 (The Phase-Shift Method for the Langmuir Adsorption Isotherms at the Noble Metal (Au, Rh) Electrode Interfaces)

  • 천장호;전상규;이재항
    • 전기화학회지
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    • 제6권2호
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    • pp.119-129
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    • 2003
  • The Langmuir adsorption isotherms of the over-potentially deposited hydrogen (OPD H) fur the cathodic $H_2$ evolution reaction (HER) at the poly-Au and $Rh|0.5M\;H_2SO_4$ aqueous electrolyte interfaces have been studied using cyclic voltammetric and ac impedance techniques. The behavior of the phase shift $(0^{\circ}{\leq}{-\phi}{\leq}90^{\circ})$ for the optimum intermediate frequency corresponds well to that of the fractional surface coverage $(1{\geq}{\theta}{\geq}0)$ at the interfaces. The phase-shift profile $({-\phi}\;vs.\;E)$ for the optimum intermediate frequency, i.e., the phase-shift method, can be used as a new electrochemical method to determine the Langmuir adsorption isotherm $({\theta}\;vs.\;E)$ of the OPD H for the cathodic HER at the interfaces. At the poly-Au|0.5M $H_2SO_4$ aqueous electrolyte interface, the equilibrium constant (K) and the standard free energy $({\Delta}G_{ads})$ of the OPD H are $2.3\times10^{-6}$ and 32.2kJ/mol, respectively. At the poly-Rh|0.5M $H_2SO_4$ aqueous electrolyte interface, K and ${\Delta}G_{ads}$ of the OPD H are $4.1\times10^4\;or\;1.2\times10^{-2}$ and 19.3 or 11.0kJ/mol depending on E, respectively. In contrast to the poly-Au electrode interface, the two different Langmuir adsorption isotherms of the OPD H are observed at the poly-Rh electrode interface. The two different Langmuir adsorption isotherms of the OPD H correspond to the two different adsorption sites of the OPD H on the poly-Rh electrode surface.

RISC 컴파일러 레지스터 할당부 설계 (The Design of A Register Allocation Phase for RISC Compilers)

  • 박종덕;임인칠
    • 대한전자공학회논문지
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    • 제27권8호
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    • pp.1211-1220
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    • 1990
  • This paper describes and implements a design method of register allocation as a required module of RISC compiler systems. It compiles a C program to a machine-independent intermediate language, translates each variable into symbolic register. After local allocation process for the symbolic registers, global register allocation is executed by applying the graph coloring algorithm. This register allocation phase is designed for a system with the large register file like RISC machines.

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PLL을 이용한 HF 대 합성기의 주파수 조정에 관한 연구 (A study on the Frequency control of HF Synthesizer using a Phase-Locked Loop)

  • 송원용;김경기
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1987년도 정기총회 및 창립40주년기념 학술대회 학회본부
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    • pp.86-89
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    • 1987
  • This paper treats with the design and fabrication of a frequency synthesizer for the generation of intermediate frequency of a HF band transceiver. The synthesizer is designed to control frequencies using a phase-locked loop and it is shown that method improved the performance of frequency accuracy and locking time then that of the crystal-reference system.

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화학공정에 의한 초전도 합성 (Fabrication of Superconducting Ceramics Using Chemical Process)

  • 이상헌
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 제38회 하계학술대회
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    • pp.234-235
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    • 2007
  • We have fabricated superconductor ceramics by chemical process. A high Tc superconductorwith a nominal composition of $Bi_{2}Sr_{2}Ca_{2}Cu_{3}O_y$ was prepared by the organic metal salts method. Experimental results suggest that the intermediate phase formed before the formation of the superconductor phase may be the most important factor. During the sintering, doped $Ag_{2}O$ was converted to Ag particles which were finely dispersed in superconductor samples.

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크롬부족 (란탄, 칼슘)크로마이트의 열분해과정 및 소결특성 (Thermal Decomposition and Sintering Characteristics of Cr-Deficient $(La,Ca)CrO_3$)

  • 이상기;조성걸
    • 한국세라믹학회지
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    • 제34권11호
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    • pp.1182-1186
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    • 1997
  • La0.8Ca0.2Cr0.98O3 powder was prepared using the modified Pechini process. Various crystalline phases formed during thermal decomposition were investigated. (La,Ca)CrO4 phase, first formed from the precursor, was transformed to (La,Ca)CrO3 and CaCrO4 above 80$0^{\circ}C$, which remained up to 110$0^{\circ}C$. However, only (La,Ca)CrO3 phase consisting of orthorhombic and intermediate rhombohedral polymorphs was observed after sintering at 125$0^{\circ}C$. The specimens sintered at 140$0^{\circ}C$ exhibited 98% of relative density and rather wide grain size distribution with average grain size of 3-4 ${\mu}{\textrm}{m}$. Densification and grain growth of the specimens observed above 125$0^{\circ}C$ were presumably attributed to liquid phase sintering resulted from melting of Ca3(CrO4)2 phase.

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Abnormal Grain Growth Mechanism of Calcium Hexaluminate Phase

  • Song, Jun-Ho;Jo, Young-Jin;Bang, Hee-Gon;Park, Sang-Yeup
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.525-526
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    • 2006
  • Calcium-hexaluminate phase $(CA_6)$ is known to be effective for the crack shielding due to the spinel block crystal structure. In this study, we focused to the control of $CA_6$ morphology for good damage tolerance behavior in alumina and zirconia/calcium-hexaluminate $(CA_6)$ composites. Calcium-hexaluminate $(CA_6)$ composites were prepared from zirconia, alumina and calcium carbornate powders. Calcium-hexaluminate $(CA_6)$ phase was obtained by the solid reaction through the formation of intermediate phase $(CA_2)$. $CA_6$ phase showed the column type abnormal grain grown behavior composed of small blocks. Due to the typical microstructure of $CA_6$, alumina and zirconia/calcium-hexaluminate composites provide a well controlled crack propagation behavior.

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