• Title/Summary/Keyword: Inorganic $As(As^{3+}$, $As^{5+})$

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Combustion and Mechanical Properties of Fire Retardant Treated Waste Paper-Waste Acrylic Raw Fiber Composite Board

  • Eom, Young Geun;Yang, Han-Seung;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.3
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    • pp.1-10
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    • 2003
  • Shredded waste newspapers, waste acrylic raw fibers, and urea-formaldehyde (UF) adhesives, at 10% by weight on raw material, were used to produce recycled waste paper-waste acrylic raw fiber composite boards in laboratory scale experiments. The physical and mechanical properties of fire retardant treated recycled waste paper-waste acrylic raw fiber composite boards were examined to investigate the possibility of using the composites as internal finishing materials with specific gravities of 0.8 and 1.0, containing 5, 10, 20, and 30(wt.%) of waste acrylic raw fiber and 10, 15, 20, and 25(wt.%) of fire retardant (inorganic chemical, FR-7®) using the fabricating method used by commercial fiberboard manufacturers. The bending modulus of rupture increased as board density increased, decreased as waste acrylic raw fiber content increased, and also decreased as the fire retardant content increased. Mechanical properties were a little inferior to medium density fiberboard (MDF) or hardboard (HB), but significantly superior to gypsum board (GB) and insulation board (IB). The incombustibility of the fire retardant treated composite board increased on increasing the fire retardant content. The study shows that there is a possibility that composites made of recycled waste paper and waste acrylic raw fiber can be use as fire retardant internal finishing materials.

Recycling of Plant Fiber Resources: Enhanced Hydration of Newspaper Stock for Decrease of Deinking Reject (식물유래 섬유자원의 재활용: 탈묵 수율 개선을 위한 신문 지료의 수화 촉진 방안)

  • Chung, Sung-Hyun;Kim, Joong-Ho;Joo, Jong-Hun;Bang, Jae-Wook
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.10a
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    • pp.39-41
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    • 2011
  • The recycling rate of recovered paper in Korea is the highest in the world, 92%, but remanufacturing yield is low due to the extremely poor quality of the paper. The poor quality, in turn, influences to the reject amount in deinking process. To increase the yield of old newspaper recycling process, hydrophobic degree of inorganic pigments of deinking stock must be reduced. To determine the hydrophobicity, Pitch Potential Deposit Tester (PDT) was newly designed and applied with respect to the SB latex property of various quality used in Korea; its hydrophobic degree according to Tg, gel content, charge and particle size of latex and optimum designing condition of SB latex. And below are the conclusions: 1. The reason of excessive reject from old newspaper deinking process for total amount of printed ink is loss of inorganic pigments. When lipase, a biochemical catalyst, was applied with the purpose of preventing inorganic pigments loss about more than 70% of total reject weight and promoting hydration of pulp for deinking, deinking process yield of pre flotation secondary stage increased remarkably without any changes of deinking efficiency. 2. Lipase improved deinking stock by cutting ester linkage on surface of hydrophobic materials to promote its hydration. From this, it reached the conclusion that hydration degree of stock exercises significant effect on flotation deinking process yield. 3. Inorganic alkali promotes hydration of deinking stock. But there have been needs for more fundamental measures other than inorganic alkali of promoting hydration for yield improvement. For this, this study intended to find out reasons of chemical properties change on surface of hydrophobic material by change of pH. 4. Pitch Deposit Test (PDT) was performed for understanding principle of why surface of coating flake from OMG is hydrophobic and why it becomes hydrophilic when pH of stock is alkaline. As a result of this test, it is determined that swelling property by change of pH of latex film, which were used as coating adhesive is the reason for hydrophobic change. 5. Hydrophilicity of coating flake increased with hydrophilic pigments. And as more of SB Latex adhesive was used and higher of calcium hardness of stock became, its hydrophilicity decreased. SB Latex adhesive film is reformed by mechanical friction. For having hydrophilicity under neutral pH, strong bruising action such as kneading is required. 6. Because swelling of adhesive film decreases as Tg of SB latex gets lower and mean diameter gets smaller, it shows hydrophobicity under neutral pH. This lowers hydrophilicity of coating flake, which leads to easy elimination with flotation reject on DIP process. Therefore, for improving future flotation yield, it is necessary to develop to use eco-friendly clean SB latex by raising Tg and increasing mean diameter for recycling, and as a result, to reduce excessive loss of coating flake as a reject from deinking process.

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Study of Catalytic Ceramic Fiber Filter Elements for Hot Gas Filtration

  • Young Jin Choi;Min Jin Park;Jun Suk Hong;Min Sun Hong;Jae Chun Lee
    • The Korean Journal of Ceramics
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    • v.5 no.3
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    • pp.284-287
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    • 1999
  • CuO catalyst-coated alumino-silicate fiber filters were prepared for the simultaneous removal of particulate matter and gaseous contaminants such as NOx and SOx. Hot gas cleaning experiments similar to Shell UOP process other than the catalyst supporting materials were carried out between 300 and $500^{\circ}C$ for the evaluation of the gas removal efficiency of the catalytic filter. Experimental results showed that removel efficiency for $SO_2$ was greater than 99% in the temperature range 450~$500^{\circ}C$ and more than 90% of NO was collected between 350 and $370^{\circ}C$. It was found that the higher the CuO content, the higher the removal efficiency for $SO_2$. Removal efficiency for NO was more affected by the gas cleaning temperature than by the CuO content in the catalyst-filter.

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The Effect of Boron Doped CdS Film on CdS/CdTe Solar Cell (CdS 박막의 boron doping에 따른 CdS/CdTe 태양전지 특성)

  • Lee, H.Y.;Lee, J.H.;Kim, J.H.;Park, Y.K.;Shin, J.H.;Shin, S.H.;Park, K.J.
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1370-1372
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    • 1998
  • Boron doped CdS films were prepared by CBD(Chemical Bath Deposition) method using boric acid ($B_3HO_3$) as donor dopant source, and their properties were investigated. As-grown CdS films were highly adherent and specularly reflective. Boron doped CdS film which was fabricated under the condition of 0.01 $B_3HO_3/Cd(Ac)_2$ mole ratio, exhibited the lowest resistivity of $2{\Omega}cm$ and the highest optical bandgap of 2.41eV. Also, CdS/CdTe solar cells were fabricated with various doping concentration of CdS films. Using optimized CdS film as the window layer of CdS/CdTe solar cell, the characteristics of the cell were improved. ( $V_{oc}$=610mV, $J_{sc}$=37.5mA/cm, FF=0.4, $\eta$=9.1% )

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Adsorption Characteristics of Strong Basic Anion Exchanger to Cellulose Reactive Dye (강 염기성 음이온 교환수지의 셀룰로우스 섬유용 반응성 염료에 대한 흡착 특성)

  • Lim, Gyeong-Eun;Chung, Paul-gene;Kwon, Ji-Young
    • Journal of Korean Society on Water Environment
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    • v.23 no.1
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    • pp.27-32
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    • 2007
  • This study focused on estimating the feasibility of a strong basic anion exchanger (PA312OH) as a sorbent for the removal of residual reactive dye and saving chemicals and water. Cellulose reactive dye C.I.RB49 was tested because reactive dye is the largest single group of dyes and that dye needs larger amount of inorganic salts as dyeing agent but nearly 50% of reactive dyes may be lost to the effluent. The adsorption characteristics of PA312OH for C.I.RB49 were as follows. Ion-selectivity among the dye and inorganic salts was Dye > ${SO_4}^{2-}$ > ${CO_3}^{2-}$ > $Cl^-$. C.I.RB49 was exchanged more than 3 times ${SO_4}^{2-}$ and ${CO_3}^{2-}$ and $Cl^-$ was not exchanged absolutely. The exchanging velocity was increased exponentially with increasing temperature. This result is positive effect on treating the high temperature dyeing process wastewater. The exchanged dye percents to initial were 96.8% and 99% at flow rate 20.5 mL/min. and 3.7 mL/min.. The exchanging capacity of PA312OH for C.I.RB49 was 215.2 mg/g at conc.=369.2 mg/L, Temp.=$25^{\circ}C$. 74% inorganic salts were recrystallized from real dark reactive color dyeing wastewater treated with PA312OH.

Physical, Chemical and Optical Properties of Fine Aerosol as a Function of Relative Humidity at Gosan, Korea during ABC-EAREX 2005

  • Moon, Kwang-Joo;Han, Jin-Seok;Cho, Seog-Yeon
    • Asian Journal of Atmospheric Environment
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    • v.7 no.3
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    • pp.129-138
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    • 2013
  • The water uptake by fine aerosol in the atmosphere has been investigated at Gosan, Korea during ABC-EAREX 2005. The concentration of inorganic ion and carbon components, size distribution, and light scattering coefficients in normal and dry conditions were simultaneously measured for $PM_{2.5}$ by using a parallel integrated monitoring system. The result of this study shows that ambient fine particles collected at Gosan were dominated by water-soluble ionic species (35%) and carbonaceous materials (18%). In addition, it shows the large growth of aerosol in the droplet mode when RH is higher than 70%. Size distribution of the particulate surface area in a wider size range ($0.07-17{\mu}m$) shows that the elevation of RH make ambient aerosol grow to be the droplet mode one around $0.6{\mu}m$ or the coarse mode one, larger than $2.5{\mu}m$. Hygroscopic factor data calculated from the ratio of aerosol scattering coefficients at a given ambient RH and a reference RH (25%) show that water uptake began at the intermediate RH range, from 40% to 60%, with the average hygroscopic factor of 1.10 for 40% RH, 1.11 for 50% RH, and 1.17 for 60% RH, respectively. Finally, average chemical composition and the corresponding growth curves were analyzed in order to investigate the relationship between carbonaceous material fraction and hygroscopicity. As a result, the aerosol growth curve shows that inorganic salts such as sulphate and nitrate as well as carbonaceous materials including OC largely contribute to the aerosol water uptake.

Skin safety of the UV Absorbers by Measurement Cytotoxicity High Functional Product with Water-in-Silicone System

  • In-Young Kim;Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.134-146
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    • 1997
  • Consumers have recently preferred to purchase extensive UV intercepting products, which are waterproof and free from side effects on skin. Testing Cytoroxicity in SR method, cell survivial ratio of UV-B interceptors decreased above 0.08W/V%, and so did that of UV-A interceptors above 0.06W/V%. Also, Patch-test of inorganic UV interceptors resulted in no skin irritation even below 10.0 and 11.25. UV interceptors in the sunlight showed yellowish discoloration in 5 to 14 days. In absorption curves, UV-B was most suitable for Octyl methoxycinnamate and UV-A for Butyl methoxy dibenzoylmethane. Fro this reason, Nylonpoly UVA/UVB the material of OMC and BMDM coated with Nylon & polyethylene, was used as the organic UV interceptor. And zinc oxide and titanium dioxide was used as inorganic UV ibterceptors. The appropriate mixture ratio of ZnO and TiO2 was 6 to 4.6% of ZnO, 4% of TiO2 and 5% of Nylonpoly UVA/UVB were all combined with our sunscreen cream. The SPF value of in-vivo applied to a guinea pig was 34.9 and that of in-vivo was 38.5. Cyclomerhicone and dimerthicone were used in water-in-Silicone system. Ceryl diverhicone and sorbitan sesquioleate were used as emulsifiers and MgSO4, 7H2O, Mg-stearate/Mg-Al-stearate copolymer as emulsification stabilizers. In practical application, each SPF duration of O/W type and W/S type containing sunscreen cream of the same content showed that W/S type of sunscreen cream was 5 times as durable as the other. This product is fit for using in swimming, climbing or skiing. This research is to minimize skin trouble used by UV interceptors and to make one with proper softness, skin safety and UV intercepting efficiency.

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A Study of Synthesis and Property of $CaCO_3$/Organic Core-Shell Particle (탄산칼슘 /유기계 Core-Shell 입자의 제조와 물성에 관한 연구)

  • Seul, Soo-Duk
    • Polymer(Korea)
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    • v.34 no.1
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    • pp.38-44
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    • 2010
  • Core-shell particles of inorganic/organic pair were synthesized from $CaCO_3$ absorbed sodium dodecyl benzene sulfonate(SDBS) surfactant. Shell components were synthesized by sequential emulsion polymerization. Various monomers were used as shell components such as methyl methacrylate(MMA), ethyl acrylate(EA), butyl acrylate(BA), and styrene(St). Ammonium persulfate(APS) was used as an initiator and 2-ethylhexyl acylate(2-EHA) was used as a functional monomer, In the $CaCO_3$/organic core-shell particle polymerization, $CaCO_3$ absorbed surfactant SDBS of 0.5 wt% was prepared first and then core $CaCO_3$ was encapsulated by emulsion polymerization. 0.1 wt% of APS was added sequentially to minimize the formation of new monomer particle during shell polymerization. The structure of inorganic/organic core-shell particles were characterized by measuring the decomposition degree of $CaCO_3$ using HCl solution, thermogravimetric analyzer, scanning electron microscope, and transmission electron microscope.

Effect of Inorganic Constituents Existing in Empty Fruit Bunch (EFB) on Features of Pyrolysis Products (팜 부산물에 존재하는 무기성분이 급속열분해 생성물의 특성에 미치는 영향)

  • Moon, Jaegwan;Lee, Jae Hoon;Hwang, Hyewon;Choi, In-Gyu;Choi, Joon Weon
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.5
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    • pp.629-638
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    • 2016
  • In this study, the effect of inorganic constituents on the physicochemical properties of pyrolytic products produced from empty fruit bunch (EFB) by fast pyrolysis were investigated. Inorganic constituents were removed from the EFB by means of washing treatment with hydrofluoric acid (HF) and distilled water (D.I water). Ash content decreased from 6.2 wt% (EFB) to 2.4 wt% (HF-EFB) and 3.5 wt% (D.I-EFB), respectively. As a result of the inorganic component, a quantity of potassium in EFB has showed the highest removal efficiency in both HF and D.I water (HF: 80.3%, D.I water: 72.8%). Fast pyrolysis was performed with demineralized EFB in the fluidized bed reactor under the temperature of $500^{\circ}C$ at the residence time of 1.3 sec. The yield of bio-oil was determined to 57.3 wt% for HF-EFB and 52.1 wt% for D.I-EFB, respectively. Biochar yield decreased whereas yield of non-condensable gas increased with decreasing inorganic content of EFB. Water content decreased from 26.9% (EFB) to 9.9% (HF-EFB) and viscosity increased from 16.1 cSt (EFB) to 334 cSt (HF-EFB).

Annealing effects of organic inorganic hybrid silica material with C-H hydrogen bonds (C-H 수소결합을 갖는 유무기 하이브리드 물질에서의 열처리 효과)

  • Oh, Teresa
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.44 no.11
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    • pp.20-25
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    • 2007
  • In this paper, It was reported the dielectric constant in organic inorganic hybrid silica material such as SiOC film modeling of bond structure by annealing in organic properties. The organic inorganic hybrid silica material were deposited using bis-trimethylsilymethane (BTMSM, [(CH3)3Si]2CH2) and oxygen gas precursor by a plasma chemical vapor deposition (CVD). The organic inorganic hybrid silica material have three types according to the deposition condition. The dielectric constant of the films were performed MIS(Al/Si-O-C film/p-Si) structure. The C 1s spectra in organin inorganic silica materials with the flow rate ratio of O2/BTMSM=1.5 was organometallic carbon with the peak 282.9 eV by XPS. It means that organometallic carbon component is the cross-link bonding structure with good stability. The dielectric constant was the lowest at annealed films with cross-link bonding structure.