• 제목/요약/키워드: Interfacial Properties

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Microdroplet 시험법과 Surface Wettability 측정을 이용한 전기증착된 탄소섬유 강화 Epoxy-PEI 복합재료의 계면물성과 미세파괴 메카니즘 (Interfacial Properties and Microfailure Mechanisms of Electrodeposited Carbon Fiber/epoxy-PEI Composites by Microdroplet and Surface Wettability Tests)

  • Kim, Dae-Sik;Kong, Jin-Woo;Park, Joung-Man;Kim, Minyoung;Kim, Wonho;Park, In-Seo
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2001년도 추계학술발표대회 논문집
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    • pp.153-157
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    • 2001
  • Interfacial properties and microfailure modes of electrodeposition (ED) treated carbon fiber reinforced polyetherimide (PEI) toughened epoxy composite were investigated using microdroplet test and the measurement of surface wettability. As PEI content increased, Interfacial shear strength (IFSS) increased due to enhanced toughness and plastic deformation of PEI. In the untreated case, IFSS increased with adding PEI content, and IFSS of pure PEI matrix showed the highest. On the other hand, for ED-treated case IFSS increased with PEI content with rather low improvement rate. The work of adhesion between fiber and matrix was not directly proportional to IFSS for both the untreated and ED-treated cases. The matrix toughness might contribute to IFSS more likely than the surface wettability. Interfacial properties of epoxy-PEI composite can be affected efficiently by both the control of matrix toughness and ED treatment.

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Sn-Bi-Ag계 땜납과 Cu기판과의 젖음성, 계면 반응 및 기계적 성질에 관한 연구 (A Study on Wetting, Interfacial Reaction and Mechanical Properties between Sn-Bi-Ag System Solders and Cu Substrate)

  • 서윤종;이경구;이도재
    • 한국주조공학회지
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    • 제17권3호
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    • pp.245-251
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    • 1997
  • Solderability, interfacial reaction and mechanical properties of joint between Sn-Bi-Ag base solder and Cu-substrate were studied. Solders were subjected to aging treatments to see the change of mechanical properties for up to 30 days at $100^{\circ}C$, and then also examined the changes of microstructure and morphology of interfacial compound. Sn-Bi-Ag base solder showed about double tensile strength comparing to Pb-Sn eutectic solder. Addition of 0.7wt%Al in the Sn-Bi-Ag alloy increase spread area on Cu substrate under R-flux and helps to reduce the growth of intermetallic compound during heat-treatment. According to the aging experiments of Cu/solder joint, interfacial intermetallic compound layer was exhibited a parabolic growth to aging time. The result of EDS, it is supposed that the soldered interfacial zone was composed of $Cu_6Sn_5$.

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나노 SiC 입자의 형상에 따른 탄소섬유 강화 에폭시 복합재료의 기계적 및 계면 물성 변화 관찰 (Improvement of Mechanical and Interfacial Properties of Carbon Fiber/Epoxy Composites by Adding Nano SiC Fillers)

  • 권동준;왕작가;김제준;장기욱;박종만
    • 접착 및 계면
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    • 제14권2호
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    • pp.75-81
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    • 2013
  • SiC 나노입자를 이용하여 에폭시 복합재료를 제조할 수 있다. SiC 형상에 따른 영향으로 복합재료의 계면 물성이 변화된다. SiC의 형상에 따른 계면 상태의 변화를 관찰하기 위해 베타 형태, 위스커 형태의 SiC 나노입자를 사용하였다. 나노입자에 대한 분산도를 평가하기 위해 커패시턴스를 이용한 분산도 평가방법을 활용하였다. FE-SEM을 이용하여 SiC 나노입자의 활용에 따른 나노복합재료의 파단면을 관찰하여, 그 강화 효과를 비교 분석하였다. 탄소섬유와 SiC 나노입자가 함유된 에폭시를 이용한 복합재료에 계면 물성을 비교하기 위해 층간전단강도 평가법과 계면전단강도 평가법을 이용하였다. 복합재료의 계면 물성을 강화하기 위해서는 베타 형태의 SiC 나노입자를 활용할 경우가 위스커 입자를 이용한 경우보다 높은 계면 강도를 나타냈다.

계면중합법을 이용한 폴리아마이드 610/탄소섬유/탄소나노튜브 복합재 제조 및 물성 평가 (Processing and Characterization of Polyamide 610/Carbon Fiber/Carbon Nanotube Composites through In-Situ Interfacial Polymerization)

  • 조범곤;황상하;박영빈
    • Composites Research
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    • 제33권6호
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    • pp.415-420
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    • 2020
  • 탄소섬유강화 플라스틱(CFRP)의 계면 특성은 복합재료의 전체적인 기계적 특성을 제어하므로 매우 중요하다. 이에 따라, 탄소나노튜브(CNT)로 탄소섬유(CF) 표면을 개질하는 것이 계면을 강화하기 위해 활발히 연구되고 있다. 그러나 대부분의 표면 개질 방법은 자체적으로 한계가 있다. 예를 들어, CVD 성장에서 탄소섬유의 CNT를 성장시키기 위해 600~1000℃ 범위의 고온을 적용해야 하며, 이는 탄소섬유 자체에 손상을 줄 수 있으므로 물성이 저하될 수 있다. 한편, 본 연구에서는, 폴리아마이드(PA) 610/CF/CNT 복합재가 PA610의 계면중합을 통해 제조되었으며, 유기계와 수계 사이의 계면에서 PA610/CNT 중합이 일어난다. 탄소섬유는 CNT가 균일하게 분산된 PA610으로 코팅되었다. 복합재 내에서의 CNT 분산상태는 주사전자현미경으로 관찰되었으며, 열중량 분석을 통해 복합재의 열안정성을 분석하였다. 그리고 섬유 뽑힘 시험을 통해 섬유와 기지 간의 계면 결합력을 측정하였다.

LSR-XLPE, EPDM-XLPE 이종계면에서의 계면처리에 따른 절연파괴특성 (The Study for the Breakdown Characteristics of Interface between LSR-XLPE, EPDM-XLPE by the Interfacial Treatment Condition)

  • 조한구;이유정
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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    • pp.460-461
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    • 2007
  • In this paper, we studied the properties of a cable insulate capacity between surfaces with the variation of the interfacial breakdown. As a function of silicon oil, the variation of pressure and interfacial roughness were investigated. The insulate trouble of a power cable is out of the interfacial parts, which breakdown the insulate breakdown capacity in a power cable. In this study, the analysis of electric field and the phenomenon of interfacial breakdown were improved by increased interfacial pressure, decreased surface roughness, and oil. And It was shown that interfacial breakdown LSR-XLPE insulators is higher that of EPDM-XLPE.

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에폭시/우레탄 블렌드의 경화거동과 기계적 계면특성에 관한 연구 (Cure Behaviors and Mechanical Interfacial Properties of Epoxy/Polyurethane Blends)

  • 석수자;이재락;박수진
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2004년도 추계학술발표대회 논문집
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    • pp.104-107
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    • 2004
  • In this work, the blend of diglycidylether of bisphenol A (DGEBA) and modified polyurethane (PU) was prepared and characterized in the cure behaviors and mechanical interfacial properties. The N-benzylpyrazinium hexafluoroantimonate was used as a cationic initiator for cure, and the content of PU was varied within 0-20 phr. The cure behaviors and mechanical interfacial properties were studied by DSC, near­IR, and the critical stress intensity actor $(K_{IC})$ measurements. Also thermal stabilities were carried out by TMA and TGA analyses. As a result, the cure activation energy $(E_a)$ and the conversion $(\alpha)$ were slightly increased with increasing the PU content, and a maximum value was found at 10 phr PU. The mechanical interfacial properties measured from $K_{IC}$ showed a similar behaviors with the results of conversion. These results were probably due to the increase of the hydrogen bonding between the hydroxyl groups of DGEBA and isocyanate groups in PU.

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Effects of Fiber Surface-Treatment and Sizing on the Dynamic Mechanical and Interfacial Properties of Carbon/Nylon 6 Composites

  • Cho, Dong-Hwan;Yun, Suk-Hyang;Kim, Jun-Kyung;Lim, Soon-Ho;Park, Min;Lee, Geon-Woong;Lee, Sang-Soo
    • Carbon letters
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    • 제5권1호
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    • pp.1-5
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    • 2004
  • The effects of fiber surface-treatment and sizing on the dynamic mechanical properties of unidirectional and 2-directional carbon fiber/nylon 6 composites by means of dynamic mechanical analysis have been investigated in the present study. The interlaminar shear strengths of 2-directional carbon/nylon 6 composites sized with various thermosetting and thermoplastic resins are also measured using a short-beam shear test method. The result suggests that different surface-treatment levels onto carbon fibers may influence the storage modulus and tan ${\delta}$ behavior of carbon/nylon 6 composites, reflecting somewhat change of the stiffness and the interfacial adhesion of the composites. Dynamic mechanical analysis and short-beam shear test results indicate that appropriate use of a sizing material upon carbon fiber composite processing may contribute to enhancing the interfacial and/or interlaminar properties of woven carbon fabric/nylon 6 composites, depending on their resin characteristics and processing temperature.

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Interfacial bond properties and comparison of various interfacial bond stress calculation methods of steel and steel fiber reinforced concrete

  • Wu, Kai;Zheng, Huiming;Lin, Junfu;Li, Hui;Zhao, Jixiang
    • Computers and Concrete
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    • 제26권6호
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    • pp.515-531
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    • 2020
  • Due to the construction difficulties of steel reinforced concrete (SRC), a new composite structure of steel and steel fiber reinforced concrete (SSFRC) is proposed for solving construction problems of SRC. This paper aims to investigate the bond properties and composition of interfacial bond stress between steel and steel fiber reinforced concrete. Considering the design parameters of section type, steel fiber ratio, interface embedded length and concrete cover thickness, a total of 36 specimens were fabricated. The bond properties of specimens were studied, and three different methods of calculating interfacial bond stress were analyzed. The results show: relative slip first occurs at the free end; Bearing capacity of specimens increases with the increase of interface embedded length. While the larger interface embedded length is, the smaller the average bond strength is. The average bond strength increases with the increase of concrete cover thickness and steel fiber ratio. And calculation method 3 proposed in this paper can not only reasonably explain the hardening stage after the loading end curve yielding, but also can be applied to steel reinforced high-strength concrete (SRHC) and steel reinforced recycled coarse aggregate concrete (SRRAC).

Molecular Dynamics Simulations of Graphite-Vinylester Nanocomposites and Their Constituents

  • Alkhateb, H.;Al-Ostaz, A.;Cheng, A.H.D.
    • Carbon letters
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    • 제11권4호
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    • pp.316-324
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    • 2010
  • The effects of geometrical parameters on mechanical properties of graphite-vinylester nanocomposites and their constituents (matrix, reinforcement and interface) are studied using molecular dynamics (MD) simulations. Young's modulii of 1.3 TPa and 1.16 TPa are obtained for graphene layer and for graphite layers respectively. Interfacial shear strength resulting from the molecular dynamic (MD) simulations for graphene-vinylester is found to be 256 MPa compared to 126 MPa for graphitevinylester. MD simulations prove that exfoliation improves mechanical properties of graphite nanoplatelet vinylester nanocomposites. Also, the effects of bromination on the mechanical properties of vinylester and interfacial strength of the graphene.brominated vinylester nanocomposites are investigated. MD simulation revealed that, although there is minimal effect of bromination on mechanical properties of pure vinylester, bromination tends to enhance interfacial shear strength between graphite-brominated vinylester/graphene-brominated vinylester in a considerable magnitude.

Electro-Micromechanical Technique을 이용한 각의 변화에 따른 Carbon과 SiC Fiber/Epoxy Composites의 계면감지능 및 평가 (Interfacial Sensing and Evaluation of Carbon and SiC Fibers/Epoxy Composites with Different Embedding Angle using Electro-Micromechanical Technique)

  • Lee, Sang-Il;Kong, Jin-Woo;Park, Joung-Man
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 춘계학술발표대회 논문집
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    • pp.199-202
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    • 2002
  • Interfacial properties and electrical sensing for fiber fracture in carbon and SiC fibers/epoxy composites were investigated by the electrical resistance measurement and fragmentation test. As fiber-embedded angle increased, interfacial shear strength (IFSS) of two-type fiber composites decreased, and the elapsed time was long to the infinity in electrical resistivity. The initial slope of electrical resistivity increased rapidly to the infinity at higher angle, whereas electrical resistivity increased gradually at small angle. Furthermore, both fiber composites with small embedded angle showed a fully-developed stress whitening pattern, whereas both composites with higher embedded angle exhibited a less developed stress whitening pattern. As embedded angle decreased, the gap between the fragments increased and the debonded length was wider for both fiber composites. Electro-micromechanical technique can be a feasible nondestructive evaluation to measure interfacial sensing properties depending on the fiber-embedded angle in conductive fiber reinforced composites.

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