• Journal of the Optical Society of Korea
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• v.18 no.6
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• pp.799-808
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• 2014

The mechanism of optical interaction of two nanoholes, milled in an opaque gold film, by means of surface plasmon polariton (SPP) propagation is investigated. The interaction depends on the polarization direction of the incident light when the nanohole pair is illuminated through uniform single antenna excitations. It is shown that by illuminating one of the nanoholes, under single antenna excitation, the other nanohole can be excited indirectly via propagated SPPs from the excited nanohole. In addition, it is found that the spectrum of electromagnetic power above the surface of the metallic film at an arbitrary point along the axis of the nanohole pair presents two resonant peaks. These peaks are due to the optical interaction between nanoholes, where the short- and long-wavelength peaks can be assigned to in-phase and antiphase interactions of magnetic dipoles relative to each nanohole, respectively. The magnetic coupled dipole approximation (MCDA) method confirms the simulation results.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3591-3596
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• 2013

The enantioselective aza-Morita Baylis Hillman reaction of nitroalkene and N-tosylimine catalyzed by thiourea-tertiary amine has been investigated using density functional theory. Enantioselectivity is dominated by the cooperative effect of non-covalent and weak covalent interactions imposed by different units of catalyst. As Lewis base, the tertiary amine unit activates nitroalkene via weak covalent bond. The weak covalent interaction orients the reaction in a major path with smaller variations of this bond. The aromatic ring unit activates N-tosylimine via ${\pi}-{\pi}$ stacking. The non-covalent interaction selects the major path with smaller changes of the efficient packing areas. Thiourea unit donates more compact H-bonded network for species of the major path. The calculated ee value in xylene solution phase (97.6%) is much higher than that in N,N-Dimethylformamide (27.2%). Our conclusion is also supported by NBO analysis.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2004.05a
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• pp.480-485
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• 2004

If a wall separates the bounded and unbounded spaces, then the wall's role in transporting the acoustic characteristics of the two spaces is not well defined. In this paper, we attempted to see how the acoustic characteristical of two spaces are really affected by the spatial characteristics of the wall. In order to understand coupling mechanism, we choose a finite space and a semi-infinite space separated by the flexible or rigid wall and an opening. A volume interaction can be occurred in structure boundary and a pressure interaction can be happened in the opening boundary. For its simplicity, without loosing generality, we use rather simplified rectangle model instead of generally shaped model. The source impedance is presented to the various types of boundaries. The distributions of pressure and active intensity are also presented at the cavity and structure-dominated modes. The resulting modification, shifts of mode1 frequencies and changing of standing wave patterns to satisfy both coupled boundary conditions and governing equations, are presented.

• Journal of Photoscience
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• v.12 no.3
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• pp.113-117
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• 2005

Spectroscopic investigations on the interaction of gabapentin (GBP) with bovine serum albumin (BSA) were reported. The association constant of GBP-BSA system was determined at different temperatures (298, 302, 306 and 311 K) based on the fluorescence quenching results. The GBP was found to quench the fluorescence of BSA through static mechanism. Thermodynamic parameters, the standard enthalpy change, $({\Delta}H^o)$ and the standard entropy change $({\Delta}S^o)$ were observed to be $-9.61{\pm}0.008\;kJ\;mol^{-1}$ and $3.58{\pm}0.011\;Jmol^{-1}K{-1}$ respectively. These indicated that the hydrophobic and electrostatic forces played a role in the interaction of GBP with BSA. The negative value of ${\Delta}G^o$ revealed that the binding reaction is spontaneous. The circular dichroism studies indicated the conformational changes in BSA upon interaction with GBP. The effect of some metal ions on the binding constant was also investigated.

• Journal of Ocean Engineering and Technology
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• v.16 no.1
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• pp.27-35
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• 2002

The interaction of grounded ice ridges with underlying seabed is one of the major considerations in the design of Arctic pipeline system. Previously several ice scour models were developed by researchers to describe the ice scour-seabed interaction mechanism. In view of possible improvements, a comparative study of those ice scour models is performed and their limitation in modeling is discussed. Simple laboratory tests are carried out and then the shape pattern of deposited soil around the ice model is newly defined. Unlike the rectangular idealization of an ice block, in this modified ice scour model, trapezoidal cross sections are assumed to represent the typical shape of an ice ridge based on the field observation data. With the horizontal and vertical motion of ice model, the ice scour depth and soil reacting forces on seabed are calculated with varying the keel angle of an ice ridge.

• Textile Coloration and Finishing
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• v.14 no.2
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• pp.85-85
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• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, 80℃. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• Textile Coloration and Finishing
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• v.14 no.2
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• pp.9-17
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• 2002

The interaction between berberine and tannin in aqueous solution was investigated spectrophotometerically. The dyeing mechanism of silk fabrics (control and tannin treated silk fabrics) with berberine was based on thermodynamic parameters obtained from equilibrium adsorption experiments. In adsorption spectra of aqueous solution of berberine and tannin mixture two isosbestic points (328nm, 357nm) were found and the mole fraction of reaction of components was 1:1. Initial dyeing rates were increased and the diffusion of dye was more effective by tannin treatment. Without regard to tannin treatment the adsorption isotherm of berberine was the langmuir type except high temperature, $80^\circ{C}$. By tannin treatment the saturation dye uptake was increased, the increase of dye uptake appeared to be a result of entropy change rather than enthalpy change. All these results can be interpreted by the hydrophobic interaction between berberine and silk treated with tannin and it is reasonable to conclude that not only the ionic force, but also the hydrophobic interaction contributes to the binding of berberine and tannin treated silk treated with tannin.

• Journal of Families and Better Life
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• v.24 no.3 s.81
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• pp.59-72
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• 2006

This article explores bilateralization phenomena in Korean families through intimacy and interaction with matrilineal kins. In-depth interviews were conducted with married men and women aged from their mid-30s to mid-40s. The findings indicate that the intimacy range of participants was restricted to blood-based kins. The power hypothesis was supported for male participants. Some wanted to actively contact their spouse's family members, while others did not want to be connected with the spouse's families. Interaction with wives' families was based on the exchange perspective. In contrast, a complicated mechanism existed in the intimacy and interaction of female participants. Most of them were connected with in-laws in a passive way but actively interacted with their family-of-origin. However, some female respondents did not have good relationships with their mothers. Undifferentiation between mothers and married daughters negatively influenced their relationships. Therefore, it could be concluded that bilateralization phenomena in Korean families is another kind of shackle of patrilineal norms.

• Journal of Magnetics
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• v.18 no.4
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• pp.417-421
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• 2013

The dominant magnetization reversal behavior of electrodeposited CoPt samples with various thicknesses deposited at different current densities was the domain wall motion by means of wall pinning. The magnetic interaction mechanism was dipolar interaction for all samples. The dipolar interaction strength was significantly affected by the sample thickness rather than by the current density, while the magnetic properties were closely related to the current density.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.53-56
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• 2015

A combined experimental and numerical study has been conducted to investigate the downstream interaction between simulated SNG-air premixed flames in fuel composition of 91% $CH_4$ + 6% $C_3H_8$ + 3% $H_2$. In this study, the effects of fuel molar concentration(lean-rich) and strain rate($a_g$) were major parameters. A main focus is to investigate flames behavior and chemical interaction at flames downstream. The numerical results were calculated by OPPDIF application. The reaction mechanism adopted was USC-II model including C3 reaction.