• Title/Summary/Keyword: In situ measurements

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Stability and Electrochemical Characteristics of Polyaniline Salt Films in 1 N HCl Solution

  • 조정환;오응주;요철현
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.715-719
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    • 1996
  • Thin films of polyaniline (PANI) salts were in situ deposited on a Pt plate during either chemical polymerization or electrochemical polymerization. The oxidation states of the salt films were controlled by the applied DC potential. AC impedance of the Pt/PANI electrode were measured in monomer-free 1 N HCl solution in order to investigate the electrodic properties of the films at the following applied DC potentials: 0, 0.45 and 0.75 V vs. SCE. Very small differences in film conductivity according to its oxidation state were observed by analysis of the impedance spectra, the reasons of which are complicated by enriched water content in the film and possible decrease in the film thickness during the measurements. The electrochemical activity of the film/solution interface varied with its oxidation state. Stability of the film in 1 N HCl solution was also evaluated by impedance and cyclic voltammetry measurements.

Orthogonality Measurement of Square Plane Mirrors for Laser Interferometry (레이저 간섭계의 직각 평면거울에 대한 직각도 오차 측정)

  • 김태호;김승우
    • Journal of the Korean Society for Precision Engineering
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    • v.15 no.12
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    • pp.169-179
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    • 1998
  • Plane mirror type laser interferometers are popularly being used in many modern ultraprecision machines, as they can perform simultaneous measurements of multiple axis positions with nanometer resolution capabilities. One important issue in this application of laser interferometers is to provide a good level of alignment between the reflecting mirrors and the laser beams so that measurement errors due to undesirable coupling effects can be avoided in multiple axis measurements In this investigation, a thorough metrological analysis is given to develop an suitable mathematical model for a precision x-y stage in which the orthogonality misalignment between the reflecting mirrors significantly affects overall x-y mea-surement results. Then a noble calibration method is suggested in which two-dimensional displacement sensors of moire gratings of concentric circles are used to realize the reversal principle of orthogonality evaluation in situ. Finally, actual experimental results are discussed to verify that the suggested method can effectively calibrate the orthogonality error with an uncertainty of 0.2667 arcsec.

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다중분광 자료를 이용한 영상기반의 대기보정 연구

  • Lee, Kwang-Jae;Kim, Yong-Seung
    • Aerospace Engineering and Technology
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    • v.4 no.1
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    • pp.211-220
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    • 2005
  • The purpose of this study is to examine the image-based atmospheric correction models using the data from Landsat Enhanced Thermal Mapper Plus (ETM+) that have quite similar spectral characteristics to the forthcoming KOrea Multi-Purpose SATellite (KOMPSAT)-2 Multi-Spectral Camera (MSC), and the in-situ measured surface reflectance data during satellite overflight. The main advantage of this type of correction is that it does not require in-situ measurements during each satellite overflight. While substantial differences are present between Top-Of-the Atmosphere (TOA) reflectance and in-situmeasurements, the results showed that Case 1 based on COST model gives most accurate results among three cases. The accuracy of Case 2_1 is very close to Case 1 and its values are smaller than in-situ data. No notable features appear between some bands in the Case 3_1 and in-situ data. It is expected from this study that if the current methods are applied to the IKONOS high resolution data, we will be able to develop the suitable atmospheric correction methods for MSC data.

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A Study on the Structural and Electrochemical Properties of Li0.99Ni0.46Mn1.56O4 Cathode Material Using Synchrotron based in-situ X-ray Diffraction

  • Choi, Sol;Yoon, JeongBae;Muhammad, Shoaib;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
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    • v.4 no.1
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    • pp.34-40
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    • 2013
  • The structural and electrochemical properties of $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ ($Fd{\bar{3}}m$, disordered spinel) cathode material were studied and compared with stoichiometric $LiNi_{0.5}Mn_{1.5}O_4$ ($P4_332$, ordered spinel). First cycle discharge capacity of $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ was similar to that of $LiNi_{0.5}Mn_{1.5}O_4$ at C/3 and 1C rate, but cycling performance of $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ was better than that of $LiNi_{0.5}Mn_{1.5}O_4$ especially at high rate of 1C. This can be explained by performing synchrotron based in-situ XRD and results of GITT measurements. It is considered that faster lithium ion diffusion in the $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ cathode results in the improvement of the rate capability. To study structural changes during cycling, synchrotron in-situ XRD patterns of both the samples were recorded at C/3 and 1C rate. Compared to stoichiometric $LiNi_{0.5}Mn_{1.5}O_4$, disordered $Li_{0.99}Ni_{0.46}Mn_{1.56}O_4$ spinel sample has pseudo one phase behavior and one step phase transition between two cubic phases. So, $LiNi_{0.5}Mn_{1.5}O_4$ would experience a much greater strain and stress, originating from the two phase transitions between three cubic phases and suffer from capacity loss during cycling especially at high rate.

Analysis Method of Passive Piles considering group effect (군말뚝효과를 고려한 수동말뚝의 해석기법)

  • 정상섬;원진오;김병철
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.03b
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    • pp.151-158
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    • 2000
  • The lateral deformation of one row pile groups was investigated based on analytical study and a numerical analysis. The emphasis was on quantifing the load transfer of pile groups subjected to lateral soil movement. An analytical method to consider pile-soil interaction in weathered soil was developed using load-transfer curve methods. Through the comparative study, it is found that the prediction by present approach is in good agreement with the general trend observed by in-situ measurements.

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Acoustic Noise Source Identification in the Automotive Industry (자동차의 음향잡음의 원인규명 방안)

  • Hall, Paul
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1996.10a
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    • pp.91-97
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    • 1996
  • We have all heard sounds that did not sound "right" while riding in an automobile. Objectionable sounds are difficult to find and understand because the sound field is complex and dynamic in the near field of an automobile. Many different noise sources and transmission paths must be understood before an engineering change can be recommended. This paper reviews the fundamental characterization of sound and chscusses the Sound Intensity measurement technique. Sound intensity measurements locate sources and sinks of acoustic energy. Used with narrowband analysis equipment, acoustic noise sources can be identified. Sound intensity measurements are made -in-situ and do not require specmi anechoic facilities. The measurement results in a vector representation of the near field sound field and can discriminate between multiple sound sources.d sources.

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The Effect of the Oxygen Scavenging System on the pH of Buffered Sample Solutions: in the Context of Single-molecule Fluorescence Measurements

  • Kim, Sung-Eun;Lee, Il-Buem;Hong, Seok-Cheol
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.958-962
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    • 2012
  • In single-molecule fluorescence experiment, the oxygen scavenging system is indispensable for avoiding photo-bleaching of fluorescent dyes. Here we report that the gloxy-based oxygen scavenging system commonly used in single molecule fluorescence experiments can disturb the solution pH considerably. To track in situ pH change, we utilized the pH-sensitive conformational transition of i-motif and examined the transition with ensemble and single-molecule FRET measurements. Based on our results, we also suggested several practical remedies for the stability of the solution pH.

Blast Design of Hilly Rock Excavation Adjacent to Structures and Facilities (구조물 및 시설물 인접 구릉지의 암반굴착 발파설계)

  • 류창하;선우춘;신희순;정소걸;최병희
    • Tunnel and Underground Space
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    • v.4 no.1
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    • pp.38-46
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    • 1994
  • This paper concerns the design of blasts adjacent to structures and facilities. In order to investigate the site characteristics, measurements of in-situ wave propagation and laboratory tests of rock cores taken from the boreholes were carried out. Effects of rock media and delay intervals on ground vibration levels were identified from over sixty measurements of three times of test blasts. For practical use in the field, an empirical propagation equation was derived so as to reflect the characteristics of rock media and delay effects. Safe limits of vibration level for structures were conservatively established based on various suggested criteria. Safe limits for facilities were adopted so that vibration levels induced by blasting should not exceed the allowable limits specified in the manufacturer's installation condition. Suggested were blast pattern and operation to enhance the rock fracturing and to reduce the ground vibration levels under the restricted conditions.

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Biaxial Tensile Behaviors of Elastomeric Polymer Networks

  • Shinzo, Kohjiya
    • Elastomers and Composites
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    • v.38 no.2
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    • pp.175-179
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    • 2003
  • For the total description of mechanical behaviors of elastomers, it is necessary to know the so-called rheological constitutive equation i.e. the strain-energy density function (W) in case of elastomers, which necessitates biaxial tensile results of elastic body. This paper first describes the experimental results of biaxial tensile measurements on poly(siloxane) model networks. W was estimated from its differential form i.e. the $1^{st}$ differential of W is stress. The W was found to reproduce the experimental stress-strain results, and the W estimated for silica filled poly(siloxane) networks suggest a different behavior between conventional precipitated silica and in situ formed silica. The difference suggests the different surface property of the two silicas.