• Title/Summary/Keyword: Interfacial Layers

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Positive Exchange Bias in Thin Film Multilayers Produced with Nano-oxide Layer

  • Jeon, Byeong-Seon;Hwang, Chan-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.304-305
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    • 2013
  • We report a positive exchange bias (HE) in thinmultilayered filmscontaining nano-oxide layer. The positive HE, obtained for our system results from an antiferromagnetic coupling between the ferromagnetic (FM) CoFe and the antiferromagnetic (AFM) CoO layers, which spontaneously form on top of the nano-oxide layer (NOL). The shift in the hysteresis loop along the direction of thecooling field and the change in the sign of exchange bias are evidence of antiferromagnetic interfacial exchange coupling between the CoO and CoFe layers. Our calculation indicates that uncompensated oxygen moments in the NOL results in antiferromagnetic interfacial exchange coupling between the CoO and CoFe layers. One of the interesting features observed with our system is that it displays the positive HE even above the bulk Neel temperature (TN) of CoO. Although the positive HEsystem has a different AFM/FM interfacial spin structure compare to that of the negative HE one, the results of the angular dependence measurements show that the magnetization reversal mechanism can be considered within the framework of the coherent rotation model.

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Layered Silicate-Polymer Nanocomposites

  • Jeong, Han-Mo
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.18-18
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    • 2003
  • Natural clays are composed of oxide layers whose thickness is about 1nm and cations existing between the layers. A number of these layers makes primary particles with a height of about 8∼10nm and these primary particles make aggregates with a size of about 0.1∼10$\mu\textrm{m}$. When layered silicate was made to be organophilic, by exchanging the interlayer cations with organic cationic molecules, the matrix polymer can penetrate between the layers to give a nanocomposite, where 1nm-scal clay layers exist separately in a continuous polymer matrix. These nanostructured hybrid organic-inorganic composites have attracted the great interest of researchers over the last 10 years. They exhibit improved performance properties compared with conventional composites, because their unique phase morphology by layer intercalation or exfoliation maximizes interfacial contact between the organic and inorganic phases and enhances interfacial properties. Since the advent of nylon-6/montmorillonite nanocomposite developed by Toyota Motor Co., the studies on layered silicate-polymer nanocomposites have been successfully extended to other polymer systems. They greatly improved the thermal, mechanical, barrier, and even the flame-retardant properties of the polymers.

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High performance of inverted polymer solar cells

  • Lee, Hsin-Ying;Lee, Ching-Ting;Huang, Hung-Lin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.61.2-61.2
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    • 2015
  • In the past decades, green energy, such as solar energy, wind power, hydropower, biomass energy, geothermal energy, and so on, has been widely investigated and developed to solve energy shortage. Recently, organic solar cells have attracted much attention, because they have many advantages, including low-cost, flexibility, light weight, and easy fabrication [1-3]. Organic solar cells are as a potential candidate of the next generation solar cells. In this abstract, to improve the power conversion efficiency and the stability, the inverted polymer solar cells with various structures were developed [4-6]. The novel cell structures included the P3HT:PCBM inverted polymer solar cells with AZO nanorods array, with pentacene-doped active layer, and with extra P3HT interfacial layer and PCBM interfacial layer. These three difference structures could respectively improve the performance of the P3HT:PCBM inverted polymer solar cells. For the inverted polymer solar cells with AZO nanorods array as the electronic transportation layer, by using the nanorod structure, the improvement of carrier collection and carrier extraction capabilities could be expected due to an increase in contact area between the nanorod array and the active layer. For the inverted polymer solar cells with pentacene-doped active layer, the hole-electron mobility in the active layer could be balanced by doping pentacene contents. The active layer with the balanced hole-electron mobility could reduce the carrier recombination in the active layers to enhance the photocurrent of the resulting inverted polymer solar cells. For the inverted polymer solar cells with extra P3HT and PCBM interfacial layers, the extra PCBM and P3HT interfacial layers could respectively improve the electron transport and hole transport. The extra PCBM interfacial layer served another function was that led more P3HT moving to the top side of the absorption layer, which reduced the non-continuous pathways of P3HT. It indicated that the recombination centers could be further reduced in the absorption layer. The extra P3HT interfacial layer could let the hole be more easily transported to the MoO3 hole transport layer. The high performance of the novel P3HT:PCBM inverted polymer solar cells with various structures were obtained.

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Comparison of retention characteristics of ferroelectric capacitors with $Pb(Zr, Ti)O_3$ films deposited by various methods for high-density non-volatile memory.

  • Sangmin Shin;Mirko Hofmann;Lee, Yong-Kyun;Koo, June-Mo;Cho, Choong-Rae;Lee, June-Key;Park, Youngsoo;Lee, Kyu-Mann;Song, Yoon-Jong
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.3 no.3
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    • pp.132-138
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    • 2003
  • We investigated the polarization retention characteristics of ferroelectric capacitors with $Pb(Zr,Ti)O_3$ (PZT) thin films which were fabricated by different deposition methods. In thermally-accelerated retention tests, PZT films which were prepared by a chemical solution deposition (CSD) method showed rapid decay of retained polarization charges as the thickness of the films decreased down to 100 nm, while the films which were grown by metal organic chemical vapor deposition (MOCVD) retained relatively large non-volatile charges at the corresponding thickness. We concluded that in the CSD-grown films, the thicker interfacial passive layer compared with the MOCVD-grown films had an unfavorable effect on retention behavior. We observed the existence of such interfacial layers by extrapolation of the total capacitance with thickness of the films and the capacitance of these layers was larger in MOCVD-grown films than in CSD-grown films. Due to incomplete compensation of surface polarization charges by the free charges in the metal electrodes, the interfacial field activated the space charges inside the interfacial layers and deposited them at the boundary between the ferroelectric layer and the interfacial layer. Such space charges built up an internal field inside the films, which interfered with domain wall motion, so that retention property at last became degraded. We observed less imprint which was a result of less internal field in MOCVD-grown films while large imprint was observed in CSD-grown films.

Solution-processed electrophosphorescent devices with a thin fluoropolymer at the hole transport interfacial layer

  • Park, Jae-Kyun;Hwang, Gyoung-Seok;Lee, Tae-Woo;Chin, Byung-Doo
    • Journal of Information Display
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    • v.12 no.4
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    • pp.223-227
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    • 2011
  • Electrophosphorescent devices with ionomer-type hole transport layers were investigated. On top of the 3,4-ethylenedioxy thiophene:poly(4-styrene sulfonate) [PEDOT:PSS] structures, fluoropolymer interfacial layers (FPIs) with different side chain lengths were introduced. Both for the PEDOT:PSS/FPI (layered) and PEDOT:PSS (mixed) structures with soluble phosphorescent emitters, the short-side-chain FPIs showed higher efficiency. The difference in the electrical properties of the two FPIs for bipolar (light-emitting) devices was not clear, but the hole-only device clearly showed the favored hole injection at the PEDOT:PSS/FPI structure with a shorter side chain, a copolymer of tetrafluoroethylene and sulfonyl fluoride vinyl ether.

Experimental Study on the Behaviour of Interfacial Layer in Saltwater Wedge (정상염수쐐기 경계층 거동에 대한 실험적 연구)

  • Lyu, Siwan;Kim, Young Do;Choi, Jae Hoon;Seo, Il Won;Kwon, Jae Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.6
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    • pp.833-842
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    • 2009
  • A series of laboratory experiments has been performed to investigate the behaviour of interfacial layer of saltwater wedge in estuary. Experimental conditions have been established according to densimetric Froude number, which is a dimensionless number comparing inertia force with buoyancy due to the density difference. To observe the behaviour of saltwater wedge, conductivity meter has been used to detect salinity. Time averaged and temporal variation of observed properties have been analyzed to determine and investigate the interfacial layer. The location and profile of interfacial layers have shown the dependency on densimetric Froude number. The thickness of interfacial layer has been also dependent on the variation of densimetric Froude number.

A study of a new interfacial instability between two vertical fluid layers of different densities (수직평판 사이를 흐르는 두 점성유체의 밀도차에 의한 계면의 새로운 불안정성 연구)

  • Lee, Cheol-U;Ju, Sang-U;Lee, Sang-Chun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.12
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    • pp.3949-3959
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    • 1996
  • A new interfacial instability between two vertical fluid layers of different densities is studied. The two layers are flowing between two parallel vertical plates vertically upward or downward, forming counter- or concurrent flows. In order to extend the study to highly-nonlinear regime in future studies, a nonlinear interface evolution equation is derived, and the stability analysis is performed based on the evolution equation. Among the parameters studies are the ratios of the fluid densities and layer thicknesses and the net flow rate.

Response of angle-ply laminated cylindrical shells with surface-bonded piezoelectric layers

  • Wang, Haojie;Yan, Wei;Li, Chunyang
    • Structural Engineering and Mechanics
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    • v.76 no.5
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    • pp.599-611
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    • 2020
  • A state-space method is developed to investigate the time-dependent behaviors of an angle-ply cylindrical shell in cylindrical bending with surface-bonded piezoelectric layers. Both the interfacial diffusion and sliding are considered to describe the properties of the imperfect interfaces. Particularly, a matrix reduction technique is adopted to establish the transfer relations between the elastic and piezoelectric layers of the laminated shell. Very different from our previous paper, in which an approximate numerical technique, i.e. power series expansion method, is used to deal with the time-dependent problems, the exact solutions are derived in the present analysis based on the piezoelasticity equations without any assumptions. Numerical results are finally obtained and the effects of imperfect interfaces on the electro-mechanical responses of the laminated shell are discussed.

Studies on the Vibration Controllability of Smart Structure Depending on the Interfacial Adhesion Properties of Composite Materials (복합재료내의 계면 접착 특성에 따른 지능형 구조물의 진동제어에 관한 연구)

  • 한상보;박종만;차진훈
    • Journal of KSNVE
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    • v.8 no.6
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    • pp.1093-1102
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    • 1998
  • The success of controllability of smart structures depends on the quality of the bonding along the interface between the main structure and the attached sensing and acuating elements. Generally, the analysis procedures neglect the effect of the interfacial bond layer or assume that this bond layer behaves like viscoelastic material. Three different bond layers. two modified epoxy adhesives, and one isocyanate adhesive were prepared for their toughness and moduli. Bond layer of the chosen adhesive provides an almost perfect bonding condition between the composite structure and the PZT while bended significantly like arrow-shape. The perfect bonding condition is tested by considering various material properties of the bond layers. and based on this perfect bonding condition, the effects of the interfacial bond layer on the dynamic behavior and controllability of the test structure is experimentally studied. Once the perfect bonding condition is achieved. dynamic effects of the bond layer itself on the dynamic characteristics of the main structure is negligible. but the contribution of the attached PZT elements on the stiffness of the multi-layered structure becomes significant when the thickness of the bond layer increased.

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Interfacial Reaction Characteristics of a Bi-20Sb-10Cu-0.3Ni Pb-free Solder Alloy on Cu Pad (Bi-10Cu-20Sb-0.3Ni 고온용 무연 솔더와 Cu와의 계면 반응 특성)

  • Kim, Ju-Hyung;Hyun, Chang-Yong;Lee, Jong-Hyun
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.1
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    • pp.1-7
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    • 2010
  • Interfacial reaction characteristics of a Bi-10Cu-20Sb-0.3Ni Pb-free alloy on Cu pad was investigated by reflow soldering at $430^{\circ}C$. The thickness of interfacial reaction layers with respect to the soldering time was also measured. After the reflow soldering, it was observed that a $(Cu,Ni)_2Sb$, a $Cu_4Sb$ intermetallic layer, and a haze layer, which is consisted of Bi and $Cu_4Sb$ phases, were successively formed at the Bi-10Cu-20Sb-0.3Ni/Cu interface. The total thickness of the reaction layers was found to be linearly increased with increasing of the reflow soldering time up to 120 s. As the added Ni element did not participate in the formation of the thickest $Cu_4Sb$ interfacial layer, suppression of the interfacial growth was not observed.