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http://dx.doi.org/10.5012/jkcs.2018.62.5.372

1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides  

Mardani, Zahra (Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
Golsanamlou, Vali (Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
Jabbarzadeh, Zahra (Inorganic Chemistry Department, Faculty of Chemistry, Urmia University)
Moeini, Keyvan (Chemistry Department, Payame Noor University,)
Carpenter-Warren, Cameron (EaStCHEM School of Chemistry, University of St Andrews)
Slawin, Alexandra M.Z. (EaStCHEM School of Chemistry, University of St Andrews)
Woollins, J. Derek (EaStCHEM School of Chemistry, University of St Andrews)
Publication Information
Journal of the Korean Chemical Society / v.62, no.5, 2018 , pp. 372-376 More about this Journal
Abstract
A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.
Keywords
Copper complex; Coordination polymer; Picolinate; Oxazolidine; X-Ray crystal structure;
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