• 한국응용과학기술학회지
• /
• 제27권2호
• /
• pp.183-187
• /
• 2010

Core-Shell polymers of silicone dioxide-styrene system were prepared by sequential emulsion polymerization. In inorganic/organic Core-Shell composite particle polymerization, silicone dioxide adsorbed by surfactant sodium dioctyl sulfosuccinate (EU-DO133L) was prepared initially and then core silicone dioxide was encapsulated emulsion by sequential emulsion polymerization using styrene at the addition of potassium persulfate (KPS) as an initiator. We found that $SiO_2$ core shell of $SiO_2$/styrene structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration sodium dioctyl sulfosuccinate (EU-DO133L) was 0.5~2.0g. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

• 한국화재소방학회논문지
• /
• 제31권6호
• /
• pp.74-82
• /
• 2017

유기단열재를 사용한 샌드위치패널(복합자재) 건축물 화재는 소화가 어려우며, 가연성 심재를 통한 빠른 화재 확산으로 화재 시 피해가 크다. 샌드위치패널은 양면이 불연재로 되어있고, 불연재 사이에 심재인 단열재로 이루어져 있다. 단열재는 유기단열재와 무기단열재가 사용되고 있으며, 유기단열재가 무기단열재에 비하여 약 80% 이상 사용되고 있다. 유기단열재는 무기단열재에 비하여 경제적인 장점이 있지만 화재에 취약하다는 단점을 가지고 있기 때문에 샌드위치패널 화재 시 일반화재에 비하여 피해가 크다. 가스유해성시험의 경우 복합자재의 심재 위험성을 측정하기 위해 패널에 지름 25 mm 크기 3개의 원형 천공을 하여 시험하지만 콘칼로리미터 시험은 샌드위치패널 형태 그대로 시험을 진행한다. 본 연구에서는 KS F ISO 5660-1 콘칼로리미터 시험에서 복합자재의 경우 불연재인 표면에 가열한 경우와 천공을 통한 심재 노출 시험 및 심재에 직접가열 시 발생하는 화재의 위험성을 측정하였다. 시험에 사용된 유기단열재는 일반 EPS와 난연 EPS를 사용하였으며, 시험체 구성은 샌드위치패널, 천공된 샌드위치 패널, 심재의 3가지 형태로 시험을 진행하였다. 본 연구의 목적은 콘칼로리미터 시험 시 복합자재 심재의 화재 위험성을 평가하는 방안을 제시하고자 하였다.

• 한국콘크리트학회:학술대회논문집
• /
• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
• /
• pp.261-266
• /
• 2003

This study is to investigate the heating value and noxious gases generation such as CO, NO and $SO_2$ known as dangerous gas for human from specimen made of cement and lightweight aggregate. The most quanity of CO gas is generated in EPS(Expanded Poly Styrene), core of commercial sandwich panel. Although specimens mainly composed of cement discharged the relatively less CO gas than organic core such as EPS, specimens which SBR was added discharged the very much amount of CO gas similar to EPS and especially, specimens including foaming agent, gas foaming agent or redipersible powder of VA/VeoVa showed the good properties in the generation of CO gas. From the standpoint of the generation of NO and $SO_2$ gas, both the core of commercial sandwich panel such as EPS, Glass wool and specimens made with polymer dispersion such as St/BA and SBR discharge the very much amount of NO and $SO_2$ gas in comparison of the other specimens. From this study, it was confirmed that organic materials such as core of commercial sandwich panel dischared much more noxious gas than specimens composed of cement and inorganic lightweight aggregate.

• 한국세라믹학회지
• /
• 제54권3호
• /
• pp.222-227
• /
• 2017

Flake-type micro hollow silica was synthesized by precipitation method using an $Mg(OH)_2$ inorganic template and sodium silicate and ammonium sulfate as the silica precursors. We investigated the effects of the silica precursor concentration on the shape, shell thickness, and surface of the hollow silica. When the concentration of the silica precursor was 0.5 M, the hollow silica had a smooth and translucent thin shell, but the shell was broken. On the other hand, the shell thickness of the hollow silica changed in the range of 12 nm to 18 nm with the increase of the precursor concentration from 0.7 M to 1.1 M. Simultaneously, unintended spherical silica satellites were created on the shell surface. The number of satellites and the size rose according to the increased concentration of silica precursor. The reason for the formation of spherical silica satellites is that the $NH_4OH$ nucleus generated in the synthesis of hollow silica acted as another silica reaction site.

• Journal of the korean society of oceanography
• /
• 제32권2호
• /
• pp.69-74
• /
• 1997

Depth profiles of organic carbon (C), biogenic silica (Si), and inorganic phosphorus (P) in Maxwell bay sediments were determined to investigate paleoclimatic changes during Holocene. Organic C and biogenic Si contents generally show a down-core decrease trend, which appears to be mostly controlled by their vertical fluxes through productivity in the surface waters, but it is uncertain that inorganic P contents are directly influenced by productivity changes with time. Before 4000 yr B.p. marine productivity seemed to be almost zero because ice permanently covered the surface waters of the study area. As the climate started to become relatively warm at 4000 yr B.p., ice was sporadically melted in the surface waters and thereby marine productivity gradually increased until 1500 yr B.p. For the last 1500 year, marine productivity must be high enough to overcome the dilution by high terrigenous sedimentation, thus that period was the warmest during the last 6000 year.

• 세라미스트
• /
• 제21권3호
• /
• pp.283-292
• /
• 2018

Here, we introduce various type of inorganic nanostructure synthesized with functional nanoparticles and silica. From two decades ago, functional inorganic nanoparticles have been synthesized and highlighted, now we moved to next level of wet-chemical synthesis. By integrating functional nanoparticles with silica, we were able to synthesize multi-functional nanostructure, which expand the applications of nanoparticles to catalyst, drug carrier, sensors. In this context, silica has been spotlighted due to its versatility. Silica has highly biocompatible, relatively transparent and stable under harsh conditions. Thus it can be used as good supporter to synthesize complex multi-functional nanostructure when mixed with other functional nanoparticles. A various shape of complex nanostructures have been synthesized including core-shell type, yolk-shell type and janus type etc. In this paper, we have described the purposes of synthesizing silica noncomplex and various case studies for biomedical applications and self-assembly.

• Bulletin of the Korean Chemical Society
• /
• 제11권2호
• /
• pp.118-123
• /
• 1990

X-ray photoelectron spectra have been obtained and comparisons have been made for 1-2-3 and 2-1-1 phases of YBaCuO compounds. The photoelectron binding energies of all the constituent elements are consistently larger for the 2-1-1 phase than for the 1-2-3 phase. The peak intensities reflect different stoichiometries of the two phases. For the superconducting 1-2-3 phase, its degradation in air and interaction with water and carbon dioxide were examined by taking core level spectra of all the elements. It appears that yttrium is the most affected by exposure to air, since it undergoes a rapid change to carbonate when water and subsequently carbon dioxide are introduced.

• Nuclear Engineering and Technology
• /
• 제55권6호
• /
• pp.2107-2111
• /
• 2023

The aim of the study is the activity concentration measurements of organic and inorganic ¹⁴C in the discharges of JSC "Institute of Nuclear Materials" (INM). In INM the research water-water reactor "IVV-2M" is operating. Collecting of ¹⁴C species was performed using a ¹⁴C sampler with a chromium oxide and platinum catalysts at different temperatures: 400, 550 and 700 ℃. The measurements of ¹⁴C activity were performed using a liquid scintillation counter. The share of organic ¹⁴C in emissions ranged from 0.30 to 0.84 and depends on the temperature of the catalyst, core structure and reactor operating mode.

• 한국분말재료학회지
• /
• 제26권6호
• /
• pp.463-470
• /
• 2019

Fe₃O₄/SiO₂/YVO₄:Eu³⁺ multifunctional nanoparticles are successfully synthesized by facile stepwise sol-gel processes. The multifunctional nanoparticles show a spherical shape with narrow size distribution (approximately 40 nm) and the phosphor shells are well crystallized. The Eu³⁺ shows strong photoluminescence (red emission at 619 nm, absorbance at 290 nm) due to an effective energy transfer from the vanadate group to Eu. Core-shell structured multifunctional nanoparticles have superparamagnetic properties at 300 K. Furthermore, the core-shell nanoparticles have a quick response time for the external magnetic field. These results suggest that the photoluminescence and magnetic properties could be easily tuned by either varying the number of coating processes or changing the phosphor elements. The nanoparticles may have potential applications for appropriate fields such as laser systems, optical amplifiers, security systems, and drug delivery materials.

• Journal of Magnetics
• /
• 제16권3호
• /
• pp.318-321
• /
• 2011

A new Fe-based amorphous compound powder was prepared from Fe-Si-B amorphous powder by crushing amorphous ribbons as the first magnetic component and Fe-Cr-Mo metallic glassy powder by water atomization as the second magnetic component. Subsequently by adding organic and inorganic binders to the compound powder and cold pressing, the new Fe-based amorphous compound powder cores were fabricated. This new Fe-based amorphous compound powder cores combine the superior DC-Bias properties and the excellent core loss. The core loss of 500 kW/$m^3$ at $B_m$ = 0.1T and f = 100 kHz was obtained When the mass ratio of FeSiB/FeCrMo equals 3:2, and meanwhile the DC-bias properties of the new Fe-based amorphous compound powder cores just decreased by 10% compared with that of the FeSiB powder cores. In addition, with the increasing of the content of the FeCrMo metallic glassy powder, the core loss tends to decrease.