• Title/Summary/Keyword: ITS II

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Synthesis of 2,2'-Iminodibenzoic Acid-Cellulose Adsorbent and Its Adsorptivity of Cu(II) and Pb(II) (2,2'-Iminodibenzoic acid-cellulose 흡착제의 합성과 Cu(II) 및 Pb(II)의 흡착에 관한 연구)

  • Shim, Sang-Kyun;Min, Byoung-Do
    • Analytical Science and Technology
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    • v.10 no.4
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    • pp.291-299
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    • 1997
  • 2,2'-iminodibenzoic acid-cellulose was prepared by reacting 2,2'-iminodibenzoic acid salt with cellulose-Cl obtained by chlorination of cellulose-OH which is the major component of sawdust. The adsorptivity of Pb(II) and Cu(II) was studied using the synthetic chelating adsorbent. The adsorption amounts of those ions increased with increasing pH and the optimum adsorption time of metal ion was about 1hr. The adsorptivity of Pb(II) was larger than that of Cu(II).

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Systems Engineering Processes for KSLV-II Program (한국형발사체개발사업 시스템엔지니어링 프로세스)

  • Park, Chang-Su;Kim, Keun-Taek
    • Journal of the Korean Society of Systems Engineering
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    • v.10 no.2
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    • pp.81-87
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    • 2014
  • The Korea space launch vehicle-II (KSLV-II) program aims at developing a national launch vehicle system capable of launching 1.5 ton satellite into a sunsynchronous orbit. It is the succeeding program to the Naro launch vehicle program. The KSLV-II is a large-scale complex system which requires a systematic approach to all parts of the program. The KSLV-II program is currently developing a tailored systems engineering process for its need. It references practices and lessons learned from developing Naro launch vehicle. Standardized NASA processes and INCOSE processes were also referenced and compared during development of the process framework. This paper introduces the systems engineering processes developed for the KSLV-II program.

Hydrothermal Synthesis, Crystal Structures and Properties of Zinc(II) Di-nuclear Complex and Copper(I) Coordination Polymer Based on Building Block 2-Phenyl-4,6-di(pyridin-2-yl)pyrimidine

  • Zhao, Pusu;Jing, Wang;Jing, Long;Jian, Fangfang;Li, Yufeng
    • Bulletin of the Korean Chemical Society
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    • v.34 no.12
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    • pp.3743-3748
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    • 2013
  • A tetradentate ligand of 2-phenyl-4,6-di(pyridin-2-yl)pyrimidine (L) has been synthesized and its complexes with $ZnI_2$ and CuI have been obtained by hydrothermal method. single crystal X-ray diffraction analysis indicates that ligand L coordinates with Zn(II) ions to form a simple four-coordinate di-nuclear complex, while the complexation of L with Cu(I) constructs a one-dimensional chain polymer. The existence of $I^-$ ion hampers the L to assemble grid-type complexes with Zn(II) and Cu(I). Fluorescence spectra show that the L emits blue fluorescence while its Cu(I) polymer decrease the fluorescence intensity and Zn(II) complex quenches the fluorescence.

Enzymatic properties of the N- and C-terminal halves of human hexokinase II

  • Ahn, Keun-Jae;Kim, Jong-Sun;Yun, Mi-Jin;Park, Jeon-Han;Lee, Jong-Doo
    • BMB Reports
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    • v.42 no.6
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    • pp.350-355
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    • 2009
  • Although previous studies on hexokinase (HK) II indicate both the N- and C-terminal halves are catalytically active, we show in this study the N-terminal half is significantly more catalytic than the C-terminal half in addition to having a significantly higher $K_m$ for ATP and Glu. Furthermore, truncated forms of intact HK II lacking its first N-terminal 18 amino acids ($\Delta$18) and a truncated N-terminal half lacking its first 18 amino acids ($\Delta$18N) have higher catalytic activity than other mutants tested. Similar results were obtained by PET-scan analysis using $^{18}F-FDG$. Our results collectively suggest that each domain of HK II possesses enzyme activity, unlike HK I, with the N-terminal half showing higher enzyme activity than the C-terminal half.

A Study on Court Dress and Its Ornaments of the Armed Vassals [I] - In Koryo Dynasty, when they attend the "Bopka", King while he is conducting his business - (위장종관(衛仗從官)의 복식(服飾)에 관한 연구(硏究)[I] - 고려대(高麗代) "법가(法駕)" 위장(衛仗)을 중심(中心)으로 -)

  • Im, Myung-Mi
    • Journal of the Korean Society of Costume
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    • v.5
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    • pp.103-112
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    • 1981
  • In Koryo Dynasty, during the reign of uijong, Choe Yun-ui and others countries collected the royal orders of the Koryo kings and adopted the Tang institutions, and compiled 50 volumes of a book, called "Detailed Ceremonies of Old and New." Recording about clothing, with a special focus on dress and its ornaments of armed vassals, when they attend the king while he is conducting his business. 1) As for the headgear's were the Pokdu, Moja, Kwan, Tumo (official hat to be worn with armors) and Malye (for protection against the cold). There were II kinds of headgear's name in all. 2) As for the clothes, (1) Kongbok (formal costume) (2) Dress, there were 34 kinds of clothes name differented by (i) flowerage on clothes (ii) size of sleeves (iii) color of clothes (iv) fabrics (v) the belt used with the dress. Others were; (3) Baeja (4) Hansam, (5) Poto, and (6) Armor. 3) As for colors of clothes, there were (i) Purple, (ii) Red(Scarlet), (iii) Green, (iv) Blue, (v) Yellow, (vi) Black and (vii) White. 4) As for materials, there were (i) Kum, Ra, Sa (all kinds of silk), (ii) Iron and (iii) Leather. 5) For belts, there were (i) Sockdae, (ii) Hongjung, (iii) Kayeundae, (iv) Dongdokum-dae, (v) Jojung and (vi) Dongshimsokdae.

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Investigation of Experimental Acute Ischemic Myocardium with a Microdialysis Appratus (미세 투석기를 이용한 실험적 급성 허혈 심근에 관한 영구)

  • Park, Seong-Dal;Kim, Song-Myeong
    • Journal of Chest Surgery
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    • v.26 no.6
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    • pp.441-451
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    • 1993
  • Protective effect of superoxide dismutase[SOD] and substrates on acute ischemic and reperfused myocardium was assessed by cardiac microdialysis. 30 Rabbits were divided into 4 groups; normal control group [group I, n=5], ischemic group [group II, n=5], SOD treated group [group III, n=10], and substrates treated group [group IV, n=10]. After a microdialysis apparatus was implanted in rabbit myocardium, coronary artery was occuluded for 5 minutes and reperfusion was performed for 30 minutes. Hemodynamic changes, CK-MB isoenzyme level and adenine ring compound level in effluent dialysates [equilibrated with interstitial fluid], and ultrastructural changes of myocardial cell were analysed. Systolic blood pressure at 10 and 30 minutes after reperfusion was higher in group III and IV than in group II [p<.05]. Also percent recovery of systolic blood pressure in group III [p<.01] and IV [p<.02] was higher than in group II. CK-MB isoenzyme level in effluent dialysates was peaked at 10 minutes after reperfusion, thereafter decreased in group II, III and IV. At 30 minutes after reperfusion, its level was lower in group III and IV than in group II[p<.05]. Adenine ring compound level in effluent dialysates increased till 10 minutes after reperfusion and progressively decreased. At 10 and 30 minutes after reperfusion, its level was lower in group III and IV than in group II without significance. Degree of myocardial damage was estimated by scoring of mitochondrial injury. Group I was within normal range and most severe injury was seen in group II. And the score of mitochondrial injury in group III and IV was lower than in group II. In conclusion, SOD and substrates[KMP solution] had protective effect on stunned myocardium. The microdialysis appratus was a good device for studying stunned myocardium, and cardiac microdialysis might be a unique technique for analysis of regional intramyocardial interstitial fluid.

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Transition Metal Complexes Derived From 2-hydroxy-4-(p-tolyldiazenyl)benzylidene)-2-(p-tolylamino)acetohydrazide Synthesis, Structural Characterization, and Biological Activities

  • Alhakimi, Ahmed N.;Shakdofa, Mohamad M.E.;Saeed, S. El-Sayed;Shakdofa, Adel M.E.;Al-Fakeh, Maged S.;Abdu, Ashwaq M.;Alhagri, Ibrahim A.
    • Journal of the Korean Chemical Society
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    • v.65 no.2
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    • pp.93-105
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    • 2021
  • Mononuclear Cu(II), Ni(II), Co(II), Mn(II), Zn(II), Fe(III), Ru(III), and UO2(II) complexes of 2-hydroxy-4-(p-tolyldiazenyl)benzylidene)-2-(p-tolylamino)acetohydrazide (H2L) were prepared by direct method. The ligand and its complexes were isolated in solid state and characterized by analytical techniques such as elemental and thermal analyses, molar conductance, magnetic susceptibility measurements and spectroscopic techniques such as UV-Visible, IR, 1H-NMR and 13C-NMR. The spectral data indicated that the ligand acted as neutral/monobasic bidentate or monobasic/dibasic tridentate ligand bonded to the metal ions through the oxygen atom of ketonic or enolic carbonyl group, azomethine nitrogen atom and deprotonated/protonated phenolic oxygen atom forming either tetragonally distorted octahedral or octahedral. Antimicrobial activities of the ligand and its complexes were evaluated against Escherichia coli, Bacillus subtilis and Aspergillus niger by well diffusion method. The results of antifungal activity showed that the Fe(III) complex (10) exhibited higher antifungal against Aspergillus niger than the other complexes. However, the results of antibacterial activity revealed that Cu(II) complex (4) is the most active against Escherichia coli while the Cu(II) complex (5) and Fe(III) complex (10) exhibited higher antibacterial effect on Bacillus subtilis than the other complexes.

A Polymeric Antibacterial Agent with Sustained Anti-bacterial Activity: Cellulose Xanthate-metal-neomycin Complexes

  • Kim, In-Ho;Jung, Yun-Jin;Kim, Young-Mi
    • Journal of Pharmaceutical Investigation
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    • v.36 no.6
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    • pp.371-375
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    • 2006
  • Neomycin coupled to a polymer matrix via a metal linker was prepared and evaluated for prolonging antibacterial activity. Microcrystallized cellulose was chemically modified to cellulose xanthate(MCX) to afford metal binding sites. MCX was treated with Cu(II), Fe(III) or Zn(II) followed by reaction with neomycin (Ne). The release of Ne from MCX-Zn(II)-Ne was investigated and its activity duration was measured by ditch plate method. The amount of metal bound to MCX was 0.36 mmol/g matrix, 0.26 mmol/g matrix and 0.56 mmol/g matrix for Cu(II), Zn(II) and Fe(III), respectively. Ne bound to MCX-metal chelates was 0.006 mmol, 0.07 mmol and 0.01 mmol per g MCX for Cu(II), Zn(II) and Fe(III), respectively. The Ne release from MCX-Zn(II)-Ne was sustained even after seven washes, whereas Ne from MC/Zn(II)/Ne mixture was almost completely released in two washes. Antibacterial activity was prolonged with MCX-Zn(II)-Ne and MCX-Fe(III)-Ne, but not with MCX-Cu(II)-Ne when compared with that of free Ne. Taken together, these results suggest that neomycin coupled to MCX via a proper metal linker has a potential as a polymeric antibacterial agent with sustained activity.

Evaluation of Pb (II) and Cd (II) biosorption from aqueous solution by Ziziphus lotus stem powder (ZLSP)

  • Nosair El Yakoubi;Mounia Ennami;Naouar Ben Ali;Zineb Nejjar El Ansari;Mohammed L'bachir EL KBIACH;Loubna Bounab;Brahim El Bouzdoudi
    • Membrane and Water Treatment
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    • v.15 no.2
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    • pp.89-98
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    • 2024
  • The ability of Zizyphus lotus stem powder (ZLSP) to remove Pb (II) and Cd (II) ions from an aqueous solution was evaluated. The present phenomenon of biosorption was revealed to depend on pH, biosorbent dosage, temperature, initial ionic concentration, time of contact and biosorbent's particle size. The sorption process was exothermic (∆H°<0), and showing a strong Pb(II)/Cd(II)-ZLSP affinity (∆S°>0). Gibbs free energy data (∆G°<0, and decreases as temperature increase) reveals that the process studied is characterized by its feasibility and spontaneous nature. The best fits of the equilibrium data were obtained by the Temkin model and the Langmuir model. The maximum Pb(II)/Cd(II)-ZLSP biosorption capacities were 33.02 mg/g for Pb (II) and 20.73 mg/g for Cd (II). The pseudo-second order model was the most appropriate for fitting the kinetic data. The characterization of the biochemical groups essentially involved in the sorption phenomenon was made possible by FTIR spectral analysis. The capacity of ZLSP as an effective and ecofriendly biosorbent is confirmed through this study.

Development of P-SURO II Hybrid Autonomous Underwater Vehicle and its Experimental Studies (P-SURO II 하이브리드 자율무인잠수정 기술 개발 및 현장 검증)

  • Li, Ji-Hong;Lee, Mun-Jik;Park, Sang-Heon;Kim, Jung-Tae;Kim, Jong-Geol;Suh, Jin-Ho
    • Journal of Institute of Control, Robotics and Systems
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    • v.19 no.9
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    • pp.813-821
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    • 2013
  • In this paper, we present the development of P-SURO II hybrid AUV (Autonomous Underwater Vehicle) which can be operated in both of AUV and ROV (Remotely Operated Vehicle) modes. In its AUV mode, the vehicle is supposed to carry out some of underwater missions which are difficult to be achieved in ROV mode due to the tether cable. To accomplish its missions such as inspection and maintenance of complex underwater structures in AUV mode, the vehicle is required to have high level of autonomy including environmental recognition, obstacle avoidance, autonomous navigation, and so on. In addition to its systematic development issues, some of algorithmic issues are also discussed in this paper. Various experimental studies are also presented to demonstrate these developed autonomy algorithms.