• Title/Summary/Keyword: Inorganic polymer

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Effects of Dual-Coagulant Performance (이중응집이 응집공정에 미치는 영향)

  • Kim, Hee-Geun;Moon, Byung-Hyun;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.1
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    • pp.92-97
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    • 2005
  • This research is to investigate the effect of the dual coagulant using inorganic coagulants($AICl3{\cdot}6H2O$) and polymer on the coagulant process. Jar-test was conducted by using Kaolin injected raw water. PDA(Photometric Dispersion Analyzer) equipment in order to analyze the size of the particles and the characteristics of the shapes. The change in the rate of sample ores' residual deposited after coagulants were also compared. According to the result derived from this experiment, the concentration of inorganic coagulant reduced 50% and the residual was lower by using dual coagulants compared to using single coagulant. However the dual coagulant required sufficient mixing time, and affected particle characteristics, with the effect of the injection order of coagulants, the simultaneous injection of inorganic coagulant and polymer showed the most effective in the particle removal.

Effect of Eco-friendly Inorganic Flame Retardants on Mechanical and Flame-Retardant Properties of EPDM Compound

  • Do, Jong Hwan;Kim, Do Young;Seo, Kwan Ho
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.40-45
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    • 2020
  • In this study, the mechanical and flame-retardant properties of ethylene-propylene-diene-termonomer (EPDM) based rubber compounds and various other environmentally friendly inorganic flame retardants were investigated. Alumina trihydrate (ATH) and magnesium hydroxide (MDH) were used as inorganic flame retardants. The mechanical properties after thermal oxidation aging and the flame-retardant properties of the EPDM compounds were measured using a moving die rheometer, a universal testing machine, a compression set, and a UL 94 V flammability test. We focused on how the properties were affected by the type and amount of flame retardants. The results demonstrated that the optimal mechanical and flame-retardant V-0 grade properties were obtained at an ATH content of 200 phr.

Fabrication of Duplex Ceramic Composites by Organic-Inorganic Solution Process

  • Lee, Sang-Jin;Kim, Youn-Cheol
    • Journal of the Korean Ceramic Society
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    • v.40 no.9
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    • pp.837-841
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    • 2003
  • Duplex microstructure of zirconia and alumina has been achieved via an organic-inorganic solution technique. Zirconium 2,4-pentanedionate, aluminum nitrate and polyethylene glycol were dissolved in ethyl alcohol without any precipitation. The organicinorganic precursor gels were turned to porous powders having volume expansion through explosive, exothermic reaction during drying process. The volume expansion was caused by abrupt decomposition of the organic groups in the gels during the vigorous exothermic reaction. The volume expanded, porous powders were crystallized and densified at 1500$^{\circ}C$ for 1 h. At the optimum amount of the PEG polymer, the metal cations were well dispersed in the solution and a homogeneous polymeric network was formed. The polymer content also affected on the specific surface area of the synthesized powder and the grain size of the sintered composite.

Study on the Improvement of Light Transmittance of Polyester Film (폴리에스터 필름의 광투과도 향상에 대한 연구)

  • Kim, Si-Min;Park, Soo-Young
    • Polymer(Korea)
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    • v.36 no.5
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    • pp.662-667
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    • 2012
  • Poly(ethylene terephthalate) (PET) base films with high light transmittance have been used for the substrate of various functional films in the flat panel display. The effects of the reflective index of coated films, the roughness of the film surface and the content of inorganic silica particles on the light transmittance were studied in this article. Light transmittance was increased by coating a water soluble resin with a low reflective index at an optimum thickness. The roughness of the film did not affect light transmittance when the Ra of the film surface was less than a quarter of the wavelength of incident light. Inorganic silica particles decreased light transmittance due to their absorbance and scattering of the incident light.

1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides

  • Mardani, Zahra;Golsanamlou, Vali;Jabbarzadeh, Zahra;Moeini, Keyvan;Carpenter-Warren, Cameron;Slawin, Alexandra M.Z.;Woollins, J. Derek
    • Journal of the Korean Chemical Society
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    • v.62 no.5
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    • pp.372-376
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    • 2018
  • A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

Flocculation Characteristics of Microalgae Through Combined Flocculants (응집제 혼합을 이용한 미세조류의 응집 특성)

  • Kwon, Do-Yeon;Jung, Chang-Kyou;Lee, Choul-Gyun;Lee, Jin-Won
    • KSBB Journal
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    • v.26 no.5
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    • pp.443-452
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    • 2011
  • In this study, inorganic flocculant with biodegradable polymer flocculant was usedfor microalgae harvest. The aim of this study was to optimize the concentration of inorganic flocculant, the concentration of biodegradable polymer flocculant and reaction volume for decreasing the amounts of flocculant and obtaining the suitable pH range for seawater by response surface methodology. The flocculation of three marine microalgae, Chlorella ellipsoidea, Dunaliella bardawil, and Dunaliella tertiolecta, using inorganic flocculants and biodegradable polymer flocculants was investigated. The results indicated that the optimal flocculant quantity showed 0.1 g/L of ferric chloride, 7.5 g/L of chitosan on Chlorella ellipsoidea. In the case of Dunaliella bardawil, the optimal flocculant quantity showed amount of ferric sulfate more than 0.12 g/L and chitosan more than 0.75 g/L. In the case of Dunaliella tertiolecta, the optimal flocculant quantity showed 1.0 g/L of sodium aluminate, 0.75 g/L of chitosan.

Preparation and Radionuclide Detection Analysis of Inorganic Fluor Impregnated Double-layered Membranes (이중구조 무기형광 함침막 제조 및 방사성핵종 탐지능력의 분석)

  • 이근우;서범경;박진호;남석태;한명진
    • Membrane Journal
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    • v.12 no.4
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    • pp.240-246
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    • 2002
  • New polysulfone scintillation proximity membranes were prepared by impregnating Cerium Activated Yttrium Silicate (CAYS), an inorganic fluor, in a membrane structure. The membranes were applied to detect the radionuclide contamination directly without the aid of a scintillation cocktail. The preparation of membranes was divided into two processes. A supporting polymer film was made of casting solutions consisting of polysulfone and solvent, their cast film being solidified by vacuum evaporation. CAYS-dispersed polymer solutions were cast over the first, solidified polymer films and coagulated either by evaporating solvent or by exchanging solvent in the solution with nonsolvent in a coagulation bath. The prepared membranes had two distinguished, but tight1y attached, double layers: one is the supporting layer of dense polymer film and the other the detecting layer consisting of CAYS and polymer. The radionuclide counting results revealed that the prepared membranes were efficient to monitor radioactivity contamination with reliable counting ability.

Organic-Inorganic Hybrid Materials Technology for Gas Barrier (가스 차단을 위한 유.무기 하이브리드 소재기술)

  • Kim, Ki-Seok;Pa가, Soo-Jin
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.112-117
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    • 2011
  • Recently, high growth potential of barrier materials industry including high performance packing materials was expected with increasing the national income and well-being culture. As high barrier materials, polymer nanocomposites have considerable attractions due to their excellent physical properties compared to conventional composite materials. In general, polymer nanocomposites were consisted of polymer matrix and inorganic fillers, such as layered silicate, carbon nanotubes, and metal- or inorganic nanoparticles. Among these materials, layered silicate which was called as the clay was usually used as nano-fillers because of naturally abundant and most economical and structural properties. Clay-reinforced polymer nanocomposites have various advantages, such as high strength, flammability, gas barrier property, abrasion resistance, and low shrinkage and used for automotive and packing materials. Therefore, in this paper, we focused on the need of gas barrier materials and materials-related technologies.

Improvement in Inorganic Affinity of Acrylic Materials for Conservation Treatment of Stone Cultural Assets (석조문화재를 위한 아크릴계 보존처리제의 무기친화성 개선)

  • Kim, Youn-Cheol;Kim, Un-Young;Kim, Hyung-Joong
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.14-19
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    • 2010
  • Applying acrylic silane monomer for determent of weathering damage of stone cultural assets from various sources was investigated to improve inorganic affinity of polymer impregnated to the stone for conservation treatment using impregnation of acrylic polymers under pressure. Radical polymerization was carried out with various mixture ratios of methacrylate (MMA), as the base monomer, and vinyl trimethoxy silane (VTMS). Subsequently, according to the changes of glass transition temperatures, average molecular weights, and storage moduli of the obtained copolymers, the case of adding 1 wt% of benzoyl peroxide, polymerization for 8 hrs, and mixing 5 mol% of VTMS to MMA was the optimum condition of monomer ratio and polymerization. Practically, fresh granites collected in domestic site and weathered stones were treated by following the obtained result above, and then, the moisture absorption, impact, acid resistance, and adhesion properties of the treated stones were compared to those of the corresponding stones treated with MMA only. It was found that those properties of the stones treated with PMV5 were considerably improved.