• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1734-1740
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• 2012

Voltammetric characterization of hydrophilic anion transfer processes across a 66 microhole array interface between the water and polyvinylchloride-2-nitrophenyloctylether gel layer is demonstrated. Since the transfer of hydrophilic anions including $Br^-$, $NO_3{^-}$, $I^-$, $SCN^-$ and $ClO_4{^-}$ across the liquid/gel interface usually sets the potential window within a negative potential region, a highly hydrophobic organic electrolyte, tetraoctylammonium tetrakis(pentafluorophenyl)borate, providing a wider potential window was incorporated into the gel phase. The transfer reaction of perchlorate anions across the microhole-water/gel interface was first studied using cyclic voltammetry and differential pulse voltammetry. The full voltammetric response of perchlorate anion transfer was then used as a reference for evaluating the half-wave transfer potentials, the formal transfer potentials and the formal Gibbs transfer energies of more hydrophilic anions such as $Br^-$, $NO_3{^-}$, $I^-$, and $SCN^-$. The current response associated with the perchlorate anion transfer across the micro-water/gel interface versus the perchlorate concentration was also demonstrated for sensing applications.

• 로봇학회논문지
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• 제1권1호
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• pp.58-65
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• 2006

The emotional interface is essential technology for the robot to provide the proper service to the user. In this research, we developed emotional components for the service robot such as a neural network based facial expression recognizer, emotion expression technologies based on 3D graphical face expression and joints movements, considering a user's reaction, behavior selection technology for emotion expression. We used our humanoid robots, AMI and AMIET as the test-beds of our emotional interface. We researched on the emotional interaction between a service robot and a user by integrating the developed technologies. Emotional interface technology for the service robot, enhance the performance of friendly interaction to the service robot, to increase the diversity of the service and the value-added of the robot for human. and it elevates the market growth and also contribute to the popularization of the robot. The emotional interface technology can enhance the performance of friendly interaction of the service robot. This technology can also increase the diversity of the service and the value-added of the robot for human. and it can elevate the market growth and also contribute to the popularization of the robot.

• 한국재료학회지
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• 제27권11호
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• pp.603-608
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• 2017

$Si_3N_4$와 Ti 또는 TiAl 합금을 $900^{\circ}C$에서 확산쌍을 제조하여 분석하고, 확산층의 분석을 통하여 생성된 층마다의 조성을 분석하여 각 원소들의 확산 경로 및 속도를 비교 하였다. $Si_3N_4/Ti$의 확산 쌍의 확산 경로는 $Si_3N_4/Ti_5Si_3+TiN/TiN/Ti$로 나타났고, Ti 측면에서 TiN층이 생성 되었음으로 N의 확산 속도가 Si 보다 빠름을 알 수 있었다. $Si_3N_4/TiAl$ 합금의 확산쌍은 $Si_3N_4/Ti$ 사이의 확산쌍과는 다르게 Si, N, Ti, Al 의 각 원소 마다의 확산 속도 차이로 인하여 확산 경로는 $Si_3N_4/TiN(Al)/Ti_3Al/TiAl$ 상으로 나타났다. 상태도를 통하여 생성된 확산쌍의 확산경로를 파악한 결과, 확산경로의 요구사항을 모두 만족하였다. $Si_3N_4/Ti$ 확산에서 Ti를 이용한 적분확산 계수는 $Ti_5Si_3$, TiN에서 $2.18{\times}10^{-16}m^2/sec$, $2.19{\times}10^{-16}m^2/sec$, $Si_3N_4/TiAl$ 확산 쌍에서 Ti를 이용한 적분확산 계수는 각각 TiN(Al) 상에서 $2.88{\times}10^{-16}m^2/sec$, $Ti_3Al$ 상에서 $1.48{\times}10^{-15}m^2/sec$으로 나타났다. 본 연구는 $Si_3N_4$와 Ti 및 TiAl의 계면 반응을 분석한 결과로서 $Si_3N_4$ 상을 이용한 확산반응의 기초자료로 사용될 수 있을 것으로 사료된다.

• 한국지반환경공학회 논문집
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• 제11권11호
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• pp.47-54
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• 2010

최근 쓰레기 매립장에 보강 및 보호 목적으로 토목섬유가 널리 사용되고 있다. 최근 연구결과, 토목섬유-흙 접촉면에서는 진행성 파괴가 발생할 수 있는데 이는 토목섬유-흙 접촉면에서 함수비, 연직응력, 화학적 요소의 영향 등 고유물성에 기인한다. 본 연구에서는 침출수 내의 산성 및 염기성과 같은 성분의 영향이 진동하중 상태에서 토목섬유-흙 접촉면의 전단강도 감소에 미치는 영향을 실내 시험을 통하여 분석하였다. 다기능 접촉면 시험기를 새로 구축하고 서로 다른 pH 조건에서 수침시킨 토목섬유와 흙시료를 이용하여 진동 직접전단시험을 수행하여 접촉면 전단두께와 화학적 요소에 의한 접촉면의 전단강도 감소를 확인하였다. 또한 접촉면 전단강도 감소를 정량적으로 표현하기 위하여 교란상태개념에 기초하여 동하중 하의 화학적 인자들에 의한 토목섬유-흙 접촉면의 정규화 교란도 함수를 파악하고 전단강도 감소 특성을 확인하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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• pp.208-209
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• 2011

In this work, we developed self-assembled monolayers (SAMs) of alkanethiols on gold that can release amine groups, when an electrical potential was applied to the gold. The strategy was based on the introduction of the electroactive carbamate group, which underwent the two-electron oxidation with simultaneous release of the amine molecules, to alkanethiols. The synthesis of the designed thiol compounds was achieved by coupling isocyanate-containing compound with hydroquinone. The electroactive thiols were mixed with hydroxyl-containing alkanethiol [$HS(CH_2)_{11}OH$] to form mixed monolayers, and cyclic votammetry was used for the characterization of the release. The mixed SAMs showed a first oxidation peak at +540 mV (versus Ag/AgCl reference electrode), demonstrating irreversible conversion from carbamate to hydroqinone with simultaneous release of the amine groups. The second and third cycles showed typical reversible redox reaction of hydroquinone and quione: the oxidation and reduction occurred at +290 mV and -110 mV, respectively. The measurement of ToF-SIMS further indicates that electrochemical-assisted chemical reaction successfully released amine groups. This new SAM-based electrochemistry would be applicable for direct release of biologically active molecules that contain amine groups.

• 한국재료학회지
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• 제30권11호
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• pp.581-588
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• 2020

Reducing CO₂ into high value fuels and chemicals is considered a great challenge in the 21st century. Efficiently activating CO₂ will lead to an important way to utilize it as a resource. This article reviews the latest progress of g-C₃N₄ based catalysts for CO₂ reduction. The different synthetic methods of g-C₃N₄ are briefly discussed. Article mainly introduces methods of g-C₃N₄ shape control, element doping, and use of oxide compounds to modify g-C₃N₄. Modified g-C₃N₄ has more reactive sites, which can significantly reduce the probability of photogenerated electron hole recombination and improve the performance of photocatalytic CO₂ reduction. Considering the literature, the hydrothermal method is widely used because of its simple equipment and process and easy control of reaction conditions. It is foreseeable that hydrothermal technology will continue to innovate and usher in a new period of development. Finally, the prospect of a future reduction of CO₂ by g-C₃N₄-based catalysts is predicted.

• 한국재료학회지
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• 제11권6호
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• pp.460-464
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• 2001

Pechini방법으로 제조한 La$_{0.8}$Ca$_{0.2}$CrO$_3$CLC소결체와 La$_{0.8}$Ca$_{0.2}$CrO$_3$CLC-Green체를 YSZ에 적층한 후 온도의 함수로 계면에서의 미세구조와 성분이동 등의 거동을 고찰하였다. CLC-G/CLC와 CLC/YSZ계면에서의 CLC면은 반응온도에 상관없이 XRD 관찰에서 주상은 La$_{1-x}$ Ca$_{x}$CrO$_3$그리고 CLC와 반응하지 않은 YSZ면의 결정 상은 cubic-ZrO$_2$으로 각각 나타났다. CLC/YSZ반응 계면의 성분이동은 Zr > La>>Cr>>>Ca 순이었으며, 온도에 따른 개개 성분의 이동도 차이는 크지 않았다. CLC/YSZ계면간의 결합은 계면성분간의 과다한 성분이동 없이 현 연구의 온도전체에 걸쳐 가능한 것으로 나타났다. CLC-G/CLC간의 SEM미세구조는 결합 면을 경계로 저온에서는 결정의 입자크기 차이를 보이다가 온도가 증가할수록 균일화되는 경향을 보였다.였다. 보였다.였다.

• 한국재료학회지
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• 제31권6호
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• pp.345-352
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• 2021

In this study, Ni nanoparticle supported by graphene oxide (GO) (Ni-GO) is successfully synthesized through hydrothermal synthesis and calcination, and Cr(VI) is extracted from aqueous solution. The morphology and structure of Ni-GO composites are characterized by scanning electron microscopy (SEM), trans mission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). High-resolution transmission electron microscopy (HRTEM) and XRD confirms the high dispersion of Ni nanoparticle after support by GO. Loading Ni on GO can obviously enhance the stability of Ni-GO composites. It can be calculated from TGA that the mass percentage of Ni is about 60.67 %. The effects of initial pH and reaction time on Cr(VI) removal ability of Ni-GO are investigated. The results indicate that the removal efficiency of Cr(VI) is greater than that of bared GO. Ni-GO shows fast removal capacity for Cr(VI) (<25 min) with high removal efficiency. Dynamic experiments show that the removal process conforms to the quasi-second order model of adsorption, which indicates that the rate control step of the removal process is chemical adsorption. The removal capacity increases with the increase of temperature, indicating that the reaction of Cr(VI) on Ni-GO composites is endothermic and spontaneous. Combined with tests and characterization, the mechanism of Cr(VI) removal by rapidly adsorption on the surface of Ni-GO and reduction by Ni nanoparticle is investigated. The above results show that Ni-GO can be used as a potential remediation agent for Cr(VI)-contaminated groundwater.

• 한국기계가공학회지
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• 제3권1호
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• pp.90-94
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• 2004

Generally, a hydraulic cylinder block which is one of a vehicle parts that plays Important role in excavator power transmission, has copper alloy separation phenomenon by sliding motion between metals in high pressure condition. In this paper, to solve this problem, the interfacial reaction layer of Fe-Cu With SCM440 and copper alloy is studied through the melting method. As the result of this study, it is found that the interfacial reaction layer of $1{\mu}m$ created in the interface of Fe-Cu which has very strong physical bonding. It has been also confirmed that the melting method can improve life of the hydraulic cylinder block.

• 한국주조공학회지
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• 제26권1호
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• pp.27-33
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• 2006

Phase evolutions involving nucleation stages together with diffusional growth have been examined in order to provide a guideline for determining rate limiting stages during phase evolutions. In multiphase materials systems in coatings, composites or multilayered structures, diffusion treatments often result in the development of metastable/intermediate phases at the reaction interfaces. The development of metastable phases during solid state interdiffusion demonstrates that the nucleation reaction can be one controlling factor. Also, the concentration gradient and the relative magnitudes of the component diffusivities provide a basis for a phase selection and the application of a kinetic bias strategy in the phase selection. For multicomponent alloy systems, the identification of the operative diffusion pathway is central to control phase formation. Experimental access to the nucleation and growth stage is discussed in thin film multi layers and bulk samples.