DOI QR코드

DOI QR Code

Synthesis on the Core-Shell Polymer of Silicone Dioxide/Styrene Using Sodium Dioctyl Sulfosuccinate (EU-DO133L) as a Surfactant

계면활성제 Sodium Dioctyl Sulfosuccinate (EU-DO133L)을 사용한 이산화규소/스티렌의 코어-셀 고분자의 합성

  • Kim, Duck-Sool (Dept. of Biomedical Engineering, Tongmyong University) ;
  • Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
  • 김덕술 (동명대학교 의용공학과) ;
  • 박근호 (창원대학교 화공시스템공학과)
  • Received : 2010.04.19
  • Accepted : 2010.06.22
  • Published : 2010.06.30

Abstract

Core-Shell polymers of silicone dioxide-styrene system were prepared by sequential emulsion polymerization. In inorganic/organic Core-Shell composite particle polymerization, silicone dioxide adsorbed by surfactant sodium dioctyl sulfosuccinate (EU-DO133L) was prepared initially and then core silicone dioxide was encapsulated emulsion by sequential emulsion polymerization using styrene at the addition of potassium persulfate (KPS) as an initiator. We found that $SiO_2$ core shell of $SiO_2$/styrene structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration sodium dioctyl sulfosuccinate (EU-DO133L) was 0.5~2.0g. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

Keywords

References

  1. H. J. Liu, L. H. Lin, and K. M. Chen, Preparation and Properties of Water- Soluble Polyester Surfactants, J. Applied Polymer Science, 88(5), 1236 (2003). https://doi.org/10.1002/app.11793
  2. W. G, Cho, K. Y. Kyung and S. M. Yu, Stability of Paeoniflorin used as Anti- Wrinkle Agents in Emulsions, J. Kor. Oil Chem. Soc., 26(2), 191 (2009).
  3. K. H. Lim, Biosurfactants: Their Structures, Properties, and Applications, J. Kor. Oil Chem. Soc., 13(2), 1 (1996).
  4. L. E. Nielsen, Mechnical Properties of Polymersand Conposite, Marcel Dekker Inc., (1974).
  5. K. G. Lee and K. H. Park, Preparation and Physical Properties of Poly(Styrene/ Acrylate) Core-Shell Latex Particles, J. Kor. Oil Chem. Soc., 20(2), 27 (2003).
  6. J. B. Kwon, N. W. Lee, and S. D. Seul, A Consideration on Thermal Stability of the PVAc Latex Adhesive, J. Kor. Soc. of Safety, 18(3), 81 (2003).
  7. S. D. Seul, S. R. Lee, and N. W. Lee, A Development of Nontoxic Composite Latex Using $CaCO_3$/ PEMA, J. Kor. Soc. of Safety, 17(4), 133 (2002).
  8. J. F. Scamehorn, Phenomena in Mixed Surfactant Systems, ACS Symposium Series 311, American Chemical Society, Washington, DC (1986).
  9. P. M. Holland, and D. M. Rubingh, Mixed Surfactant Systems, ACS Symposium Series 501, American Chemical Society, Washington, DC (1992).
  10. A. Khan, and E. Marques, Catanionic Surfactants, In Specialist Surfactants, Robb, I.D.(Ed.), Blackies Academic and Professional, London, 37-80 (1997).
  11. S. P. Christiano, and K. C. Fey, Silicone Antifoam Performance Enhancement by Nonionic Surfactants in Potato Medium, J. Industrial Microbiology & Biotechnology, 30(1), 13 (2003). https://doi.org/10.1007/s10295-002-0003-3
  12. M. Hasegawa, K. Arai, and S. Saito, Effect of Surfactant Adsorbed on Encapsulation of Fine Inorganic Power with Soapless Emulsion Polymerization, J. polym. sci. Part A, Polym. chem., 25(12), 3231-3239, (1987). https://doi.org/10.1002/pola.1987.080251205
  13. M. Hasegawa, K. Arai, and S. Saito, Selective Adsorption of Polymer on Freshly Ground Solid Surfaces in Soapless Emulsion Polymerization, J. Applied Polym. sci., 33(2), 411-418, (1987). https://doi.org/10.1002/app.1987.070330212