• 한국재료학회:학술대회논문집
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• 한국재료학회 2012년도 춘계학술발표대회
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• pp.64.1-64.1
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• 2012

Next generation displays such as high performance LCD, AMOLED, flexible display and transparent display require specific TFT back-planes. For high performance TFT back-planes, low temperature poly silicon (LTPS), and metal-oxide semiconductors are studied. Flexible TFT backplanes require low temperature processible organic semiconductors. Not only development of active semiconducting materials but also design and synthesis of semiconductor corresponding gate dielectric materials are important issues in those display back-planes. In this study, we investigate the high heat resistant polymeric gate dielectric materials for organic TFT and inorganic TFT with good insulating properties and processing chemical resistance. We also controlled and optimized surface energy and morphology of gate dielectric layers for direct printing process with solution processible organic and inorganic semiconductors.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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• pp.1145-1148
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• 2008

The present status and trend of oxide phosphor thin-film development for thin-film electroluminescent (TFEL) device application are presented in this paper. Recently, several newly developed types of bendable or bendable see-through oxide TFEL lamps have been fabricated using the TFEL technology with a newly developed bendable ceramic sheet, glass sheet or sapphire sheet substrate, which has become available on the market. Stable operation at high temperatures was obtained in double-insulating-layer-type TFEL lamps fabricated with a $Zn_2Si_{0.6}Ge_{0.}4O_4$:Mn thin-film emitting layer forming on translucent or transparent bendable sheet substrates.

• 분석과학
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• 제28권3호
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• pp.204-211
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• 2015

란탄족 착물은 독특한 발광 특성으로 인하여 많은 연구가 되고 있는 물질이다. 유로피움(III) β-디케토네이트 착물에 아민계열 또는 포스핀옥사이드계열 리간드를 추가로 배위 결합시켜 발광 효율을 비교하였으며, 아민계열 배위보다는 발광 효율 증진에는 포스핀옥사이드 계열이 더 좋은 추가 리간드임을 확인하였다. 그 중에서도 트리옥틸포스핀 옥사이드를 배위시켰을 때 가장 높은 발광효율이 관찰되었다. 추가로 배위될 수 있는 트리옥틸포스핀 옥사이드의 당량을 확인하기 위해서 ³¹P-NMR과 photoluminescence를 분석하였다. 유로피움(III) β-디케토네이트 화합물은 리간드의 입체장애에 따라 트리옥틸포스핀 옥사이드의 배위 당량은 1 개 또는 2 개가 가능함을 확인하였다.

• Carbon letters
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• 제25권
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• pp.14-24
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• 2018

Electrochemical properties and performance of composites performed by incorporating metal oxide or metal hydroxide on carbon materials based on graphene and carbon nanotube (CNT) were analyzed. From the surface analysis by field emission scanning electron microscopy and field emission transmission electron microscopy, it was confirmed that graphene, CNT and metal materials are well dispersed in the ternary composites. In addition, structural and elemental analyses of the composite were conducted. The electrochemical characteristics of the ternary composites were analyzed by cyclic voltammetry, galvanostatic charge-discharge tests, and electrochemical impedance spectroscopy in 6 M KOH, or $1M\;Na_2SO_4$ electrolyte solution. The highest specific capacitance was $1622F\;g^{-1}$ obtained for NiCo-containing graphene with NiCo ratio of 2 to 1 (GNiCo 2:1) and the GNS/single-walled carbon $nanotubes/Ni(OH)_2$ (20 wt%) composite had the maximum specific capacitance of $1149F\;g^{-1}$. The specific capacitance and rate-capability of the $CNT/MnO_2/reduced$ graphene oxide (RGO) composites were improved as compared to the $MnO_2/RGO$ composites without CNTs. The $MnO_2/RGO$ composite containing 20 wt% CNT with reference to RGO exhibited the best specific capacitance of $208.9F\;g^{-1}$ at a current density of $0.5A\;g^{-1}$ and 77.2% capacitance retention at a current density of $10A\;g^{-1}$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2012년도 제43회 하계 정기 학술대회 초록집
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• pp.374-374
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• 2012

Nowadays, Active Matrix Organic Light-Emitting Diodes (AM-OLEDs) are the superior display device due to their vivid full color, perfect video capability, light weight, low driving power, and potential flexibility. One of the advantages of AM-OLED over Liquid Crystal Display (LCD) lies in its flexibility. The potential flexibility of AM-OLED is not fully explored due to its sensitivity to moisture and oxygen which are readily present in atmosphere, and there are no flexible encapsulation layers available to protect these. Therefore, we come up with a new concept of Inorganic-Organic hybrid thin film as the encapsulation layer. Our Inorganic layer is Al2O3 and Organic layer is F-Alucone. We deposited these layers in vacuum state using Atomic Layer Deposition (ALD) and Molecular Layer Deposition (MLD) techniques. We found the results are comparable to commercial requirement of 10-6 g/m2 day for Water Vapor Transmission Rate (WVTR). Using ALD and MLD, we can control the exact thin film thickness and fabricate more dense films than chemical or physical vapor deposition methods. Moreover, this hybrid encapsulation layer potentially has both the flexibility of organic layers and superior protection properties of inorganic layer.

• 한국수소및신에너지학회논문집
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• 제33권1호
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• pp.28-37
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• 2022

In this study, we synthesized a poly(pheneylene oxide) (PPO)-based organic/inorganic composite membrane having silicotungstic acid (STA) for the development of an anion exchange membrane with excellent ionic conductivity and physicochemical stability. The organic/inorganic composite membranes were prepared by introducing different STA contents (0 wt%, 10 wt%, 30 wt%, and 50 wt%) into the quaternizaed(Q)-PPO matrix. The prepared anion exchange membranes were subjected to structural analysis by proton neclear magnetic resonance and Fourier transform infrared, and thermal behavior of membranes was confirmed by thermogravimetric analysis. Among the prepared composite membranes, the ion conductivity of Q-PPO/STA-50 (40.5 mS cm^-1) showed 1.46 times compared to that of the pristine membrane (27.6 mS cm^-1). Therefore, these results demonstrated that organic/inorganic composite membranes are promising candidates for application of anion exchange membranes.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2003년도 춘계총회 및 연구발표회 초록집
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• pp.53.2-53
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• 2003

• Membrane and Water Treatment
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• 제9권6호
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• pp.481-487
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• 2018

Membrane clogging or fouling of the membrane caused by organic, inorganic, and biological on the surface is one of the main obstacles to achieve high flux over a long period of the membrane filtration process. So researchers have been many attempts to reduce membrane fouling and found that there is a close relationship between membrane surface hydrophilicity and membrane fouling, such that the same conditions, a greater hydrophilicity were less prone to fouling. Nanotechnology in the past decade is provided numerous opportunities to examine the effects of metal nanoparticles on the both hydrophilic and antibacterial properties of the membrane. In the present study the improvement of hydrophilic and antimicrobial properties of the membrane was evaluated by adding nanoparticles of titanium dioxide and copper oxide. For this purpose, 4% copper oxide and titanium dioxide nanoparticles with a ratio of 0, 30, 50, and 70% of copper oxide added to the polymeric membrane and compare to the pure polymeric membrane. Comparison experiments were performed on E. coli PTCC1998 in two ways disc and tube and also to evaluate membrane hydrophilic by measuring the contact angle and diameter of pores and analysis point SEM has been made. The results show that the membrane-containing nanoparticle has antibacterial properties and its impact by increasing the percentage of copper oxide nanoparticles increases.

• 분석과학
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• 제7권2호
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• pp.155-164
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• 1994

전형적인 Grimm형 방전관을 제작하고 고주파 방전에 의한 금속 및 세라믹시료 분석에 적용하였다. 금속 알루미늄과 알루미나에 대해 방출 스펙트럼을 관찰하였고 방전에 미치는 고주파의 전력과 알곤 기체의 압력에 대한 영향을 관찰하였으며, 시료와 접촉된 전극에 나타나는 DC-bias voltage를 확인하였다. 또한 SEM 사진을 관찰함으로써 rf-sputtering에 의한 알루미나 표면의 미세구조를 확인하였다. 저합금강(BAS 404-405) 중의 망간성분과 황동시료(NIST 1108-1117) 중의 아연성분에 대해 검량곡선을 작성한 결과 양호한 직선성을 보여 주었다.

• Bulletin of the Korean Chemical Society
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• 제25권8호
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• pp.1182-1188
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• 2004

Polydisperse oligo(PO-b-EO) allyl ether siloxane surfactants were synthesized by the hydrosilylation reaction of OMTS with Allyl-oligo(PO-b-EO) series. The surface tension of siloxane surfactants increased with increasing the EO chain length while it decreased with increasing the PO ratio. However, the sedimentation time of the aqueous solution showed opposite trend to the surface tension data. Both the surface tension and sedimentation time of the aqueous solution containing inorganic electrolyte gradually decreased as the content of inorganic electrolyte increased because of the surface arrangement of surfactant molecules. However, they increased with an increase of pH values due to the hydrolysis of the siloxane backbone. The $C_p$ values tended to increase with the increase in the EO chain length and decrease of the PO ratio. It seems that intermolecular interaction between PO/EO block copolymer and water affects the variation of transition temperature.