• Title/Summary/Keyword: Interfacial resistance

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Evaluation of Electrochemical Characteristics on Graphene Coated Austenitic and Martensitic Stainless Steels for Metallic Bipolar Plates in PEMFC Fabricated with Hydrazine Reduction Methods (하이드라진으로 환원시킨 그래핀을 코팅한 오스테나이트와 마르텐사이트 스테인리스 강 고체고분자형 연료전지 금속 분리판의 전기화학적 특성 평가)

  • Cha, Seong-Yun;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.15 no.2
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    • pp.92-107
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    • 2016
  • Graphene was coated on austenitic and martensitic stainless steels to simulate the metallic bipolar plate of proton exchange membrane fuel cell (PEMFC). Graphene oxide (GO) was synthesized and was reduced to reduced graphene oxide (rGO) via a hydrazine process. rGO was confirmed by FE-SEM, Raman spectroscopy and XPS. Interfacial contact resistance (ICR) between the bipolar plate and the gas diffusion layer (GDL) was measured to confirm the electrical conductivity. Both ICR and corrosion current density decreased on graphene coated stainless steels. Corrosion resistance was also improved with immersion time in cathodic environments and satisfied the criteria of the Department of Energy (DOE), USA. The total concentrations of metal ions dissolved from graphene coated stainless steels were reduced. Furthermore hydrophobicity was improved by increasing the contact angle.

Effect of Different Interfacial Shear Reinforcement Lengths and Types on Flexural Behavior of PC/PS-Half Slab (계면 전단 보강근 길이 및 형태 변화에 따른 PC/PS-Half Slab의 휨 거동)

  • 이차돈;이종민
    • Proceedings of the Korea Concrete Institute Conference
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    • 2001.05a
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    • pp.131-138
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    • 2001
  • Total number of seven experimental specimens of size 4.6m$\times$2.4m are designed in full scale with due considerations given to the constructability as well as economic applications. Each specimen is made with different shapes of trusses or hooks along the interfacial surface between precast panel and topping concrete to maintain appropriate shear resistance. Structural performances in terms of strength and ductility under flexural load are examined for each specimen with different types of interfacial shear resistance reinforcements. Experimentally obtained flexural strength are also compared with those of analytical predictions. Based on experimental and analytical studies, design equations are suggested for the developed precast prestressed concrete half-slab systems.

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CNTs Electric Field Enhancement of CIGS Solar Cells

  • Han, Seong-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.67-67
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    • 2011
  • Compound semiconductor/CNTs composites have shown considerably improved efficiency improvement in photovoltaic devices, which is often attributed to two different factors. One is the formation of efficient electronic energy cascade structures. The other effect of CNTs on the performance of photovoltaic devices is the decrement of interfacial resistance. The interfacial resistances at n-type/ p-type materials and/or n-type materials/TCO electrode are reduced by an outstanding electrical property of CNTs. In addition to the effects of CNTs, we report the third reason for increment of efficiency in photovoltaic devices by CNT's well-known electrical field enhancement effects. The improved ${\beta}$ values in reverse-FE currents of CIGS electrode with SWNTs layers indicate the enhancement of electrical field in photovoltaic devices, which implies the acceleration of the electron transfer rate in the cell. Due to the formation of an efficient electronic energy cascade structure and the decrease of the interfacial resistance as well as the improvement of the electrical field in the photovoltaic devices, the power conversion efficiency of electrochemically deposited superstrate-type CIGS solar cells was increased 24.3% in the presence of SWNTs and showed 10.40% conversion efficiency.

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Improvement on Interfacial, Thermal, and Water Resistance Properties of Wood Sandwich Composites for Stone Bed using CNT-Animal Glue Adhesive (탄소나노튜브/아교 접착제를 이용한 돌침대용 목재 샌드위치 복합재의 계면, 열적 및 방수특성 증가)

  • Kim, Jong-Hyun;Kwon, Dong-Jun;Shin, Pyeong-Su;Baek, Yeong-Min;Park, Ha-Seung;Moon, Sun-Ok;Park, Joung-Man
    • Composites Research
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    • v.30 no.4
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    • pp.235-240
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    • 2017
  • Animal glue, a water-soluble adhesive, has been used historically for high-performance traditional furniture despite the disadvantage of weakness against moisture. Many scientists studied the ways to improve water resistance of animal glue. Improvements on the interfacial, thermal, and water resistance properties of wood sandwich composites (WSC) was studied with carbon nanotube (CNT) wt% in animal glue. Real-time temperature of WSC was measured after WSC was heated with increasing CNT wt%. Lap shear test was performed to determine the interfacial properties of wood and animal glue with CNTs. Water resistance properties of animal glue were determined by lap shear test using specimens dipped in water and the results were compared with the dry case. Hydrophobicity of animal glue by static contact angle was correlated with the variation of lap shear test. Interfacial, thermal, and water resistance properties for animal glue were improved with properly added CNTs.

Characterization of (La,Sr))$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ Interface with Citric Acid Contents and Sintering Temperature (시트르산의 양과 소결온도에 따른 (La,Sr)$MnO_3/Gd_{0.2}Ce_{0.8}O_{1.9}$ 계면특성)

  • 윤일영;윤희성;김병호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.1
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    • pp.18-25
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    • 1998
  • G $d_{0.2}$C $e_{0.8}$ $O_{1.9}$(CGO) for electrolyte and L $a_{0.5}$S $r_{0.5}$Mn $O_3$(LSM50) for cathode in Solid Oxide Fuel Cells(SOFC) were synthesized by citrate process. Specimens were prepared with sintering temperatures at 110$0^{\circ}C$, 120$0^{\circ}C$ and 130$0^{\circ}C$, which were fabricated by slurry coating with citric acid contents. Interfacial resistance was measured between cathode and electrolyte using AC-impedance analyzer. With various citric acid content, the degree of agglomeration for the initial particles changed. Also sintering temperature changed the particle size and the degree of densification of cathode. Factors affecting the interfacial resistance were adherent degree of the electrolyte and cathode, distribution of TPB(three phase boundaries, TPB i.e., electrolyte/electrode/gas phase area) and porosity of cathode. By increasing the sintering temperature, particle size and densification of the cathode were increased. And then, TPB area which occurs catalytic reaction was reduced and so interfacial resistance was increased.sed.sed.d.

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Effects of Interfacial Adhesion and Chemical Crosslinking of HDPE Composite Systems on PTC Characteristics (HDPE 가교 결합과 계면 접착력 변화에 따른 PTC 특성 연구)

  • 김재철;이종훈;남재도
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.275-284
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    • 2003
  • The positive temperature coefficient (PTC) effects of high density polyethylene (HDPE)/carbon black composite materials were investigated by enhancing adhesive characteristics of electrodes and controlling HDPE chemical crosslinking. When the silver paste was used as an electrode for the same 45 wt% HDPE/carbon composites, the resistance was over 1 $\Omega$, which should be compared with the resistance of 0.2 $\Omega$ for the dendritic copper electrode. In general, the silver-paste electrode exhibited higher electrical resistance than cupper electrode due to the interfacial resistance between the electrode and PTC composites. The HDPE/carbon composite exhibited typical PTC characteristics maintaining a constant resistance up to vicat point and showing a maximum at the melting point of HDPE. The crosslinked HDPE significantly decreased the negative temperature coefficient (NTC) phenomena, and desirably showed a constant or slightly increasing feature of electrical resistance in the high temperature region.

A Study on Development of High Strength and Wear Resistance Intermetallic Compounds/Al Matrix Composites (고강도 내마모 금속간화합물/Al기지 복합재료의 개발을 위한 기초연구)

  • Choi, Dap-Chun;Lee, Kyung-Ku;Lee, Ho-Jong;Ghi, Whe-Bong
    • Journal of Korea Foundry Society
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    • v.13 no.3
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    • pp.276-284
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    • 1993
  • The interfacial phenomena between intermetallic compounds and Al matrix have been studied at $680^{\circ}C$ for various holding time under argon atmosphere. Model experiments were performed using Fe, Ni and Ti wire to observe the interfacial phenomena. The interfacial phenomena between intermetallic compounds and Al matrix were analysed by optical microscope, SEM and EDX. The results of EDX and XRD showed that the interfacial zones of intermetallic compounds/Al matrix were composed of several intermetallic layers. The reaction layer was varied with holding time and heating temperature. The investigation of interfacial zones in the specimen as a function of heat treatment time at $680^{\circ}C$ indicated that the best heat treatment condition for squeeze casting was $680^{\circ}C$ for 5min.

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Interfacial Boundary Estimation in Stratified Flow of Two Immiscible Liquids Using Hybrid-type Fourier Series

  • Kim, Bong Seok;Choi, Bong-Yeol;Kim, Kyung Youn
    • Journal of IKEEE
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    • v.18 no.4
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    • pp.463-470
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    • 2014
  • In stratified flows of two immiscible liquids, due to the vibration in a pipe, the shape of the interface is not always periodic and it causes the different end points of the interfacial boundary. In this case the performance is not good. To solve this, in this paper, the hybrid-type Fourier series is proposed, which consists of both the polynomial and the trigonometric terms. Under the stationary interfacial boundary during acquiring a full set of voltage data, the performance of the proposed method is evaluated through the numerical experiments. The results show that the proposed method performs better than the conventional Fourier series in estimating the interfacial boundary.

Effect of Ni Addition Interfacial Reaction and Corrosion Resistance in Hot Dip Galvanizing (용융안연 도금욕의 Ni첨가가 도금강판의 게면반응 및 내식성에 미치는 영향)

  • 이경구;시희봉;이도재
    • Journal of the Korean institute of surface engineering
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    • v.31 no.6
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    • pp.379-388
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    • 1998
  • The iron-zinc interfacial reaction and corrosin properties in galvanizing bath containning Ni have been intestigated. The substrate steel plates were galvanized in Zn or Zn-0.018Al baths with various Ni contents. The corrosion resistance of galvanized specimens was also evaluated by $60^{\circ}$bending test for galvannealing speaaimens. The corrosion resistance was improved with Ni addition in pure Zn bath, while deteriorated with Ni addition in Zn-0.18Al bath. The anti-powdering property, on thhe otherhand, was improved with Ni addition in Zn-0.18Al bath, while deteriorated with Ni addition in pure Zn. It was found that the anti-powdering property was improved with increasing $\xi$ phase ratio in reaction layer.

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Conducting and interface characterization of carbonate-type organic electrolytes containing EMImBF4 as an additive against activated carbon electrode

  • Kim, Mingyeong;Kim, Kyungmin;Kim, Seok
    • Carbon letters
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    • v.16 no.1
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    • pp.51-56
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    • 2015
  • Carbonate-type organic electrolytes were prepared using propylene carbonate (PC) and dimethyl carbonate (DMC) as a solvent, quaternary ammonium salts, and by adding different contents of 1-ethyl-3-methyl imidazolium tetrafluoroborate ($EMImBF_4$). Cyclic voltammetry and linear sweep voltammetry were performed to analyze conducting behaviors. The surface characterizations were analyzed by scanning electron microscopy method and X-ray photoelectron spectroscopy. From the experimental results, increasing the $EMImBF_4$ content increased the ionic conductivity and reduced bulk resistance and interfacial resistance. In particular, after adding 15 vol% $EMImBF_4$ in 0.2 M $SBPBF_4$ PC/DMC electrolyte, the organic electrolyte showed superior capacitance and interfacial resistance. However, when $EMImBF_4$ content exceeded 15 vol%, the capacitance was saturated and the voltage range decreased.