• 제목/요약/키워드: Interaction Effects

검색결과 5,270건 처리시간 0.036초

Dual Substituent Effects on Anilinolysis of Bis(aryl) Chlorothiophosphates

  • Barai, Hasi Rani;Lee, Hai Whang
    • Bulletin of the Korean Chemical Society
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    • 제34권12호
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    • pp.3597-3601
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    • 2013
  • The reactions of bis(Y-aryl) chlorothiophosphates (1) with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. The Hammett plots for substituent Y variations in the substrates show biphasic concave upwards with a break point at Y = H. The cross-interaction constants (${\rho}_{XY}$) are positive for both electron-donating and electron-withdrawing Y substituents. The kinetic results of 1 are compared with those of Y-aryl phenyl chlorothiophosphates (2). The cross-interaction between Y and Y, due to additional substituent Y, is significant enough to result in the change of the sign of ${\rho}_{XY}$ from negative with 2 to positive with 1. The effect of the cross-interaction between Y and Y on the rate changes from negative role with electron-donating Y substituents to positive role with electron-withdrawing Y substituents, resulting in biphasic concave upward free energy correlation with Y. A stepwise mechanism with a rate-limiting leaving group departure from the intermediate involving a predominant frontside attack hydrogen bonded, four-center-type transition state is proposed based on the positive sign of ${\rho}_{XY}$ and primary normal deuterium kinetic isotope effects.

전남지역 대학생의 양식당에 대한 만족도에 미치는 성과 지출비의 영향 (Effects of Gender and Expenditure on Satisfaction with Foodservice of Western Restaurants)

  • 강종헌;주영주
    • 한국생활과학회지
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    • 제15권2호
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    • pp.251-259
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    • 2006
  • The purpose of this study is to identify main effect of gender and expenditure, and interaction effect of gender by expenditure on satisfaction with foodservices of western restaurants. Accordingly, this study surveyed questionnaires concerning 20 measures of foodservice as well as major subject descriptors. The result of this study was as follows: KMO and Bartlett's test statistics showed that the data well fitted a factor analysis. Results of the factor analysis, average variance extracted estimates, and shared variance showed that the convergent and discriminant validities of 5 factors were supported, and Cronbach's alpha also showed that the internal consistencies of 5 factors were supported. But there was an interaction effect between independent variables and covariate on service quality factor. This study, therefore, used food decor factor, facility factor, food quality factor, and food value factor as dependent variables in two way 3$\times$2 design factorial ANCOVA. It was found that there were no main effects of gender and expenditure on those four factors. It was however revealed that there was an interaction effect of gender by expenditure on food decor factor.

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세포와 흡착면간의 영향을 고려한 흡착형 세포의 3 차원 동적 해석 모델 개발 (Development of Three-dimensional Chemotaxis Model for a Single Crawling Cell, Considering the Interaction between the Cell and Substrate)

  • 송지환;김동철
    • 대한기계학회논문집A
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    • 제35권11호
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    • pp.1355-1360
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    • 2011
  • 흡착형 세포의 이동에 있어 세포와 바닥면간의 상호작용은 매우 중요한 역할을 한다. 본 논문은 주화성에 의한 흡착형 세포의 이동에 있어 세포와 바닥면과의 상호작용에 따른 영향을 보이기 위해 확산계면모델을 바탕으로 한 3 차원의 입체 모델을 제안한다. 세포와 바닥면간의 영향을 표현하기 위해 세포 주위 물질과의 관계를 고려한 경계에너지를 고려하였다. 본 연구에서 적용한 확산계면모델은 경계에너지, 주화성, 확산성을 모두 고려한 다중 메커니즘 모델로서 흡착형 세포이동의 역학적 특성을 정확히 예측하는데 있어 높은 신뢰성을 보일 것이라 기대된다.

제작차륜이동 시험기의 실동주행 가속도측정 (A Real Vehicle Tracking Acceleration Using A Tire-Wheel-Tracking Machine)

  • 성익현;성승열
    • 한국재난정보학회 논문집
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    • 제7권3호
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    • pp.190-197
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    • 2011
  • 본 연구에서는 타이어를 장착한 차량시험기에서 교량과 차량의 상호작용효과를 분석하고자 반복하중시험을 실시하고 이에 대한 동적반응을 파악하였다. 이를 위하여 차량-교량간 상호작용이 포함된 이동질량형 윤하중 실험기를 단순교 형식의 교량에 적용하여 이동질량 반복주행실험을 수행하였다. 이동질량 반복주행실험 결과를 분석하여 차량-교량간의 상호작용을 포함한 가속도 형태의 실동주행차량가속도를 규명하였다. 규명된 차량의 실동주행차량가속도를 범용 해석프로그램에 적용하여 차량-교량 상호작용을 재현할 수 있었다.

Numerical study of hydrodynamic interaction on a vessel in restricted waterways

  • Lee, Chun-Ki
    • International Journal of Naval Architecture and Ocean Engineering
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    • 제4권1호
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    • pp.1-8
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    • 2012
  • The hydrodynamic interaction between ship and bank can't be neglected when a vessel is app- roached toward the tip of a wedge-shaped bank in restricted waterways, such as in a harbor, near some fixed obstacles, or in a narrow channel. In this paper, the characteristic features of the hydrodynamic interaction acting on a slowly moving vessel in the proximity of a wedge-shaped bank are described and illustrated, and the effects of water depth and the spacing between ship and wedge-shaped bank are summarized and discussed based on the slender body theory. From the theoretical results, it indicated that the hydrodynamic interactions decrease as wedge-shaped bank of angle ${\beta}$ in-creases. For water depth to draft ratio less than about 2.0, the hydrodynamic interactions between ship and bank in-crease sharply as h/d decreases, regardless of the wedge-shaped bank of angle ${\beta}$. Also, for lateral separation more than about 0.2L between ship and wedge-shaped bank, it can be concluded that the bank effects decrease largely as the separation increases.

부모의 유머스타일이 유아의 정서 표현성에 미치는 영향 (The Effects of Parents' Humor Styles on Children's Emotional Expressiveness)

  • 오연경;황혜신
    • 한국보육지원학회지
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    • 제14권6호
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    • pp.107-122
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    • 2018
  • Objective: The purpose of this study is to investigate the effects of parental humor style on their children's emotional expressiveness. Methods: Parental humor styles and their children's emotional expressiveness were measured in 306 parents and their 153 young children enrolled in a infant educational institution located in Seoul and Gyeong-gi Province. A total of 459 subjects participated in this study. The data were used in producing basic statistics and a t-test and regression analysis with SPSS 21.0 program were performed. Results: First, parents with young children were found to use humor above the medium level in interaction with their children, especially societal humor. Second, societal, self-expansive, and self-defeating humors used by mother were found to predict children's emotional expressiveness, while the humor used by fathers was found to have no effect on children's emotional expressiveness. Conclusion/Implications: The parental use of humor is a common phenomenon these days and is aimed at creating more intimate parent-child interaction. In addition, it was found that mother's humorous interaction can bring about positive emotional expressiveness in her child.

Benzodiazepine계 약물과 그 문제점

  • 오강섭
    • 대한불안의학회:학술대회논문집
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    • 대한불안의학회 2005년도 춘계학술대회
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    • pp.88-103
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    • 2005
  • o Rational Use of BZ - relative safe, widely useful o Hidden side effects/disastrous effects in vulnerable patients o Review tolerance, dependency, withdrawal symptoms o Consider Drug interaction o Periodic Evaluation of Risk/Benefit of BZ o Advice to patients planning a pregnancy

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애니메이션 캐릭터 색채에 대한 유아의 의복 선호도 -미키와 미니마우스를 중심으로- (Children's Clothing Preference on Animation Character Color -Focusing on Mickey and Mini Mouse-)

  • 성남숙;최수경
    • 한국의상디자인학회지
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    • 제13권2호
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    • pp.63-71
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    • 2011
  • The purpose of this study was to analyze children's clothing preference on animated character color. The experimental materials developed for this study were a set of stimulus and response scales. The stimuli were 30 color pictures, in which gender (boy, girl), type of character (Mickey Mouse, Mini Mouse), hue of character (red, yellow, green, blue, purple), and tone of character (vivid, light, dark) were manipulated. The 5-point scale was used to evaluate children's clothing preferences. Data were obtained from 300 boys and 300 girls living in Seoul, Busan, Jinju, and Changwon in April 2010. For data analysis, ANOVA and Duncan-test were used by using SPSS program. Results of this study were as follows. Tone of character had an independent effect on children's clothing preference. Interaction effects of gender and hue of the character were found. Interaction effects of gender and tone of the character were found. Interaction effects of type and tone of the character were found.

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소셜집단특성이 소셜커머스 재구매의도에 미치는 영향과 실용적 가치의 조절효과 (Social Group Factors Impacting the Customer Satisfaction, Trust and Intention to Re-purchase in Social Commerce and the Moderating Effects of Utilitarian Value)

  • 김상현;박현선
    • 한국정보시스템학회지:정보시스템연구
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    • 제22권2호
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    • pp.1-24
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    • 2013
  • The main purpose of this study is to understand how the characteristics of social network services' social group can impact customer satisfaction, trust and repurchase intention. For this, this study extracts five social group factors(word of mouth effect, social interaction, collectivism, variety seeking, information seeking) based on relevant literature reviews. In addition, the study examines the moderating effects of utilitarian value on the relationships between customer satisfaction and trust and intention to repurchase. The proposed model of this study is empirically tested using survey data collected from 220 social commerce users. The results indicated that social group factors except social interaction were positively related to customer satisfaction. In addition, social group factors except social interaction and information seeking were positively related to trust. The results also showed that customer satisfaction and trust had a significant influence on intention to repurchase. The moderating effects of utilitarian value also was significant. The results of this study presented the strategic implications for social commerce firms.

작품 가격 추정을 위한 기계 학습 기법의 응용 및 가격 결정 요인 분석 (Price Determinant Factors of Artworks and Prediction Model Based on Machine Learning)

  • 장동률;박민재
    • 품질경영학회지
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    • 제47권4호
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    • pp.687-700
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    • 2019
  • Purpose: The purpose of this study is to investigate the interaction effects between price determinants of artworks. We expand the methodology in art market by applying machine learning techniques to estimate the price of artworks and compare linear regression and machine learning in terms of prediction accuracy. Methods: Moderated regression analysis was performed to verify the interaction effects of artistic characteristics on price. The moderating effects were studied by confirming the significance level of the interaction terms of the derived regression equation. In order to derive price estimation model, we use multiple linear regression analysis, which is a parametric statistical technique, and k-nearest neighbor (kNN) regression, which is a nonparametric statistical technique in machine learning methods. Results: Mostly, the influences of the price determinants of art are different according to the auction types and the artist 's reputation. However, the auction type did not control the influence of the genre of the work on the price. As a result of the analysis, the kNN regression was superior to the linear regression analysis based on the prediction accuracy. Conclusion: It provides a theoretical basis for the complexity that exists between pricing determinant factors of artworks. In addition, the nonparametric models and machine learning techniques as well as existing parameter models are implemented to estimate the artworks' price.