• Title/Summary/Keyword: Ignition catalyst

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Development of Hydrogen Peroxide Thruster adopted Silver Catalyst (은을 촉매로 사용하는 과산화수소 추력기 개발)

  • Lee, Su-Lim;Lee, Choong-Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.4
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    • pp.67-73
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    • 2007
  • In recent years hydrogen peroxide has become considerably more attractive as a green rocket propellant so a laboratory model of hydrogen peroxide thruster adopted silver catalyst and a test facility has been developed to research a hydrogen peroxide propulsion. The design scheme of thruster and the test data are presented including ignition delay, efficiency of characteristic exhaust velocity. As a result, 95% of efficiency of characteristic exhaust velocity was obtained at steady state operation condition.

Combined Application of Burner and Oxidation Catalyst for Diesel Particulate Filter Regeneration (DPF 재생을 위한 버너-산화촉매 복합 적용)

  • Shim, Sung-Hoon;Jeong, Sang-Hyun
    • Journal of the Korean Society of Combustion
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    • v.15 no.3
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    • pp.25-31
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    • 2010
  • Combined technique of burner and DOC has been used for regeneration of Diesel Particulate Filter. Experiments has been performed to increase the temperature of engine exhaust gas to burn the collected soot in DPF at all conditions of operation of 3 liter diesel engine. Ignition temperature of soot can be successfully obtained by heats of burner flame and residual fuel oxidation at diesel oxidation catalyst even in the condition of oxygen deficiency. It is found that the load of air compressor and heat loss can be reduced to the level of practical application. It is also found that CO and THC emissions are not increase by additional combustion of regeneration burner.

Thermal Phenomena of an N2O Catalyst Bed for Hybrid Rockets Using a Porous Medium Approach (다공성 매질 접근법을 적용한 하이브리드 로켓 N2O 촉매 점화기의 열적 현상)

  • 유우준;김수종;김진곤;장석필
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.9
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    • pp.89-96
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    • 2006
  • In this study, fluid flow and thermal characteristics in a catalyst bed for nitrous oxide catalytic decomposition which is introduced as a hybrid rocket ignition system for small satellites were theoretically considered. To analyze the thermal phenomena of the catalyst bed, a so-called porous medium approach has been opted for modeling the honeycomb geometry of the catalyst bed. Using a Brinkman-extended Darcy model for fluid flow and the one-equation model for heat transfer, the analytical solutions for both velocity and temperature distributions in the catalyst bed are obtained and compared with experimental data to validate the porous medium approach. Based on the analytical solutions, parameters of engineering importance are identified to be the porosity of the catalyst bed, effective volumetric ratio, the ratio of the radius of the catalyst bed to the radius of a pore, heat flux generated by a heater, and pumping power. Their effects on thermal phenomena of the catalyst bed are studied.

Catalytic Combustion Characteristics of Hydrogen-Air Premixture in a Millimeter Scale Monolith Coated with Platinum (밀리미터 스케일 촉매 연소기에서의 수소-공기 예혼합 가스의 촉매 연소 특성)

  • Choi, Won-Young;Kwon, Se-Jin
    • Journal of the Korean Society of Combustion
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    • v.10 no.1
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    • pp.20-26
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    • 2005
  • In the present study, catalytic combustion of hydrogen-air premixture in a millimeter scale monolith coated with Pt catalyst was investigated. As the combustor size decreases, the heat loss increases in proportion with the inverse of the scale of combustion chamber and combustion efficiency decreases in a conventional type of combustor. Combustion reaction assisted by catalyst can reduce the heat loss by decreasing the reaction temperature at which catalytic conversion takes place. Another advantage of catalytic combustion is that ignition is not required. Platinum was coated by incipient wetness method on a millimeter scale monolith with cell size of $1{\times}1mm$. Using this monolith as the core of the reaction chamber, temperatures were recorded at various locations along the flow direction. Burnt gas was passed to a gas chromatography system to measure the hydrogen content after the reaction. The measurements were made at various volume flow rate of the fuel-air premixture. The gas chromatography results showed the reaction was complete at all the test conditions and the reacting species penetrated the laminar boundary layer at the honeycomb and made contact with the catalyst coated surface. At all the measuring locations, the record showed monotonous increase of temperature during the measurement duration. And the temperature profile showed that the peak temperature is reached at the point nearest to the gas inlet and decreasing temperature along the flow direction.

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Solution Combustion Synthesis of LaFeO3 Powders and Their Carbon Ignition Property (용액연소합성법을 이용한 LaFeO3 분말 합성 및 탄소 연소 특성)

  • Rang, Da-Sik;Lee, Tae-Kun;Hwang, Yeon;Bae, Kwang-Hyun;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.17 no.7
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    • pp.382-385
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    • 2007
  • [ $LaFeO_3$ ] powders were prepared as the oxidation catalyst materials to reduce the emission of particulate matters from diesel engine and their catalytic effects on the oxidation of carbon were investigated. Solution combustion method was employed for the powder synthesis, which uses highly exothermic and selfsustaining reactions. In this study $LaFeO_3$ powders were synthesized at $400^{\circ}C$ as varying the ratio ($\Phi$) of fuel (citric acid) and oxidizer (metal nitrate), and their phase and carbon ignition property were examined. As $\Phi$ decreases, the crystallinity of synthesized $LaFeO_3$ powders enhanced. By calcining at $700^{\circ}C$, all the powders synthesized at various $\Phi$ fully crystallized. The calcined $LaFeO_3$ powders showed carbon ignition temperature as low as $501{\sim}530^{\circ}C$, which implied the decrease of the ignition temperature by $120{\sim}150^{\circ}C$.

A Study on Multi-Stage Catalytic Ignitor for Hybrid Rocket Auto Ignition (하이브리드 로켓 자동점화를 위한 다단촉매점화기에 관한 연구)

  • Choi, Woojoo;Kim, Jincheol;Kwon, Minchan;Yoo, Yeongjun;Kim, Taegyu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.117-119
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    • 2017
  • The multi-stage catalytic igniter for hybrid rocket auto ignition is described in this paper. After charging the catalyst and pre-heating the first stage, the $N_2O$ was supplied at the first stage with the low mass flow rate, and then the $N_2O$ with the high flow rate was supplied into the second stage. Even though the $N_2O$ flow rate was high, it was decomposed by supplying the high temperature gas which was evolved from the $N_2O$ decomposition in the first stage. This multi-stage ignitor resulted in the decrease of the ignition time in comparison with the previous ignitor, and confirmed the possibility of $N_2O$ decomposition with the high flow rate using the multi-stage catalytic-ignition system.

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Measurements of Autoigniton Temperature(AIT) and Time Lag of BTX(Benzene, Toluene, Xylenes) (BTX(Benzene, Toluene, Xylenes)의 자연발화온도와 발화지연시간의 측정)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.21 no.3 s.75
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    • pp.45-52
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    • 2006
  • The AITs(autoignition temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. The AITs are often used as a factor in determining the upper temperature limit for processing operations and conditions for handling, storage and transportation, and in determining potential fire hazard from accidental contact with hot surfaces. The measurement AITs are dependent upon many factors, namely initial temperature, pressure, volume, fuel/air stoichiometry, catalyst material, concentration of vapor, time lag. Therefore, the AITs reported by different ignition conditions are sometimes significantly different. This study measured the AITs of benzene, toluene and xylene isomers from time lag using AS1M E659-78 apparatus. The experimental ignition delay times were a good agreement with the calculated ignition delay times by the proposed equations wtih a few A.A.D.(average absolute deviation). Also The experimental AITs of benzene, toluene, o-xylene, m-xylene and p-xylene were $583^{\circ}C,\;547^{\circ}C,\;480^{\circ}C,\;587^{\circ}C,\;and\;557^{\circ}C$, respectively.

Improvement of Thermal Efficiency using Atkinson Cycle in a High-Compression Ratio, Spark-Ignition, Natural Gas Engine for Power Generation (고압축비 전기점화 천연가스 발전용 엔진에서 앳킨슨 사이클 적용을 통한 열효율 향상)

  • Junsun Lee;Hyunwook Park;Seungmook Oh;Changup Kim;Yonggyu Lee;Kernyong Kang
    • Journal of ILASS-Korea
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    • v.28 no.2
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    • pp.55-61
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    • 2023
  • Natural gas is a high-octane fuel that is effective in controlling knocking combustion. In addition, as a low-carbon fuel with a high hydrogen-carbon ratio, it emits less carbon dioxide and almost no particulate matter compared to conventional fossil fuels. Stoichiometric combustion engines equipped with a three-way catalyst are useful in various fields such as transportation and power generation because of their excellent exhaust emission reduction performance. However, stoichiometric combustion engines have a disadvantage of lower thermal efficiency compared to lean combustion engines. In this study, a combination of high compression ratio and Atkinson cycle was implemented in a 11 liter, 6-cylinder, spark-ignition engine to improve the thermal efficiency of the stoichiometric engine. As a result, pumping and friction losses were reduced and the operating range was extended with optimized Atkinson camshaft. Based on the exhaust gas limit temperature of 730℃, the maximum load and thermal efficiency were improved to BMEP 0.66 MPa and BTE 35.7% respectively.

An Experimental Study for Reducing the Exhaust Hydrocarbon Emission at SI Engine Using Timed Secondary Air Injection (2차 공기 분사에 의한 스파크 점화 가솔린 엔진의 배기 Hydrocarbon 저감에 관한 실험적 연구)

  • 심현성;김세준;정석호
    • Transactions of the Korean Society of Automotive Engineers
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    • v.7 no.7
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    • pp.104-112
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    • 1999
  • An experimental study for reducing the exhaust hydrocarbon emission at spark ignition engine using timed secondary air injection is carried out . In this study, secondary air injection timings and durations are controlled to decrease the hydrocarbon emission and to increase exhaust gas temperature at cold and warm-up engine conditions. The hydrocarbon reduction rate and exhaust gas temperature are compared between timed secondary air injection and continuous air injection. The optimum secondary air injection timing for reducing the hydrocarbon emission is at the exhaust valve open timing. At some engine conditions , the hydrocarbon emissions are decreased to 10% of engine raw values and exhaust gas temperatures increase by 20$0^{\circ}C$ with times secondary air injection . Timed secondary air injection has more hydrocarbon reduction rate that continuous secondary air injection except some engine conditions.

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Development of $H_2O_2$ Monopropellant Thruster with Monolith Support (모노리스를 이용한 과산화수소 단일추진제 추력기 개발)

  • An, Sung-Yong;Jin, Jung-Kun;Kwon, Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.1
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    • pp.18-26
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    • 2007
  • A development of monopropellant thruster for microsatellite that uses concentrated hydrogen peroxide is described. Catalyst, the most important component in the thruster, was prepared and coated on a monolith honeycomb. Performance evaluation of thruster was peformed by considering the efficiency of characteristic velocity and ignition delay. As a result, 96.0% of $C^*$ efficiency was obtained at designed propellant flowrate and steady state operating condition.