• Bulletin of the Korean Chemical Society
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• 제31권7호
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• pp.1907-1914
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• 2010

A novel catalytic kinetic method is proposed for the determination of Se(IV), Se(VI) and total inorganic selenium in water based on the catalytic effect of Se(IV) on the reduction of bromate by p-nitrophenylhydrazine at pH 3.0. The generated bromine, $Br_2$ or $Cl_2$ plus $Br_2$ in 0.1 M NaCl (or NaBr) environment efficiently decolorized Calmagite and the reaction was monitored spectrophotometrically at 523 nm as a function of time. In this indicator reaction, bromide acted as an activator for the catalysis of selenium (IV) and a reducing agent for selenium (VI) at pH 3.0, which allowed the determination of total selenium. The fixed time method was adopted for the determination and speciation of inorganic selenium. Under the optimum conditions, the calibration graph are linear in the range 1 - 35 ${\mu}gL^{-1}$ of Se(IV) for the fixed time method at $25^{\circ}C$. The detection limit based on statistical $3S_{blank}$/m-criterion was 0.215 ${\mu}gL^{-1}$ for the fixed time method (7 min). All of the variables that affect the sensitivity at 523 nm were investigated, and the optimum conditions were established. The interference effect of various cations and anions on the Se (IV) determination was also studied. The selectivity of the selenium determination was greatly improved with the use of the strongly cation exchange resin such as Amberlite IR120 plus. The proposed kinetic method was validated statistically and through recovery studies in natural water samples. The RSDs for ten replicate measurements of 5, 15 and 25 ${\mu}gL^{-1}$ of Se(IV) and Se(VI) was changed between 2.1 - 4.85%. Analyses of a certified standard reference material (NIST SRM 1643e) for selenium using the fixed-time method showed that the proposed kinetic method has good accuracy. Se(IV), Se(VI) and total inorganic selenium in environmental water samples have been successfully determined by this method after selective reduction of Se(VI) to Se(IV).

• 전기학회논문지
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• 제61권4호
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• pp.534-541
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• 2012

This paper tries to elicit an optimal generation mix of Korea. Two approaches, using the screening curve method and taking advantage of a generation expansion planning tool, WASP-IV, are applied in getting the mix. The data used in this study is based on the 5th basic plan for long-term electricity supply and demand. The Load Duration Curve, that is needed for applying Screening Curve Method(SCM), is made based on the load profile in 2010. In our using SCM, the nuclear plant's operation characteristic, carbon emission cost and spinning reserve are considered. In using WASP-IV to get the adequate generation mix, the base and target demand forecasts in the 5th basic plan are used and the carbon emission cost is also considered. In this paper, It introduces the domestic adequacy generation mix in 2024 though SCM and WASP-IV.

• 품질경영학회지
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• 제28권3호
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• pp.59-67
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• 2000

In analysis of resolution IV fractional factorial experiments, the main effects only are analyzed, even though we can get some useful information on the confounded 2-factor interactions. In this paper, we introduce an exploiting method of the confounded structure of interactions, especially for the near minimal resolution IV 3$^{t}$ fractional factorial designs developed by Anderson and Thomas (1979). Moreover, in this paper the application way of the proposed method is also discussed by analyzing some simulated data.

• 한국콘텐츠학회논문지
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• 제7권4호
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• pp.206-212
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• 2007

IV(intravenous) 카데터 조각을 정맥 내에서 정확한 위치 및 크기를 확인하기위해 MDCT의 3D 재구성 기법인 볼륨렌더링의 임계치를 측정하고 변화에 따라 IV 카데터 조각의 영상을 구현하였다. 3D프로그램에서 파일럿 방법으로 IV 카데터의 HU(hounsfield unit) 값을 측정하였고, IV 카데터가 남아 있는 환자를 대상으로 프로파일과 관심영역 테이블 기능을 이용하여 IV 카데터의 HU 값을 측정하여 임계치를 설정하여 IV 카데터 조각의 위치 및 크기를 볼륨렌더링 영상에서 확인 하였다. 볼륨렌더링 영상에서 HU의 임계치 설정은 IV 카데터 조각의 정확한 위치 및 크기를 확인하는데 매우 중요한 요소이다.

• 대한화학회지
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• 제8권4호
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• pp.147-152
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• 1964

有機溶媒(benzene)에 의한 抽出法을 利用하고, 分光光度法에 의한 몰比法과 連續變化法을 써서, V(IV)-cupferrate와 V(V)-cupferrate의 化學沮成이 水溶液相에서 有機溶媒相으로 分配된 다음에도 雙하지 않을 것이라는 假定밑에서, 水溶液의 酸性度에 따르는 cupferrate 錯化合物의 化學組成을 決定하였다. V(IV)-cupferrate의 benzene 溶液에서의 最大吸光波長은 pH에 따라 445$m{\mu}$ 또는 450$m{\mu}$이고, V(V)-cupferrate의 그것은 pH 1.8以下에서는 pH에 無關하게 445$m{\mu}$이었다. V(V)-cupferrate의 化學組成은 沈澱이 形成되는 水溶液의 pH에 따라 다르며, pH 1.0 以下에서는 $VCupf_4$, pH 1.3∼1.7에서는 $HVOCupf_3$ 또는 $VCupf_4$와 $VOCupf_2$의 거의 같은 몰씩으로된 混合物이고, pH 1.8∼4.3에서는 $VOCupf_2$이었다. V(V)-cupferrate의 化學組成은 水溶液의 pH에 따라 變化가 없고, pH 1.8 以下에서는 $HVO_2Cupf_2$이었다.

• 분석과학
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• 제8권3호
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• pp.397-404
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• 1995

Three Arsenazo I-XAD Chelating resins, with different surface areas and pore sizes were synthesized and characterized. The total sorption capacities of these chelating resins for Cu(II) at pH 5.0 by batch method decreased as follows, Arsenazo I-XAD-16(0.59mmol/g)>Arsenazo I-XAD-4(0.56mmol/g)>Arsenazo I-XAD-2(0.38mmol/g). The sorption and desorption properties of Arsenazo I-XAD-16 chelating resins for U(VI), Th(IV), Hf(IV), Zr(IV), Ni(II), Mn(II), Cd(II). and Cu(II) were studied by both batch and elution method. The Arsenazo I-XAD-16 chelating resin was successfully applied to the separation and concentration of trace U(VI) and Th(IV) in sea and waste waters.

• 대한전기학회논문지
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• 제32권3호
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• pp.76-83
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• 1983

This paper describes the method of operating the phase controlled rectifier by controlling the firing angle in III, IV quadrant to absorb the lrading reactive power and of improving the waveform of ac current by driving dual converter. The system is intended to compensate the reactive power for any lagging load. Also, by the above method this paper enables us to improve the power factor and waveform referred to the source current and the dc output voltage in the converter.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2004년도 추계학술대회논문집
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• pp.677-684
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• 2004

This paper describes a method for identifying the dynamic characteristics of air foil bearings for high speed turbomachinerys with the LS/IV method. In fact identifying the characteristics of air foil bearings is very difficult work, and it is tried to identify it. Experiments were conducted to determine the structural dynamic and hydrodynamic characteristics of air foil bearings. Numerical predictions compare the static and dynamic force performances. The housing of the bearing on the journal was driven by the impact hammer which were used to simulate impact force acting on air foil bearings. The characteristics of air foil bearings were extracted from the frequency response function (FRF) by LS(Least Square) method and IV(Instrumental Variable) method. The experiment was tested at 0 rpm and $10000\sim16000rpm$. And the test results were introduced about the dynamic characteristics of air foil bearings, and also compared with theoritical results.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2011년도 제42회 하계학술대회
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• pp.1768-1769
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• 2011

The nonlinear estimation and the pseudo-linear estimation are used to treat the target localization in sensor network which provides range difference of arrival (RDOA) measurements. It is known that the nonlinear estimation has sensitive problem for the initial estimate and the pseudo-linear estimation has a large estimation error. The QCLS method is the typical estimator of the methods for pseudo-linear estimation. However the estimate by using the QCLS method includes the estimation error because the first stage of two estimation processes of the QCLS method causes the biased estimation error. Therefore we propose a instrumental variables(IV) method for minimizing the estimation error of the first stage. The simulation shows that the performance of the proposed method is superior to the QCLS method.

• 한국안전학회지
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• 제9권1호
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• pp.95-99
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• 1994

Recently, there has been considerable concern about waste water discharges of chromium. The Chromium(IV) is of particular concern because this form has been demonstrated to be public health hazard. Chromium(IV) could be removed by the method of electrolysis from plating waste water. It was found that almost all of chromium(IV) present could be treated by electrolysis at current, 3A and pH 8.