• Title/Summary/Keyword: Interfacial Properties

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Shear bond strength of a layered zirconia and porcelain according to treatment of zirconia liner (치과용 지르코니아 이장재 처리에 따른 지르코니아와 도재의 전단결합강도 비교)

  • Seo, Jeong Il;Park, Won Uk;Kim, Yang Geun
    • Journal of Technologic Dentistry
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    • v.39 no.1
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    • pp.43-52
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    • 2017
  • Purpose: Physical and chemical properties of gold is most suitable to be restored of teeth to its original state. Recently zirconia was used instead of gold because of esthetical and intimacy of human body. Because of high strength and high abrasion resistance of zirconia, all zirconia artificial tooth lead to wear the original tooth of opposite site. To preserve this original tooth, zirconia artificial tooth covered with dental ceramic glass was used. When joining the zirconia core and dental ceramic glass, difference of their thermal expansion coefficient and wetting ability is generated the residual stress at interface lead to crack. In order to solve this problem, intermediate layer what is called zir-liner was imported to decrease the residual stress and increase the bonding strength. Methods: In this study, to identify the optimum conditions for manufacturing process, various methods to rough the surface of zirconia core were adopted, and vary the thickness of interlayer, and analyzed bond strength. Results: Bond strength of sanding specimens group showed higher than that of non-sanding specimens group, and once applied intermediate layer with sanding specimens showed highest bond strength with 28 MPa. SEM photomicrographs of zirconia cores fired at $1500^{\circ}C$ showed parallel straight lines in sanding and pockmarked surface in blasting surfaces as abrasion traces. Observation of the destruction section after shear test by SEM were carried out. Liner applied non-sanding group and non-liner applied sanding group all showed interfacial crack. Sandblasting group with non-liner showed remained dental ceramic glass on the surface of zirconia. Sandblasting group with once applied liner showed partially remained liner and dental ceramic glass on the surface of zirconia. XRD analysis revealed that sandblasting group showed higher monoclinic peaks than other specimens group and this result was due to the high collision energy for stress induced phase transformation. Conclusions: A study on the improvement of bonding strength between zirconia and dental ceramic glass steadily carried out for the future to practical use.

Environment Deterioration Characteristics of Polypropylene / Glass Fiber Composites under Moisture Absorption Environment (흡습 환경 하의 폴리프로필렌/유리 섬유 강화 복합재료의 환경 열화 특성)

  • Kim, Yun-Hae;Park, Chang-Wook;Jung, Gyung-Seok;Shin, Seok-Jin
    • Journal of Ocean Engineering and Technology
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    • v.30 no.6
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    • pp.520-525
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    • 2016
  • In this study, a mixture of polypropylene fibers and glass fibers were used to weave polypropylene/glass fiber-reinforced composite panels with characteristics such as highly elongated short fibers, high ductility, anti-fouling, and hydrophobicity as a result of a directional property. Mechanical and environmental tests were carried out with specimens fabricated with this composite panel, and its applicability to shipbuilding and ocean leisure industries was evaluated through a comparison with existing glass fiber-reinforced composite materials. The results of this experiment verified the excellence of the polypropylene/glass-mixed woven fiber-reinforced composite material compared to the existing glass fiber-reinforced composite material. However, the forming process needs to be changed to improve the weak interfacial bonding, and the properties of the composite material itself could be improved through mixed weaving with other fibers after development. Maximizing of the advantages of the polypropylene fibers and overcoming their shortcomings will improve their applicability to the shipbuilding, ocean leisure, and other industries, and increase the value of polypropylene fibers in the composite material market.

Evaluation of SHCC on Direct Tensile Load using Acoustic Emission Technique (음향방출기법을 이용한 혼입되는 섬유의 종류에 따른 SHCC의 직접인장거동특성 평가)

  • Kim, Yun-Su;Yun, Hyun-Do;Jeon, Esther;Park, Wan-Shin
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.177-180
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    • 2008
  • SHCC shows the high energy tolerance capacity due to the interfacial bonding of the fibers to the cement matrix. For effective material design and application of SHCC, it is needed to investigate the damage process and micro-fracture mechanism of cement matrix reinforced with different types of fibers. The objective of this paper is to investigate the direct tensile response of cement composites reinforced with single and hybrid fibers using acoustic emission(AE) technique. In this study, the correlations between AE signal and result of the direct tensile response of SHCC. For these purposes, three kinds of fibers were used: PET1.5%, PET1.0+PE0.5%, PET1.0%+PVA0.5%. The result of the direct tensile response of SHCC, for the same volume fraction of fibers, ultimate strength of PET-PE specimen was 2.7 times higher than specimens with PET fibers. And from AE signal value, AE event numbers and cumulative energy were different according to kind of fiber because of the different material properties of reinforced fiber.

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Analysis of Insulating Reliability in Epoxy Composites (Epoxy 복합체의 절연 신뢰도 해석)

  • 임중관;천민우;박용필
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.10a
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    • pp.724-728
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    • 2001
  • In this study, the dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. The dielectric breakdown characteristics origin in epoxy composites were examined and various effects of dielectric breakdown on epoxy composites were also discussed. As a result, first of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. And the breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised, the electric field is concentrated, and the acceleration of electron and the growth of electron avalanche are early accomplished. In the case of filled specimens with treating silane, the breakdown strength become much higher since this suggests that silane coupling agent improves interfacial combination and relaxs electric field concentration. Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1%, the applied field value needed to be under 21.5㎹/cm.

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A Experimental Study on the Property of Lightweight Aggregate Concrete Using Hollow Micro Sphere (유리질 중공 미소 구체를 사용한 경량골재콘크리트의 특성에 관한 실험적 연구)

  • Kim, Sang Heon;Kim, Se Hwan;Park, Young Shin;Jeon, Hyun Gyu;Seo, Chee Ho
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.177-183
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    • 2015
  • In this study, the thermal conductivity, physical and mechanical properties of lightweight aggregate concretes with hollow micro sphere(HMS) are experimentally examined as a basic research for the development of structural insulation concrete. As the results of this experiment, in the case of concrete mixed with HMS, the value of slump has been reduced, so it is found that the dosage of superplasticizer should be increased. As the replacement ratio of HMS increases, it has shown that the compressive strength is somewhat decreased due to the low interfacial adhesion strength of HMS. But the thermal conductivity is found to be greatly improved with the replacement ratio of HMS increases, the thermal conductivity of HMS shows the lower value of 68% at lightweight aggregate concrete and 32% of normal concrete. Also it is found that the compressive strength is decreased and thermal conductivity is increased as the water-cement ratio increases. The most outstanding for insulation performance is observed when using 20% of HMS and 50% of water-cement ratio.

Characterization of Thickness and Thermoelastic Properties of Interphase in Polymer Nanocomposites using Multiscale Analysis (멀티스케일 해석을 통한 고분자 나노복합재의 계면 상 두께와 열탄성 물성 도출)

  • Choi, Joonmyung;Cho, Maenghyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.29 no.6
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    • pp.577-582
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    • 2016
  • In this study, a multiscale method for solving a thermoelasticity problem for interphase in the polymeric nanocomposites is developed. Molecular dynamics simulation and finite element analysis were numerically combined to describe the geometrical boundaries and the local mechanical response of the interfacial region where the polymer networks were highly interacted with the nanoparticle surface. Also, the micrmechanical thermoelasticity equations were applied to the obtained equivalent continuum unit to compute the growth of interphase thickness according to the size of nanoparticles, as well as the thermal phase transition behavior at a wide range of temperatures. Accordingly, the equivalent continuum model obtained from the multiscale analysis provides a meaningful description of the thermoelastic behavior of interphase as well as its nanoparticle size effect on thermoelasticity at both below and above the glass transition temperature.

Interaction and mechanical effect of materials interface of contact zone composite samples: Uniaxial compression experimental and numerical studies

  • Wang, Weiqi;Ye, Yicheng;Wang, Qihu;Luo, Binyu;Wang, Jie;Liu, Yang
    • Geomechanics and Engineering
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    • v.21 no.6
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    • pp.571-582
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    • 2020
  • Aiming at the mechanical and structural characteristics of the contact zone composite rock, the uniaxial compression tests and numerical studies were carried out. The interaction forms and formation mechanisms at the contact interfaces of different materials were analyzed to reveal the effect of interaction on the mechanical behavior of composite samples. The research demonstrated that there are three types of interactions between the two materials at the contact interface: constraint parallel to the interface, squeezing perpendicular to the interface, and shear stress on the interface. The interaction is mainly affected by the differences in Poisson's ratio and elastic modulus of the two materials, stronger interface adhesion, and larger interface inclination. The interaction weakens the strength and stiffness of the composite sample, and the magnitude of weakening is positively correlated with the degree of difference in the mechanical properties of the materials. The tensile-shear stress derived from the interaction results in the axial tensile fracture perpendicular to the interface and the interfacial shear facture. Tensile cracks in stronger material will propagation into the weaker material through the bonded interface. The larger inclination angle of the interface enhances the effect of composite tensile/shear failure on the overall sample.

PZT/LSMO/Pt Thin-Film by Pulse Laser and Sol-Gel Deposition (PZT/LSMO/Pt에 대한 펄스레이저 및 졸겔법에 의한 증착연구)

  • Choi, Kang-Ryong;Shim, In-Bo;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.15 no.1
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    • pp.21-24
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    • 2005
  • This work is to present each properties and the interfacial characterization between PZT layer and LSMO layer of PZT/LSMO/Pt. LSMO thin film grown by KrF(248 nm) excimer lasers are used in pulsed in pulsed laser deposition(PLD). PZT coposites thin films were deposited by spin coating using a commercial resist spinner. LSMO thin film by deposition oxygen pressure 125 mtorr have rhombohedral structure on Pt(111) substrate. The PZT/LSM/Pt pre-orientate to [111] direction. The final thin films were shown that magnetic and electric property was typical value, respective. We report that the lattice between the PZT/LSMO thin film and the substrate plays a very important role and may control to another effects.

Emulsion Properties of Pseudo-Ceramide PC104/Water/Polyoxyethylene Cholesteryl Ether and Polyoxyethylene Cetyl Ether Mixtures.

  • Kim, Do-Hoon;Oh, Seong-Geun;Lee, Young-Jin;Kim, Youn-Joon;Kim, Han-Kon;Kang, Hak-Hee
    • Proceedings of the SCSK Conference
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    • 2003.09b
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    • pp.330-342
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    • 2003
  • The formation of emulsions and micelles in water/ceramide PC104/CholE $O_{20}$/C$_{16}$E $O_{20}$ and water/ceramide PC104/CholE $O_{20}$ mixtures was investigated through the phase behavior studies. The phase diagrams showed the existence of micelle and emulsion regions in both systems. The mixed surfactant system (CholE $O_{20}$/C$_{16}$E $O_{20}$) showed the wider micellar and emulsion regions than the single surfactant system (CholE $O_{20}$). From FT-IR measurements, it was found that the polyoxyethylene (POE) groups of surfactants formed the hydrogen bonds with amido carbonyl group in ceramide PC104. This result indicated that the hydrophilic part (EO) of surfactants could stabilize the lamellar structure and emulsion of ceramide PC104. The mixed surfactant system (CholE $O_{20}$/C$_{16}$E $O_{20}$) resulted in the smaller emulsion droplet size due to the effect of curvature at the interface, thus further increasing emulsion stability. With the penetration of $C_{16}$E $O_{20}$into the interfacial layer of surfactants in emulsion, the curvature of the interface might be altered for the formation of smaller emulsion droplets. The mixed surfactant system could incorporate up to 4 wt. % of ceramide PC104 into emulsion more than single surfactant system.ystem.m.

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The Rheological Behaviors of Solid-Liquid Transfer Emulsion (고상-액상 전이형 에멀젼의 레올로지 거동)

  • Park, Byeong-Gyun;Han, Jong-Sub;Lee, Sang-Min;Lee, Cheon-Koo;Yoon, Moung-Seok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.31 no.2 s.51
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    • pp.135-140
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    • 2005
  • A solid state emulsion haying high velocity gradient shows two important transition ranges in the plot of storage modulus(G') as a function of shear strain, when the state is changed from solid to liquid. However, a solid state emulsion having low velocity gradient shows only one apparent transition range when the change from solid to liquid state takes place. The result implies the importance of the surface properties in the solid state emulsion. The addition of water phase in the solid state emulsion reduces the modulus in the modulus in the surface transition range by increasing interfacial friction and weakening the matrix. The addition of pigments increases the modulus in the modulus in the surface transition range by reinforcing the matrix, when there is no wafer phase in the solid state emulsion. When the solid state emulsion has water phase, however, the addition of pigments decreases the modulus in the modulus in the surface transition range.